Conichalcite
Encyclopedia
Conichalcite, Ca
Cu
(As
O
4)(OH
), is a relatively common arsenate mineral
related to duftite
(Pb
Cu(AsO4)(OH)). It is green, often botryoidal
, and occurs in the oxidation zone of some metal deposits. It occurs with limonite
, malachite
, beudantite
, adamite
, cuproadamite, olivenite
and smithsonite
.
orebodies
. Here groundwater enriched with oxygen react with copper sulfide
and copper oxide
to produce an array of minerals such as malachite
, azurite
and linarite
. Conichalcite is often found encrusted on to limonitic rocks that have yellow to red colors.
Conichalcite will also form a solid solution
series with the mineral calciovolborthite. When these two minerals form a solid solution series, the two interchanging elements are arsenic
and vanadium
. Conichalcite is the arsenic rich end member of the series and calciovolborthite is the vanadium rich end member.
Notable occurrences of conichalcite include Juab Co.
, Utah
; Lincoln
and Lyon
counties of Nevada
and Bisbee
, Arizona
, in the USA
; Durango
, Mexico
; Collahuasi, Tarapaca, Chile
; Calstock, Cornwall
and Caldbeck Fells, Cumbria
, England
; Andalusia
, Spain
; and Tsumeb
, Namibia
.
Calcium
Calcium is the chemical element with the symbol Ca and atomic number 20. It has an atomic mass of 40.078 amu. Calcium is a soft gray alkaline earth metal, and is the fifth-most-abundant element by mass in the Earth's crust...
Cu
Copper
Copper is a chemical element with the symbol Cu and atomic number 29. It is a ductile metal with very high thermal and electrical conductivity. Pure copper is soft and malleable; an exposed surface has a reddish-orange tarnish...
(As
Arsenic
Arsenic is a chemical element with the symbol As, atomic number 33 and relative atomic mass 74.92. Arsenic occurs in many minerals, usually in conjunction with sulfur and metals, and also as a pure elemental crystal. It was first documented by Albertus Magnus in 1250.Arsenic is a metalloid...
O
Oxygen
Oxygen is the element with atomic number 8 and represented by the symbol O. Its name derives from the Greek roots ὀξύς and -γενής , because at the time of naming, it was mistakenly thought that all acids required oxygen in their composition...
4)(OH
Hydrogen
Hydrogen is the chemical element with atomic number 1. It is represented by the symbol H. With an average atomic weight of , hydrogen is the lightest and most abundant chemical element, constituting roughly 75% of the Universe's chemical elemental mass. Stars in the main sequence are mainly...
), is a relatively common arsenate mineral
Arsenate mineral
Arsenate minerals usually refer to the naturally occurring orthoarsenates, possessing the 3- anion group and, more rarely, other arsenates with anions like AsO32- or [AsO22]- . Arsenite minerals are much less common...
related to duftite
Duftite
Duftite is a relatively common arsenate mineral with the formula CuPb, related to conichalcite. It is green and often forms botryoidal aggregates. It is a member of the Adelite-Descloizite Group, Conichalcite-Duftite Series. Duftite and conichalcite specimens from Tsumeb are commonly zoned in...
(Pb
Lead
Lead is a main-group element in the carbon group with the symbol Pb and atomic number 82. Lead is a soft, malleable poor metal. It is also counted as one of the heavy metals. Metallic lead has a bluish-white color after being freshly cut, but it soon tarnishes to a dull grayish color when exposed...
Cu(AsO4)(OH)). It is green, often botryoidal
Botryoidal
A botryoidal texture or mineral habit is one in which the mineral has a globular external form resembling a bunch of grapes as derived from the Greek. This is a common form for many minerals particularly hematite where it is the classically recognized shape. It is also a common form of goethite,...
, and occurs in the oxidation zone of some metal deposits. It occurs with limonite
Limonite
Limonite is an ore consisting in a mixture of hydrated iron oxide-hydroxide of varying composition. The generic formula is frequently written as FeO·nH2O, although this is not entirely accurate as limonite often contains a varying amount of oxide compared to hydroxide.Together with hematite, it has...
, malachite
Malachite
Malachite is a copper carbonate mineral, with the formula Cu2CO32. This green-colored mineral crystallizes in the monoclinic crystal system, and most often forms botryoidal, fibrous, or stalagmitic masses. Individual crystals are rare but do occur as slender to acicular prisms...
