Granular material
Encyclopedia
A granular material is a conglomeration of discrete solid
, macroscopic particles characterized by a loss of energy whenever the particles interact (the most common example would be friction
when grains collide). The constituents that compose granular material must be large enough such that they are not subject to thermal motion fluctuations. Thus, the lower size limit for grains in granular material is about 1 µm
. On the upper size limit, the physics of granular materials may be applied to ice floes where the individual grains are iceberg
s and to asteroid belt
s of the solar system
with individual grains being asteroid
s.
Some examples of granular materials are nuts
, coal
, sand
, rice
, coffee
, corn flakes
, fertilizer
, and ball bearing
s. Powder
s are a special class of granular material due to their small particle size, which makes them more cohesive
and more easily suspended
in a gas
. Granular materials are commercially important in applications as diverse as pharmaceutical industry, agriculture
, and energy production. Research into granular materials is thus directly applicable and goes back at least to Charles-Augustin de Coulomb
, whose law of friction
was originally stated for granular materials.
The soldier
/physicist
Brigadier Ralph Alger Bagnold
was an early pioneer of the physics of granular matter and whose book "The Physics of Blown Sand and Desert Dunes" remains an important reference to this day.
According to material scientist Patrick Richard, "Granular materials are ubiquitous in nature
and are the second-most manipulated material in industry (the first one is water
)".
In some sense, granular materials do not constitute a single phase of matter but have characteristics reminiscent of solid
s, liquid
s, or gas
es depending on the average energy per grain. However in each of these states granular materials also exhibit properties which are unique.
Granular materials also exhibit a wide range of pattern forming behaviors when excited (e.g. vibrated or allowed to flow). As such granular materials under excitation can be thought of as an example of a complex system
.
and arch
ing.
When freely flowing, granular materials have flow characteristics that roughly resemble those of ordinary Newtonian fluid
s. However, granular materials dissipate energy quickly, so techniques of statistical mechanics
that assume conservation of energy are of limited use. Bulk flow characteristics of granular materials do differ from those of homogeneous fluids
in several important ways:
.
Unlike conventional gases granular materials will tend to cluster and clump due to the dissipative nature of the collisions between grains. This clustering has some interesting consequences. For example, if a partially partitioned box of granular materials is vigorously shaken then grains will over time tend to collect in one of the partitions rather than spread evenly into both partitions as would happen in a conventional gas. This effect, known as the granular Maxwell's Demon
, does not violate any thermodynamics principles since energy is constantly being lost from the system in the process.
and undergo a jamming transition which is thought of a thermodynamic phase transition to a jammed state.
Lubachevsky-Stillinger algorithm
of jamming allows one to produce simulated jammed granular configurations.
Some of the
pattern-forming behaviours
have been possible to reproduce in computer simulations.
There are two main computational approaches to such simulations, time-stepped and event-driven
,
the former being the most efficient for a higher density of the material
and the motions of a lower intensity,
and the latter for a lower density of the material
and the motions of a higher intensity.
exhibit squeaking when walked upon. Some desert dunes are known to exhibit booming during avalanching or when their surface is otherwise disturbed. Granular materials discharged from silos produce loud acoustic emissions in a process known as silo honking.
particles are made to adhere to form larger, multiparticle entities called granules.
Solid
Solid is one of the three classical states of matter . It is characterized by structural rigidity and resistance to changes of shape or volume. Unlike a liquid, a solid object does not flow to take on the shape of its container, nor does it expand to fill the entire volume available to it like a...
, macroscopic particles characterized by a loss of energy whenever the particles interact (the most common example would be friction
Friction
Friction is the force resisting the relative motion of solid surfaces, fluid layers, and/or material elements sliding against each other. There are several types of friction:...
when grains collide). The constituents that compose granular material must be large enough such that they are not subject to thermal motion fluctuations. Thus, the lower size limit for grains in granular material is about 1 µm
Micrometre
A micrometer , is by definition 1×10-6 of a meter .In plain English, it means one-millionth of a meter . Its unit symbol in the International System of Units is μm...
