Conjugate acid
Encyclopedia
Within the Brønsted–Lowry acid-base theory (protonic), a conjugate acid is the acid member, HX, of a pair of two compounds that transform into each other by gain or loss of a proton. A conjugate acid can also be seen as the chemical substance that releases, or donates, a proton in the forward chemical reaction, hence, the term acid. The base produced, X−, is called the conjugate base, and it absorbs, or gains, a proton in the backward chemical reaction. In aqueous solution, the chemical reaction involved is of the form
This principle is discussed in detail in the article on acid-base reaction theories. The position of the equilibrium is measured as an acid dissociation constant
(Ka)
Tabulated below are several examples of conjugate acid-base pairs. Acid strength decreases and base strength increases down the table.
- HX + H2O X− + H3O+
This principle is discussed in detail in the article on acid-base reaction theories. The position of the equilibrium is measured as an acid dissociation constant
Acid dissociation constant
An acid dissociation constant, Ka, is a quantitative measure of the strength of an acid in solution. It is the equilibrium constant for a chemical reaction known as dissociation in the context of acid-base reactions...
(Ka)
Tabulated below are several examples of conjugate acid-base pairs. Acid strength decreases and base strength increases down the table.
Acid | Base |
---|---|
HFSbF5 Fluoroantimonic acid Fluoroantimonic acid Fluoroantimonic acid is a mixture of hydrogen fluoride and antimony pentafluoride in various ratios. The 1:1 combination forms the strongest known superacid, which has been demonstrated to protonate even hydrocarbons to afford carbocations and H2.... |
SbF6− Hexafluoroantimonate Antimony pentafluoride Antimony pentafluoride is the inorganic compound with the formula SbF5. This colourless, viscous liquid is a valuable Lewis acid and a component of the superacid fluoroantimonic acid, the strongest known acid... ion |
HCl Hydrochloric acid Hydrochloric acid Hydrochloric acid is a solution of hydrogen chloride in water, that is a highly corrosive, strong mineral acid with many industrial uses. It is found naturally in gastric acid.... |
Cl− Chloride Chloride The chloride ion is formed when the element chlorine, a halogen, picks up one electron to form an anion Cl−. The salts of hydrochloric acid HCl contain chloride ions and can also be called chlorides. The chloride ion, and its salts such as sodium chloride, are very soluble in water... ion |
H2SO4 Sulfuric acid Sulfuric acid Sulfuric acid is a strong mineral acid with the molecular formula . Its historical name is oil of vitriol. Pure sulfuric acid is a highly corrosive, colorless, viscous liquid. The salts of sulfuric acid are called sulfates... |
HSO4− Hydrogen sulfate ion |
HNO3 Nitric acid Nitric acid Nitric acid , also known as aqua fortis and spirit of nitre, is a highly corrosive and toxic strong acid.Colorless when pure, older samples tend to acquire a yellow cast due to the accumulation of oxides of nitrogen. If the solution contains more than 86% nitric acid, it is referred to as fuming... |
NO3− Nitrate Nitrate The nitrate ion is a polyatomic ion with the molecular formula NO and a molecular mass of 62.0049 g/mol. It is the conjugate base of nitric acid, consisting of one central nitrogen atom surrounded by three identically-bonded oxygen atoms in a trigonal planar arrangement. The nitrate ion carries a... ion |
H3O+ Hydronium Hydronium In chemistry, a hydronium ion is the cation , a type of oxonium ion produced by protonation of water. This cation is often used to represent the nature of the proton in aqueous solution, where the proton is highly solvated... ion |
H2O Water |
HSO4− Hydrogen sulfate ion | SO42− Sulfate Sulfate In inorganic chemistry, a sulfate is a salt of sulfuric acid.-Chemical properties:... ion |
H3PO4 Phosphoric acid Phosphoric acid Phosphoric acid, also known as orthophosphoric acid or phosphoric acid, is a mineral acid having the chemical formula H3PO4. Orthophosphoric acid molecules can combine with themselves to form a variety of compounds which are also referred to as phosphoric acids, but in a more general way... |
H2PO4− Dihydrogen phosphate ion |
CH3COOH Acetic acid Acetic acid Acetic acid is an organic compound with the chemical formula CH3CO2H . It is a colourless liquid that when undiluted is also called glacial acetic acid. Acetic acid is the main component of vinegar , and has a distinctive sour taste and pungent smell... |
CH3COO− Acetate Acetate An acetate is a derivative of acetic acid. This term includes salts and esters, as well as the anion found in solution. Most of the approximately 5 billion kilograms of acetic acid produced annually in industry are used in the production of acetates, which usually take the form of polymers. In... ion |
H2CO3 Carbonic acid Carbonic acid Carbonic acid is the inorganic compound with the formula H2CO3 . It is also a name sometimes given to solutions of carbon dioxide in water, because such solutions contain small amounts of H2CO3. Carbonic acid forms two kinds of salts, the carbonates and the bicarbonates... |
HCO3− Hydrogen carbonate ion |
H2S Hydrosulfuric acid | HS− Hydrogen sulfide Hydrogen sulfide Hydrogen sulfide is the chemical compound with the formula . It is a colorless, very poisonous, flammable gas with the characteristic foul odor of expired eggs perceptible at concentrations as low as 0.00047 parts per million... ion |
H2PO4− Dihydrogen phosphate ion | HPO42− Hydrogen phosphate ion |
NH4+ Ammonium Ammonium The ammonium cation is a positively charged polyatomic cation with the chemical formula NH. It is formed by the protonation of ammonia... ion |
NH3 Ammonia Ammonia Ammonia is a compound of nitrogen and hydrogen with the formula . It is a colourless gas with a characteristic pungent odour. Ammonia contributes significantly to the nutritional needs of terrestrial organisms by serving as a precursor to food and fertilizers. Ammonia, either directly or... |
HCO3− Hydrogencarbonate (bicarbonate) ion | CO32− Carbonate Carbonate In chemistry, a carbonate is a salt of carbonic acid, characterized by the presence of the carbonate ion, . The name may also mean an ester of carbonic acid, an organic compound containing the carbonate group C2.... ion |
HPO42− Hydrogen phosphate ion | PO43− Phosphate Phosphate A phosphate, an inorganic chemical, is a salt of phosphoric acid. In organic chemistry, a phosphate, or organophosphate, is an ester of phosphoric acid. Organic phosphates are important in biochemistry and biogeochemistry or ecology. Inorganic phosphates are mined to obtain phosphorus for use in... ion |
H2O Water Water Water is a chemical substance with the chemical formula H2O. A water molecule contains one oxygen and two hydrogen atoms connected by covalent bonds. Water is a liquid at ambient conditions, but it often co-exists on Earth with its solid state, ice, and gaseous state . Water also exists in a... (neutral, pH PH In chemistry, pH is a measure of the acidity or basicity of an aqueous solution. Pure water is said to be neutral, with a pH close to 7.0 at . Solutions with a pH less than 7 are said to be acidic and solutions with a pH greater than 7 are basic or alkaline... 7) |
OH− Hydroxide Hydroxide Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and a hydrogen atom held together by a covalent bond, and carrying a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, as a ligand, a nucleophile, and a... ion |