, beudantite
Beudantite
Beudandite is a secondary mineral occurring in the oxidized zones of polymetallic deposits. It is a lead, iron, arsenate, sulfate with endmember formula: PbFe36SO4AsO4....
, adamite
Adamite
Adamite is a zinc arsenate hydroxide mineral, Zn2AsO4OH. It is a mineral that typically occurs in the oxidized or weathered zone above zinc ore occurrences. Pure adamite is colorless, but usually it possess yellow color due to Fe compounds admixture. Tints of green also occur and are connected with...
, cuproadamite, olivenite
Olivenite
Olivenite is a copper arsenate mineral, formula Cu2AsO4OH. It crystallizes in the monoclinic system , and is sometimes found in small brilliant crystals of simple prismatic habit terminated by domal faces...
and smithsonite
Smithsonite
Smithsonite, or zinc spar, is zinc carbonate , a mineral ore of zinc. Historically, smithsonite was identified with hemimorphite before it was realised that they were two distinct minerals. The two minerals are very similar in appearance and the term calamine has been used for both, leading to some...
.
Formation
Conichalcite forms in the oxidation zones of copperCopper
Copper is a chemical element with the symbol Cu and atomic number 29. It is a ductile metal with very high thermal and electrical conductivity. Pure copper is soft and malleable; an exposed surface has a reddish-orange tarnish...
orebodies
Ore
An ore is a type of rock that contains minerals with important elements including metals. The ores are extracted through mining; these are then refined to extract the valuable element....
. Here groundwater enriched with oxygen react with copper sulfide
Copper sulfide
Copper sulfides describe a family of chemical compounds and minerals with the formula CuxSy. Both minerals and synthetic materials comprise these compounds. Some copper sulfides are economically important ores....
and copper oxide
Copper oxide
Copper oxide is a compound from the two elements copper and oxygen.Copper oxide may refer to:*Copper oxide , a red powder;*Copper oxide , a black powder...
to produce an array of minerals such as malachite
Malachite
Malachite is a copper carbonate mineral, with the formula Cu2CO32. This green-colored mineral crystallizes in the monoclinic crystal system, and most often forms botryoidal, fibrous, or stalagmitic masses. Individual crystals are rare but do occur as slender to acicular prisms...
, azurite
Azurite
Azurite is a soft, deep blue copper mineral produced by weathering of copper ore deposits. It is also known as Chessylite after the type locality at Chessy-les-Mines near Lyon, France...
and linarite
Linarite
Linarite is a somewhat rare, crystalline mineral that is known among mineral collectors for its unusually intense, pure blue color. It is formed by the oxidation of galena and chalcopyrite and other copper sulfides. It is a combined copper lead sulfate hydroxide with formula PbCuSO42.Linarite...
. Conichalcite is often found encrusted on to limonitic rocks that have yellow to red colors.
Conichalcite will also form a solid solution
Solid solution
A solid solution is a solid-state solution of one or more solutes in a solvent. Such a mixture is considered a solution rather than a compound when the crystal structure of the solvent remains unchanged by addition of the solutes, and when the mixture remains in a single homogeneous phase...
series with the mineral calciovolborthite. When these two minerals form a solid solution series, the two interchanging elements are arsenic
Arsenic
Arsenic is a chemical element with the symbol As, atomic number 33 and relative atomic mass 74.92. Arsenic occurs in many minerals, usually in conjunction with sulfur and metals, and also as a pure elemental crystal. It was first documented by Albertus Magnus in 1250.Arsenic is a metalloid...
and vanadium
Vanadium
Vanadium is a chemical element with the symbol V and atomic number 23. It is a hard, silvery gray, ductile and malleable transition metal. The formation of an oxide layer stabilizes the metal against oxidation. The element is found only in chemically combined form in nature...
. Conichalcite is the arsenic rich end member of the series and calciovolborthite is the vanadium rich end member.
Notable occurrences of conichalcite include Juab Co.
Juab County, Utah
Juab County is a county located in the U.S. state of Utah. As of 2000 the population was 8,238, and by 2005 had been estimated at 9,113. It was named from an Indian word meaning thirsty valley, or possibly only valley. Its county seat and largest city is Nephi.Juab County is part of the...