. On the upper size limit, the physics of granular materials may be applied to ice floes where the individual grains are iceberg
Iceberg
An iceberg is a large piece of ice from freshwater that has broken off from a snow-formed glacier or ice shelf and is floating in open water. It may subsequently become frozen into pack ice...
s and to asteroid belt
Asteroid belt
The asteroid belt is the region of the Solar System located roughly between the orbits of the planets Mars and Jupiter. It is occupied by numerous irregularly shaped bodies called asteroids or minor planets...
s of the solar system
Solar System
The Solar System consists of the Sun and the astronomical objects gravitationally bound in orbit around it, all of which formed from the collapse of a giant molecular cloud approximately 4.6 billion years ago. The vast majority of the system's mass is in the Sun...
with individual grains being asteroid
Asteroid
Asteroids are a class of small Solar System bodies in orbit around the Sun. They have also been called planetoids, especially the larger ones...
s.
Some examples of granular materials are nuts
Nut (fruit)
A nut is a hard-shelled fruit of some plants having an indehiscent seed. While a wide variety of dried seeds and fruits are called nuts in English, only a certain number of them are considered by biologists to be true nuts...
, coal
Coal
Coal is a combustible black or brownish-black sedimentary rock usually occurring in rock strata in layers or veins called coal beds or coal seams. The harder forms, such as anthracite coal, can be regarded as metamorphic rock because of later exposure to elevated temperature and pressure...
, sand
Sand
Sand is a naturally occurring granular material composed of finely divided rock and mineral particles.The composition of sand is highly variable, depending on the local rock sources and conditions, but the most common constituent of sand in inland continental settings and non-tropical coastal...
, rice
Rice
Rice is the seed of the monocot plants Oryza sativa or Oryza glaberrima . As a cereal grain, it is the most important staple food for a large part of the world's human population, especially in East Asia, Southeast Asia, South Asia, the Middle East, and the West Indies...
, coffee
Coffee
Coffee is a brewed beverage with a dark,init brooo acidic flavor prepared from the roasted seeds of the coffee plant, colloquially called coffee beans. The beans are found in coffee cherries, which grow on trees cultivated in over 70 countries, primarily in equatorial Latin America, Southeast Asia,...
, corn flakes
Corn flakes
Corn flakes are a popular breakfast cereal originally manufactured by Kellogg's through the treatment of maize. A patent for the product was filed on May 31, 1895, and issued on April 14, 1896.-History:...
, fertilizer
Fertilizer
Fertilizer is any organic or inorganic material of natural or synthetic origin that is added to a soil to supply one or more plant nutrients essential to the growth of plants. A recent assessment found that about 40 to 60% of crop yields are attributable to commercial fertilizer use...
, and ball bearing
Ball bearing
A ball bearing is a type of rolling-element bearing that uses balls to maintain the separation between the bearing races.The purpose of a ball bearing is to reduce rotational friction and support radial and axial loads. It achieves this by using at least two races to contain the balls and transmit...
s. Powder
Powder (substance)
A powder is a dry,thick bulk solid composed of a large number of very fine particles that may flow freely when shaken or tilted. Powders are a special sub-class of granular materials, although the terms powder and granular are sometimes used to distinguish separate classes of material...
s are a special class of granular material due to their small particle size, which makes them more cohesive
Cohesion (chemistry)
Cohesion or cohesive attraction or cohesive force is the action or property of like molecules sticking together, being mutually attractive...
and more easily suspended
Suspension (chemistry)
In chemistry, a suspension is a heterogeneous fluid containing solid particles that are sufficiently large for sedimentation. Usually they must be larger than 1 micrometer. The internal phase is dispersed throughout the external phase through mechanical agitation, with the use of certain...
in a gas
Gas
Gas is one of the three classical states of matter . Near absolute zero, a substance exists as a solid. As heat is added to this substance it melts into a liquid at its melting point , boils into a gas at its boiling point, and if heated high enough would enter a plasma state in which the electrons...
. Granular materials are commercially important in applications as diverse as pharmaceutical industry, agriculture
Agriculture
Agriculture is the cultivation of animals, plants, fungi and other life forms for food, fiber, and other products used to sustain life. Agriculture was the key implement in the rise of sedentary human civilization, whereby farming of domesticated species created food surpluses that nurtured the...
