Argyrodite
Encyclopedia
Argyrodite is an uncommon silver
germanium
sulfide mineral
with formula Ag8GeS6. The color is iron-black with a purplish tinge, and the lustre
metallic.
Discovered by Clemens Winkler
in 1886, it is of interest as it was described shortly after the element germanium
was isolated, 15 years after it had been postulated by Mendeleev. It was first described for an occurrence in the Himmelsfürst Mine, Erzgebirge, Freiberg, Saxony
, Germany
.
The Freiberg mineral had previously been imperfectly described by August Breithaupt
under the name plusinglanz, and Bolivian crystals were incorrectly described in 1849 as crystallized brongniardite.
Isomorphous with argyrodite is the corresponding tin
bearing mineral Ag8SnS6, also found in Bolivia as pseudocubic crystals, and known by the name canfieldite
. There is also a related mineral, putzite, with composition (Cu4.7Ag3.3)GeS6.
Argyrodite gets its name from the Greek words that loosely translate into "rich in silver
".
Silver
Silver is a metallic chemical element with the chemical symbol Ag and atomic number 47. A soft, white, lustrous transition metal, it has the highest electrical conductivity of any element and the highest thermal conductivity of any metal...
germanium
Germanium
Germanium is a chemical element with the symbol Ge and atomic number 32. It is a lustrous, hard, grayish-white metalloid in the carbon group, chemically similar to its group neighbors tin and silicon. The isolated element is a semiconductor, with an appearance most similar to elemental silicon....
sulfide mineral
Sulfide mineral
The sulfide minerals are a class of minerals containing sulfide as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the arsenides, the antimonides, the bismuthinides, the sulfarsenides and the sulfosalts...
with formula Ag8GeS6. The color is iron-black with a purplish tinge, and the lustre
Lustre (mineralogy)
Lustre is a description of the way light interacts with the surface of a crystal, rock, or mineral. The word lustre traces its origins back to the Latin word lux, meaning "light", and generally implies radiance, gloss, or brilliance....
metallic.
Discovered by Clemens Winkler
Clemens Winkler
Clemens Alexander Winkler was a German chemist who discovered the element germanium in 1886, solidifying Dmitri Mendeleev's theory of periodicity.- Life :...
in 1886, it is of interest as it was described shortly after the element germanium
Germanium
Germanium is a chemical element with the symbol Ge and atomic number 32. It is a lustrous, hard, grayish-white metalloid in the carbon group, chemically similar to its group neighbors tin and silicon. The isolated element is a semiconductor, with an appearance most similar to elemental silicon....
was isolated, 15 years after it had been postulated by Mendeleev. It was first described for an occurrence in the Himmelsfürst Mine, Erzgebirge, Freiberg, Saxony
Freiberg, Saxony
Freiberg is a city in the Free State of Saxony, Germany, administrative center of the Mittelsachsen district.-History:The city was founded in 1186, and has been a center of the mining industry in the Ore Mountains for centuries...
, Germany
Germany
Germany , officially the Federal Republic of Germany , is a federal parliamentary republic in Europe. The country consists of 16 states while the capital and largest city is Berlin. Germany covers an area of 357,021 km2 and has a largely temperate seasonal climate...
.
The Freiberg mineral had previously been imperfectly described by August Breithaupt
August Breithaupt
Johann Friedrich August Breithaupt was a German mineralogist and professor at Freiberg Mining Academy in Freiberg, Saxony.-Biography:...
under the name plusinglanz, and Bolivian crystals were incorrectly described in 1849 as crystallized brongniardite.
Isomorphous with argyrodite is the corresponding tin
Tin
Tin is a chemical element with the symbol Sn and atomic number 50. It is a main group metal in group 14 of the periodic table. Tin shows chemical similarity to both neighboring group 14 elements, germanium and lead and has two possible oxidation states, +2 and the slightly more stable +4...
bearing mineral Ag8SnS6, also found in Bolivia as pseudocubic crystals, and known by the name canfieldite
Canfieldite
Canfieldite is a rare silver tin sulfide mineral with formula: Ag8SnS6. The mineral typically contains variable amounts of germanium substitution in the tin site and tellurium in the sulfur site. There is a complete series between canfieldite and its germanium analogue, argyrodite. It forms black...
. There is also a related mineral, putzite, with composition (Cu4.7Ag3.3)GeS6.
Argyrodite gets its name from the Greek words that loosely translate into "rich in silver
Silver
Silver is a metallic chemical element with the chemical symbol Ag and atomic number 47. A soft, white, lustrous transition metal, it has the highest electrical conductivity of any element and the highest thermal conductivity of any metal...
".