Boninite is a mafic

Mafic

Mafic is an adjective describing a silicate mineral or rock that is rich in magnesium and iron; the term is a portmanteau of the words "magnesium" and "ferric". Most mafic minerals are dark in color and the relative density is greater than 3. Common rock-forming mafic minerals include olivine,...

 extrusive rock

Rock (geology)

In geology, rock or stone is a naturally occurring solid aggregate of minerals and/or mineraloids.The Earth's outer solid layer, the lithosphere, is made of rock. In general rocks are of three types, namely, igneous, sedimentary, and metamorphic...

 high in both magnesium

Magnesium

Magnesium is a chemical element with the symbol Mg, atomic number 12, and common oxidation number +2. It is an alkaline earth metal and the eighth most abundant element in the Earth's crust and ninth in the known universe as a whole...

 and silica, formed in fore-arc environments, typically during the early stages of subduction. The rock is named for its occurrence in the Izu-Bonin arc

Island arc

An island arc is a type of archipelago composed of a chain of volcanoes which alignment is arc-shaped, and which are situated parallel and close to a boundary between two converging tectonic plates....

 south of Japan

Japan

Japan is an island nation in East Asia. Located in the Pacific Ocean, it lies to the east of the Sea of Japan, China, North Korea, South Korea and Russia, stretching from the Sea of Okhotsk in the north to the East China Sea and Taiwan in the south...

. It is characterized by extreme depletion in incompatible trace elements that are not fluid mobile (e.g., the heavy rare earth elements plus Nb, Ta, Hf) but variable enrichment in the fluid mobile elements (e.g., Rb, Ba, K). They are found almost exclusively in the fore-arc of primitive island arcs (that is, closer to the trench) and in ophiolite complexes thought to represent former fore-arc settings.

Boninite is considered to be a primitive andesite

Andesite

Andesite is an extrusive igneous, volcanic rock, of intermediate composition, with aphanitic to porphyritic texture. In a general sense, it is the intermediate type between basalt and dacite. The mineral assemblage is typically dominated by plagioclase plus pyroxene and/or hornblende. Magnetite,...

 derived from melting of metasomatised

Metasomatism

Metasomatism is the chemical alteration of a rock by hydrothermal and other fluids.Metasomatism can occur via the action of hydrothermal fluids from an igneous or metamorphic source. In the igneous environment, metasomatism creates skarns, greisen, and may affect hornfels in the contact...

 mantle

Mantle (geology)

The mantle is a part of a terrestrial planet or other rocky body large enough to have differentiation by density. The interior of the Earth, similar to the other terrestrial planets, is chemically divided into layers. The mantle is a highly viscous layer between the crust and the outer core....

.

Similar Archean

Archean

The Archean , also spelled Archeozoic or Archæozoic) is a geologic eon before the Paleoproterozoic Era of the Proterozoic Eon, before 2.5 Ga ago. Instead of being based on stratigraphy, this date is defined chronometrically...

 intrusives called sanukitoid

Sanukitoid

Sanukitoids are a variety of high-Mg granitoid found in convergent margin settings. The term "sanukitoid" was originally used to define a variety of Archean plutonic rock, but now also includes younger rocks with similar geochemical characteristics...

s have been reported in the rocks of several early craton

Craton

A craton is an old and stable part of the continental lithosphere. Having often survived cycles of merging and rifting of continents, cratons are generally found in the interiors of tectonic plates. They are characteristically composed of ancient crystalline basement rock, which may be covered by...

s.

Petrology

Boninite typically consists of phenocryst

Phenocryst

thumb|right|300px|[[Granite]]s often have large [[feldspar|feldspatic]] phenocrysts. This granite, from the [[Switzerland|Swiss]] side of the [[Mont Blanc]] massif, has large white [[plagioclase]] phenocrysts, [[triclinic]] [[mineral]]s that give [[trapezium|trapezoid]] shapes when cut through)...

s of pyroxene

Pyroxene

The pyroxenes are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. They share a common structure consisting of single chains of silica tetrahedra and they crystallize in the monoclinic and orthorhombic systems...

s and olivine

Olivine

The mineral olivine is a magnesium iron silicate with the formula 2SiO4. It is a common mineral in the Earth's subsurface but weathers quickly on the surface....

 in a crystallite-rich glassy matrix

Matrix (geology)

The matrix or groundmass of rock is the finer grained mass of material in which larger grains, crystals or clasts are embedded.The matrix of an igneous rock consists of finer grained, often microscopic, crystals in which larger crystals are embedded. This porphyritic texture is indicative of...

.