, and energy production. Research into granular materials is thus directly applicable and goes back at least to Charles-Augustin de Coulomb
Charles-Augustin de Coulomb
Charles-Augustin de Coulomb was a French physicist. He is best known for developing Coulomb's law, the definition of the electrostatic force of attraction and repulsion. The [SI unit] of charge, the coulomb, was named after him....
, whose law of friction
Friction
Friction is the force resisting the relative motion of solid surfaces, fluid layers, and/or material elements sliding against each other. There are several types of friction:...
was originally stated for granular materials.
The soldier
Soldier
A soldier is a member of the land component of national armed forces; whereas a soldier hired for service in a foreign army would be termed a mercenary...
/physicist
Physicist
A physicist is a scientist who studies or practices physics. Physicists study a wide range of physical phenomena in many branches of physics spanning all length scales: from sub-atomic particles of which all ordinary matter is made to the behavior of the material Universe as a whole...
Brigadier Ralph Alger Bagnold
Ralph Alger Bagnold
Brigadier Ralph Alger Bagnold, FRS OBE, was the founder and first commander of the British Army's Long Range Desert Group during World War II. He is also generally considered to have been a pioneer of desert exploration, an acclaim earned for his activities during the 1930s...
was an early pioneer of the physics of granular matter and whose book "The Physics of Blown Sand and Desert Dunes" remains an important reference to this day.
According to material scientist Patrick Richard, "Granular materials are ubiquitous in nature
Nature
Nature, in the broadest sense, is equivalent to the natural world, physical world, or material world. "Nature" refers to the phenomena of the physical world, and also to life in general...
and are the second-most manipulated material in industry (the first one is water
Water
Water is a chemical substance with the chemical formula H2O. A water molecule contains one oxygen and two hydrogen atoms connected by covalent bonds. Water is a liquid at ambient conditions, but it often co-exists on Earth with its solid state, ice, and gaseous state . Water also exists in a...
)".
In some sense, granular materials do not constitute a single phase of matter but have characteristics reminiscent of solid
Solid
Solid is one of the three classical states of matter . It is characterized by structural rigidity and resistance to changes of shape or volume. Unlike a liquid, a solid object does not flow to take on the shape of its container, nor does it expand to fill the entire volume available to it like a...
s, liquid
Liquid
Liquid is one of the three classical states of matter . Like a gas, a liquid is able to flow and take the shape of a container. Some liquids resist compression, while others can be compressed. Unlike a gas, a liquid does not disperse to fill every space of a container, and maintains a fairly...
s, or gas
Gas
Gas is one of the three classical states of matter . Near absolute zero, a substance exists as a solid. As heat is added to this substance it melts into a liquid at its melting point , boils into a gas at its boiling point, and if heated high enough would enter a plasma state in which the electrons...
es depending on the average energy per grain. However in each of these states granular materials also exhibit properties which are unique.
Granular materials also exhibit a wide range of pattern forming behaviors when excited (e.g. vibrated or allowed to flow). As such granular materials under excitation can be thought of as an example of a complex system
Complex system
A complex system is a system composed of interconnected parts that as a whole exhibit one or more properties not obvious from the properties of the individual parts....
.
Granular solids
When the average energy of the individual grains is low and the grains are fairly stationary relative to each other, the granular material acts like a solid. In general, stress in a granular solid is not distributed uniformly but is conducted away along so-called force chains which are networks of grains resting on one another. Between these chains are regions of low stress whose grains are shielded for the effects of the grains above by vaultingVault (architecture)
A Vault is an architectural term for an arched form used to provide a space with a ceiling or roof. The parts of a vault exert lateral thrust that require a counter resistance. When vaults are built underground, the ground gives all the resistance required...
and arch
Arch
An arch is a structure that spans a space and supports a load. Arches appeared as early as the 2nd millennium BC in Mesopotamian brick architecture and their systematic use started with the Ancient Romans who were the first to apply the technique to a wide range of structures.-Technical aspects:The...
ing.
