Franckeite, chemical formula Pb₅Sn₃Sb₂S₁₄, belongs to a family of complex sulfide mineral

Sulfide mineral

The sulfide minerals are a class of minerals containing sulfide as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the arsenides, the antimonides, the bismuthinides, the sulfarsenides and the sulfosalts...

s. Franckeite is a sulfosalt. It is closely related to cylindrite

Cylindrite

Cylindrite is a sulfosalt mineral containing tin, lead, antimony and iron with formula: Pb3Sn4FeSb2S14. It forms triclinic pinacoidal crystals which often occur as tubes or cylinders which are in fact rolled sheets...

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It was first described in 1893 for an occurrence in Chocaya, Potosí Department

Potosí Department

Potosí Department is a department in southwestern Bolivia. It comprises 118,218 km² with 709,013 inhabitants . The capital is the city of Potosí....

, Bolivia

Bolivia

Bolivia officially known as Plurinational State of Bolivia , is a landlocked country in central South America. It is the poorest country in South America...

. It is named after the mining engineers, Carl and Ernest Francke. It can be found in Bolivia at Poopó in Oruro and at Las Aminas, southeast of Chocaya, in Potosi. Franckeite has an average density of 5.7 and can be both grayish black, blackish gray in color.

It occurs in hydrothermal silver-tin deposits in Bolivia and in contact metamorphosed limestone

Limestone

Limestone is a sedimentary rock composed largely of the minerals calcite and aragonite, which are different crystal forms of calcium carbonate . Many limestones are composed from skeletal fragments of marine organisms such as coral or foraminifera....

 deposit in the Kalkar quarry in California

California

California is a state located on the West Coast of the United States. It is by far the most populous U.S. state, and the third-largest by land area...

. It occurs with cylindrite, teallite

Teallite

Teallite is a sulfide mineral of tin and lead with chemical formula: PbSnS2. It occurs in hydrothermal veins and is sometimes mined as an ore of tin. Teallite forms soft silvery grey mica-like plates and crystallizes in the orthorhombic system...

, plagionite, zinkenite

Zinkenite

Zinkenite is a steel-gray metallic sulfosalt mineral composed of lead antimony sulfide Pb9Sb22S42. Zinkenite occurs as acicular needle-like crystals....

, cassiterite

Cassiterite

Cassiterite is a tin oxide mineral, SnO2. It is generally opaque, but it is translucent in thin crystals. Its luster and multiple crystal faces produce a desirable gem...

, wurtzite

Wurtzite

Wurtzite is a zinc iron sulfide mineral a less frequently encountered mineral form of sphalerite. The iron content is variable up to eight percent. It is trimorphous with matraite and sphalerite....

, pyrrhotite

Pyrrhotite

Pyrrhotite is an unusual iron sulfide mineral with a variable iron content: FeS . The FeS endmember is known as troilite. Pyrrhotite is also called magnetic pyrite because the color is similar to pyrite and it is weakly magnetic...

,
marcasite

Marcasite

The mineral marcasite, sometimes called white iron pyrite, is iron sulfide with orthorhombic crystal structure. It is physically and crystallographically distinct from pyrite, which is iron sulfide with cubic crystal structure. Both structures do have in common that they contain the disulfide...

, arsenopyrite

Arsenopyrite

Arsenopyrite is an iron arsenic sulfide . It is a hard metallic, opaque, steel grey to silver white mineral with a relatively high specific gravity of 6.1. When dissolved in nitric acid, it releases elemental sulfur. When arsenopyrite is heated, it becomes magnetic and gives off toxic fumes...

, galena

Galena

Galena is the natural mineral form of lead sulfide. It is the most important lead ore mineral.Galena is one of the most abundant and widely distributed sulfide minerals. It crystallizes in the cubic crystal system often showing octahedral forms...

, pyrite

Pyrite

The mineral pyrite, or iron pyrite, is an iron sulfide with the formula FeS2. This mineral's metallic luster and pale-to-normal, brass-yellow hue have earned it the nickname fool's gold because of its resemblance to gold...

, sphalerite

Sphalerite

Sphalerite is a mineral that is the chief ore of zinc. It consists largely of zinc sulfide in crystalline form but almost always contains variable iron. When iron content is high it is an opaque black variety, marmatite. It is usually found in association with galena, pyrite, and other sulfides...

, siderite

Siderite

Siderite is a mineral composed of iron carbonate FeCO3. It takes its name from the Greek word σίδηρος sideros, “iron”. It is a valuable iron mineral, since it is 48% iron and contains no sulfur or phosphorus...

 and stannite

Stannite

Stannite is a mineral, a sulfide of copper, iron, and tin. The chemical formula Cu2FeSnS4. Zinc commonly occurs with the iron and trace germanium may be present. Stannite is used as an ore of tin, consisting of approximately 28% tin, 13% iron, 30% copper, 30% sulfur by mass...

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