Geochemistry

Boninite is defined by

• high magnesium content (MgO
  MGO
  MGO may refer to:*Magnesium oxide, the chemical formula MgO*Methylglyoxal, abbreviated MGO*Metal Gear Online, a PlayStation 3 online multiplayer spin-off of the Metal Gear video game series...
  
   = 8-15%)
• low titanium
  Titanium
  Titanium is a chemical element with the symbol Ti and atomic number 22. It has a low density and is a strong, lustrous, corrosion-resistant transition metal with a silver color....
  
   (TiO₂
  Titanium dioxide
  Titanium dioxide, also known as titanium oxide or titania, is the naturally occurring oxide of titanium, chemical formula . When used as a pigment, it is called titanium white, Pigment White 6, or CI 77891. Generally it comes in two different forms, rutile and anatase. It has a wide range of...
  
   < 0.5%)
• silica content is 57 - 60%
• high Mg/(Mg + Fe
  Iron
  Iron is a chemical element with the symbol Fe and atomic number 26. It is a metal in the first transition series. It is the most common element forming the planet Earth as a whole, forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust...
  
  ) (0.55-0.83)
• Mantle-normal compatible
  Compatibility (geochemistry)
  In geochemistry, compatibility is a measure of how readily a particular trace element substitutes for a major element within a mineral.Compatibility of an ion is controlled by two things: its valence and its ionic radius. Both must approximate those of the major element for the trace element to be...
  
   elements Ni
  Nickel
  Nickel is a chemical element with the chemical symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel belongs to the transition metals and is hard and ductile...
  
   = 70-450 parts per million, Cr
  Chromium
  Chromium is a chemical element which has the symbol Cr and atomic number 24. It is the first element in Group 6. It is a steely-gray, lustrous, hard metal that takes a high polish and has a high melting point. It is also odorless, tasteless, and malleable...
  
   = 200-1800 ppm
• Ba
  Barium
  Barium is a chemical element with the symbol Ba and atomic number 56. It is the fifth element in Group 2, a soft silvery metallic alkaline earth metal. Barium is never found in nature in its pure form due to its reactivity with air. Its oxide is historically known as baryta but it reacts with...
  
  , Sr
  Strontium
  Strontium is a chemical element with the symbol Sr and the atomic number 38. An alkaline earth metal, strontium is a soft silver-white or yellowish metallic element that is highly reactive chemically. The metal turns yellow when exposed to air. It occurs naturally in the minerals celestine and...
  
  , LREE
  Rare earth element
  As defined by IUPAC, rare earth elements or rare earth metals are a set of seventeen chemical elements in the periodic table, specifically the fifteen lanthanides plus scandium and yttrium...
  
   enrichments compared to tholeiite
• Characteristic Ti/Zr
  Zirconium
  Zirconium is a chemical element with the symbol Zr and atomic number 40. The name of zirconium is taken from the mineral zircon. Its atomic mass is 91.224. It is a lustrous, grey-white, strong transition metal that resembles titanium...
  
   ratios (23-63) and La
  Lanthanum
  Lanthanum is a chemical element with the symbol La and atomic number 57.Lanthanum is a silvery white metallic element that belongs to group 3 of the periodic table and is the first element of the lanthanide series. It is found in some rare-earth minerals, usually in combination with cerium and...
  
  /Yb
  Ytterbium
  Ytterbium is a chemical element with the symbol Yb and atomic number 70. A soft silvery metallic element, ytterbium is a rare earth element of the lanthanide series and is found in the minerals gadolinite, monazite, and xenotime. The element is sometimes associated with yttrium or other related...
  
   ratios (0.6-4.7)

Genesis

Boninite magma is formed by second stage melting in forearc

Forearc

A forearc or forarc, also called arc-trench gap is a depression in the sea floor located between a subduction zone and an associated volcanic arc. It is typically filled with sediments from the adjacent landmass and the island arc in addition to trapped oceanic crustal material...

s via hydration

Mineral hydration

Mineral hydration is an inorganic chemical reaction where water is added to the crystal structure of a mineral, usually creating a new mineral, usually called a hydrate....

 of previously depleted mantle within the mantle wedge above a subducted slab

Subduction

In geology, subduction is the process that takes place at convergent boundaries by which one tectonic plate moves under another tectonic plate, sinking into the Earth's mantle, as the plates converge. These 3D regions of mantle downwellings are known as "Subduction Zones"...

, causing further melting of the already depleted peridotite

Peridotite

A peridotite is a dense, coarse-grained igneous rock, consisting mostly of the minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium, reflecting the high proportions of magnesium-rich olivine, with appreciable iron...

. The extremely low content of titanium, which is an incompatible element within melting of peridotite is the result of previous melting events that removed most of the incompatible elements from the residual mantle source. The first stage melting typically forms island arc basalt.