Granular liquids
When the granular matter is driven and energy is fed into the system (such as by shaking) such that the grains are not in constant contact with each other, the granular material is said to fluidize and enter a liquid-like state.When freely flowing, granular materials have flow characteristics that roughly resemble those of ordinary Newtonian fluid
Newtonian fluid
A Newtonian fluid is a fluid whose stress versus strain rate curve is linear and passes through the origin. The constant of proportionality is known as the viscosity.-Definition:...
s. However, granular materials dissipate energy quickly, so techniques of statistical mechanics
Statistical mechanics
Statistical mechanics or statistical thermodynamicsThe terms statistical mechanics and statistical thermodynamics are used interchangeably...
that assume conservation of energy are of limited use. Bulk flow characteristics of granular materials do differ from those of homogeneous fluids
Fluid dynamics
In physics, fluid dynamics is a sub-discipline of fluid mechanics that deals with fluid flow—the natural science of fluids in motion. It has several subdisciplines itself, including aerodynamics and hydrodynamics...
in several important ways:
- Shearing or shaking a granular material may result in its becoming inhomogeneous in space and time (see Brazil nut effectBrazil nut effectGranular convection is a phenomenon where granular material subjected to shaking or vibration will exhibit circulation patterns similar to types of fluid convection...
). - Granular materials tend to clog when forced through a constriction (as in a salt cellar)
- A compacted granular material must expand (or dilate) before it can deform (A process known as dilatencyDilatantA dilatant material is one in which viscosity increases with the rate of shear strain. Such a shear thickening fluid, also known by the acronym STF, is an example of a non-Newtonian fluid....
). - TurbulenceTurbulenceIn fluid dynamics, turbulence or turbulent flow is a flow regime characterized by chaotic and stochastic property changes. This includes low momentum diffusion, high momentum convection, and rapid variation of pressure and velocity in space and time...
is almost impossible to achieve in granular materials - Granular materials can support (small) shear stresses indefinitely
- Granular materials are often inhomogeneous and anisotropic
- Granular materials exhibit avalancheAvalancheAn avalanche is a sudden rapid flow of snow down a slope, occurring when either natural triggers or human activity causes a critical escalating transition from the slow equilibrium evolution of the snow pack. Typically occurring in mountainous terrain, an avalanche can mix air and water with the...
s. Avalanching sand is a paradigm example of the process of Self-organized criticalitySelf-organized criticalityIn physics, self-organized criticality is a property of dynamical systems which have a critical point as an attractor. Their macroscopic behaviour thus displays the spatial and/or temporal scale-invariance characteristic of the critical point of a phase transition, but without the need to tune...
.
Granular gases
If the granular material is driven harder such that contacts between the grains become highly infrequent, the material enters a gaseous state. Correspondingly, one can define a granular temperature equal to the root mean square of grain velocity fluctuations that is analogous to thermodynamic temperatureThermodynamic temperature
Thermodynamic temperature is the absolute measure of temperature and is one of the principal parameters of thermodynamics. Thermodynamic temperature is an "absolute" scale because it is the measure of the fundamental property underlying temperature: its null or zero point, absolute zero, is the...
.
Unlike conventional gases granular materials will tend to cluster and clump due to the dissipative nature of the collisions between grains. This clustering has some interesting consequences. For example, if a partially partitioned box of granular materials is vigorously shaken then grains will over time tend to collect in one of the partitions rather than spread evenly into both partitions as would happen in a conventional gas. This effect, known as the granular Maxwell's Demon
Maxwell's demon
In the philosophy of thermal and statistical physics, Maxwell's demon is a thought experiment created by the Scottish physicist James Clerk Maxwell to "show that the Second Law of Thermodynamics has only a statistical certainty." It demonstrates Maxwell's point by hypothetically describing how to...
, does not violate any thermodynamics principles since energy is constantly being lost from the system in the process.
Jamming transition
Granular systems are known to exhibit jammingJamming (physics)
Jamming is the physical process by which some materials, such as granular materials, glasses, foams, and other complex fluids, become rigid with increasing density...
and undergo a jamming transition which is thought of a thermodynamic phase transition to a jammed state.