, Utah
Utah
Utah is a state in the Western United States. It was the 45th state to join the Union, on January 4, 1896. Approximately 80% of Utah's 2,763,885 people live along the Wasatch Front, centering on Salt Lake City. This leaves vast expanses of the state nearly uninhabited, making the population the...
; Lincoln
Lincoln County, Nevada
Lincoln County is a county located in the U.S. state of Nevada. As of the 2000 census, the population was 4,165. Its county seat is Pioche.-History:...
and Lyon
Lyon County, Nevada
Lyon County is a county located in the U.S. state of Nevada. As of the 2010 census, the population was 51,980. Its county seat is Yerington.-History:...
counties of Nevada
Nevada
Nevada is a state in the western, mountain west, and southwestern regions of the United States. With an area of and a population of about 2.7 million, it is the 7th-largest and 35th-most populous state. Over two-thirds of Nevada's people live in the Las Vegas metropolitan area, which contains its...
and Bisbee
Bisbee
Bisbee may refer to:* Bisbee, Arizona* Bisbee, North Dakota* Bisbee Blue, turquoise from Bisbee, Arizona.* Bisbee Deportation, the illegal expulsion of 1,300 miners from Bisbee, Arizona...
, Arizona
Arizona
Arizona ; is a state located in the southwestern region of the United States. It is also part of the western United States and the mountain west. The capital and largest city is Phoenix...
, in the USA
United States
The United States of America is a federal constitutional republic comprising fifty states and a federal district...
; Durango
Durango
Durango officially Estado Libre y Soberano de Durango is one of the 31 states which, with the Federal District, comprise the 32 Federal Entities of Mexico. The state is located in Northwest Mexico. With a population of 1,632,934, it has Mexico's second-lowest population density, after Baja...
, Mexico
Mexico
The United Mexican States , commonly known as Mexico , is a federal constitutional republic in North America. It is bordered on the north by the United States; on the south and west by the Pacific Ocean; on the southeast by Guatemala, Belize, and the Caribbean Sea; and on the east by the Gulf of...
; Collahuasi, Tarapaca, Chile
Chile
Chile ,officially the Republic of Chile , is a country in South America occupying a long, narrow coastal strip between the Andes mountains to the east and the Pacific Ocean to the west. It borders Peru to the north, Bolivia to the northeast, Argentina to the east, and the Drake Passage in the far...
; Calstock, Cornwall
Cornwall
Cornwall is a unitary authority and ceremonial county of England, within the United Kingdom. It is bordered to the north and west by the Celtic Sea, to the south by the English Channel, and to the east by the county of Devon, over the River Tamar. Cornwall has a population of , and covers an area of...
and Caldbeck Fells, Cumbria
Cumbria
Cumbria , is a non-metropolitan county in North West England. The county and Cumbria County Council, its local authority, came into existence in 1974 after the passage of the Local Government Act 1972. Cumbria's largest settlement and county town is Carlisle. It consists of six districts, and in...
, England
England
England is a country that is part of the United Kingdom. It shares land borders with Scotland to the north and Wales to the west; the Irish Sea is to the north west, the Celtic Sea to the south west, with the North Sea to the east and the English Channel to the south separating it from continental...
; Andalusia
Andalusia
Andalusia is the most populous and the second largest in area of the autonomous communities of Spain. The Andalusian autonomous community is officially recognised as a nationality of Spain. The territory is divided into eight provinces: Huelva, Seville, Cádiz, Córdoba, Málaga, Jaén, Granada and...
, Spain
Spain
Spain , officially the Kingdom of Spain languages]] under the European Charter for Regional or Minority Languages. In each of these, Spain's official name is as follows:;;;;;;), is a country and member state of the European Union located in southwestern Europe on the Iberian Peninsula...
; and Tsumeb
Tsumeb
Tsumeb is a city of 15,000 inhabitants and the largest town in Oshikoto region in northern Namibia. Tsumeb is the home of the world-famous Tsumeb mine, and the "gateway to the north" of Namibia. It is the closest town to the Etosha National Park...
, Namibia
Namibia
Namibia, officially the Republic of Namibia , is a country in southern Africa whose western border is the Atlantic Ocean. It shares land borders with Angola and Zambia to the north, Botswana to the east and South Africa to the south and east. It gained independence from South Africa on 21 March...
.