Boninite attains its high magnesium and very low titanium content via high degrees of partial melting within the convecting

Mantle convection

Mantle convection is the slow creeping motion of Earth's rocky mantle caused by convection currents carrying heat from the interior of the Earth to the surface. The Earth's surface lithosphere, which rides atop the asthenosphere , is divided into a number of plates that are continuously being...

 mantle wedge. The high degrees of partial melting are caused by the high water content of the mantle. With the addition of slab-derived volatiles, and incompatible elements derived from the release of low-volume partial melts of the subducted slab, the depleted mantle in the mantle wedge undergoes melting.

Evidence for variable enrichment or depletion of incompatible elements suggests that boninites are derived from refractory peridotite which has been metasomatically enriched in LREE, Sr, Ba and alkali

Alkali

In chemistry, an alkali is a basic, ionic salt of an alkali metal or alkaline earth metal element. Some authors also define an alkali as a base that dissolves in water. A solution of a soluble base has a pH greater than 7. The adjective alkaline is commonly used in English as a synonym for base,...

s. Enrichment in Ba, Sr and alkalis may result from a component derived from subducted oceanic crust. This is envisaged as contamination from the underlying subducted slab, either as a sedimentary source or as melts derived from the dehydrating slab.

Boninites can be derived from the peridotite residue of earlier arc tholeiite generation which is metasomatically enriched in LREE before boninite volcanism

Volcano

2. Bedrock3. Conduit 4. Base5. Sill6. Dike7. Layers of ash emitted by the volcano8. Flank| 9. Layers of lava emitted by the volcano10. Throat11. Parasitic cone12. Lava flow13. Vent14. Crater15...

, or arc tholeiites and boninites can be derived from a variably depleted peridotite source which has been variably metasomatised in LREE.

Areas of fertile peridotite would yield tholeiites while refractory areas would yield boninites.