Lubachevsky-Stillinger algorithm
Lubachevsky-Stillinger algorithm
Lubachevsky-Stillinger algorithm isa numerical procedure that simulates or imitatesa physical process of compressing an assemblyof hard particles...
of jamming allows one to produce simulated jammed granular configurations.
Pattern formation
Excited granular matter is a rich pattern-forming system. Some of the pattern-forming behaviours seen in granular materials are:- The un-mixing or segregation of unlike grains under vibration and flow. An example of this is the so-called Brazil nut effectBrazil nut effectGranular convection is a phenomenon where granular material subjected to shaking or vibration will exhibit circulation patterns similar to types of fluid convection...
where Brazil nuts rise to the top of a packet of mixed nuts when shaken.The cause of this effect is that when shaken, granular (and some other) materials move in a circular pattern. some larger materials (Brazil nuts) get stuck while going down the circle and therefore stay on the top. - The formation of surface patterns in vibrated granular layers. These patterns include but are not limited to stripes, squares and hexagons. These patterns are thought to be composed of fundamental excitations of the surface known as oscillonOscillonIn physics, an oscillon is a soliton-like phenomenon that occurs in granular and other dissipative media. Oscillons in granular media result from vertically vibrating a plate with a layer of uniform particles placed freely on top...
s. - The formation of sand ripplesRipple marksIn geology, ripple marks are sedimentary structures and indicate agitation by water or wind.- Defining ripple cross-laminae and asymmetric ripples :...
, dunes, and sandsheets
Some of the
pattern-forming behaviours
have been possible to reproduce in computer simulations.
There are two main computational approaches to such simulations, time-stepped and event-driven
Event-driven
Event driven may refer to:The term event-driven refers to a methodology that focuses on events and event dependencies.Examples include:* Event-driven finite-state machine, finite-state machine where the transition from one state to another is triggered by an event or a message* Event-driven...
,
the former being the most efficient for a higher density of the material
and the motions of a lower intensity,
and the latter for a lower density of the material
and the motions of a higher intensity.
Acoustic effects
Some beach sands such as those of the aptly named squeaky beachTidal river
A tidal river is a river, or more typically a stretch of a river, whose flow and level is influenced by tides. An example of a tidal river is the portion of the Connecticut River flowing from Windsor Locks, Connecticut, to the Atlantic Ocean. The Brisbane River, which flows into the Pacific Ocean...
exhibit squeaking when walked upon. Some desert dunes are known to exhibit booming during avalanching or when their surface is otherwise disturbed. Granular materials discharged from silos produce loud acoustic emissions in a process known as silo honking.
Granulation
Granulation is the act or process in which primary powderPowder (substance)
A powder is a dry,thick bulk solid composed of a large number of very fine particles that may flow freely when shaken or tilted. Powders are a special sub-class of granular materials, although the terms powder and granular are sometimes used to distinguish separate classes of material...
particles are made to adhere to form larger, multiparticle entities called granules.
External links
- Mester, L., The new physical-mechanical theory of granular materials. 2009, Homonnai, ISBN 96383-43-87
- Pareschi, L., Russo, G., Toscani, G., Modelling and Numerics of Kinetic Dissipative Systems, Nova Science Publishers, New York, 2006.
See also
- Fragile matterFragile matterIn materials science, fragile matter is a granular material that is jammed solid. Everyday examples include beans getting stuck in a hopper in a whole food shop, or milk powder getting jammed in an upside-down bottle. The term was coined by physicist Michael Cates, who asserts that such...
- LiquefactionLiquefactionLiquefaction may refer to:* Liquefaction, the general process of becoming liquid* Soil liquefaction, the process by which sediments become suspended* Liquefaction of gases in physics, chemistry, and thermal engineering* Liquefactive necrosis in pathology...
- Particulate
- Paste (rheology)Paste (rheology)In physics, a paste is a substance that behaves as a solid until a sufficiently large load or stress is applied, at which point it flows like a fluid. In rheological terms, a paste is an example of a Bingham plastic fluid....
- SandcastleSandCastleSandcastle is a documentation generator from Microsoft that automatically produces MSDN style reference documentation out of reflection information of .NET assemblies and XML documentation comments found in the source code of these assemblies...
- Singing Sands