Examples

Examples of Boninite

Name	Location	Age	Comments
Bonin Islands	Pacific Ocean Pacific Ocean The Pacific Ocean is the largest of the Earth's oceanic divisions. It extends from the Arctic in the north to the Southern Ocean in the south, bounded by Asia and Australia in the west, and the Americas in the east.At 165.2 million square kilometres in area, this largest division of the World...	Eocene Eocene The Eocene Epoch, lasting from about 56 to 34 million years ago , is a major division of the geologic timescale and the second epoch of the Paleogene Period in the Cenozoic Era. The Eocene spans the time from the end of the Palaeocene Epoch to the beginning of the Oligocene Epoch. The start of the...	mostly volcanic breccia Breccia Breccia is a rock composed of broken fragments of minerals or rock cemented together by a fine-grained matrix, that can be either similar to or different from the composition of the fragments.... s and pillow lava Pillow lava Pillow lavas are lavas that contain characteristic pillow-shaped structures that are attributed to the extrusion of the lava under water, or subaqueous extrusion. Pillow lavas in volcanic rock are characterized by thick sequences of discontinuous pillow-shaped masses, commonly up to one metre in...  flows
Cape Vogel	Papua New Guinea Papua New Guinea Papua New Guinea , officially the Independent State of Papua New Guinea, is a country in Oceania, occupying the eastern half of the island of New Guinea and numerous offshore islands...	Paleocene Paleocene The Paleocene or Palaeocene, the "early recent", is a geologic epoch that lasted from about . It is the first epoch of the Palaeogene Period in the modern Cenozoic Era...
Troodos Troodos Mountains Troodos is the biggest mountain range of Cyprus, located in the center of the island. Troodos' highest peak is Mount Olympus at 1,952 metres.The Troodos mountain range stretches across most of the western side of Cyprus...	Cyprus Cyprus Cyprus , officially the Republic of Cyprus , is a Eurasian island country, member of the European Union, in the Eastern Mediterranean, east of Greece, south of Turkey, west of Syria and north of Egypt. It is the third largest island in the Mediterranean Sea.The earliest known human activity on the...	Cretaceous Cretaceous The Cretaceous , derived from the Latin "creta" , usually abbreviated K for its German translation Kreide , is a geologic period and system from circa to million years ago. In the geologic timescale, the Cretaceous follows the Jurassic period and is followed by the Paleogene period of the...	upper pillow lavas of ophiolite complex
Guam Guam Guam is an organized, unincorporated territory of the United States located in the western Pacific Ocean. It is one of five U.S. territories with an established civilian government. Guam is listed as one of 16 Non-Self-Governing Territories by the Special Committee on Decolonization of the United...	Pacific Ocean Pacific Ocean The Pacific Ocean is the largest of the Earth's oceanic divisions. It extends from the Arctic in the north to the Southern Ocean in the south, bounded by Asia and Australia in the west, and the Americas in the east.At 165.2 million square kilometres in area, this largest division of the World...	Paleogene Paleogene The Paleogene is a geologic period and system that began 65.5 ± 0.3 and ended 23.03 ± 0.05 million years ago and comprises the first part of the Cenozoic Era...	late Eocene to early Oligocene Oligocene The Oligocene is a geologic epoch of the Paleogene Period and extends from about 34 million to 23 million years before the present . As with other older geologic periods, the rock beds that define the period are well identified but the exact dates of the start and end of the period are slightly...
Setouchi	Japan Japan Japan is an island nation in East Asia. Located in the Pacific Ocean, it lies to the east of the Sea of Japan, China, North Korea, South Korea and Russia, stretching from the Sea of Okhotsk in the north to the East China Sea and Taiwan in the south...	Miocene Miocene The Miocene is a geological epoch of the Neogene Period and extends from about . The Miocene was named by Sir Charles Lyell. Its name comes from the Greek words and and means "less recent" because it has 18% fewer modern sea invertebrates than the Pliocene. The Miocene follows the Oligocene...	sanukitoid Sanukitoid Sanukitoids are a variety of high-Mg granitoid found in convergent margin settings. The term "sanukitoid" was originally used to define a variety of Archean plutonic rock, but now also includes younger rocks with similar geochemical characteristics... s, 13 million years old
Baja California Baja California Baja California officially Estado Libre y Soberano de Baja California is one of the 31 states which, with the Federal District, comprise the 32 Federal Entities of Mexico. It is both the northernmost and westernmost state of Mexico. Before becoming a state in 1953, the area was known as the North...	Mexico Mexico The United Mexican States , commonly known as Mexico , is a federal constitutional republic in North America. It is bordered on the north by the United States; on the south and west by the Pacific Ocean; on the southeast by Guatemala, Belize, and the Caribbean Sea; and on the east by the Gulf of...	Miocene	14 to 12 million years old, includes bajaite
New Caledonia New Caledonia New Caledonia is a special collectivity of France located in the southwest Pacific Ocean, east of Australia and about from Metropolitan France. The archipelago, part of the Melanesia subregion, includes the main island of Grande Terre, the Loyalty Islands, the Belep archipelago, the Isle of...	Pacific Ocean Pacific Ocean The Pacific Ocean is the largest of the Earth's oceanic divisions. It extends from the Arctic in the north to the Southern Ocean in the south, bounded by Asia and Australia in the west, and the Americas in the east.At 165.2 million square kilometres in area, this largest division of the World...	Mesozoic Mesozoic The Mesozoic era is an interval of geological time from about 250 million years ago to about 65 million years ago. It is often referred to as the age of reptiles because reptiles, namely dinosaurs, were the dominant terrestrial and marine vertebrates of the time...	Permian Permian The PermianThe term "Permian" was introduced into geology in 1841 by Sir Sir R. I. Murchison, president of the Geological Society of London, who identified typical strata in extensive Russian explorations undertaken with Edouard de Verneuil; Murchison asserted in 1841 that he named his "Permian... -Triassic Triassic The Triassic is a geologic period and system that extends from about 250 to 200 Mya . As the first period of the Mesozoic Era, the Triassic follows the Permian and is followed by the Jurassic. Both the start and end of the Triassic are marked by major extinction events...  and Cretaceous age
Mariana Trench Mariana Trench The Mariana Trench or Marianas Trench is the deepest part of the world's oceans. It is located in the western Pacific Ocean, to the east of the Mariana Islands. The trench is about long but has a mean width of only...	Pacific Ocean Pacific Ocean The Pacific Ocean is the largest of the Earth's oceanic divisions. It extends from the Arctic in the north to the Southern Ocean in the south, bounded by Asia and Australia in the west, and the Americas in the east.At 165.2 million square kilometres in area, this largest division of the World...	Eocene

Eruption of boninite lava was observed in 2009 at West Mata

West Mata

West Mata is a submarine volcano located southwest of the Samoas. The volcano's peak lies 1,100 meters underwater. The volcano is currently the deepest erupting submarine volcano in the ocean, and the first to ever be filmed erupting...

 volcano in the Pacific Ocean by scientists using a remotely-operated submersible

Submersible

A submersible is a small vehicle designed to operate underwater. The term submersible is often used to differentiate from other underwater vehicles known as submarines, in that a submarine is a fully autonomous craft, capable of renewing its own power and breathing air, whereas a submersible is...

. Previously, boninite had been found only near extinct volcanoes more than one million years old.