Hot cathode
Encyclopedia
In vacuum tube
s, a hot cathode is a cathode
electrode which emits electron
s due to thermionic emission
. In the accelerator community, these are referred to as thermionic cathodes. (Cf. cold cathode
s, where field electron emission is used and which do not require heating.) The heating element is usually an electrical filament. Hot cathodes typically achieve much higher power density than cold cathodes, emitting significantly more electrons from the same surface area.
Hot cathodes are the main source of electrons in electron gun
s in cathode ray tube
s, electron microscope
s, vacuum tube
s, and fluorescent lamp
s.
. The filament is most often made of tungsten
. With indirectly heated cathodes, the filament is usually called the heater instead. The cathode for indirect heating is usually realized as a nickel tube which surrounds the heater.
The first cathodes consisted simply of a tungsten filament heated to white incandescence (known as bright emitters). Later cathodes are typically covered with an emissive layer, made of a material with lower work function
, which emits electrons more easily than bare tungsten metal, reducing the necessary temperature and lowering the emission of metal ions. Cathodes can be made of pure sintered tungsten as well; tungsten cathodes in the shape of a parabolic
mirror are used in electron beam furnace
s. Thorium
can be added to tungsten to increase its emissivity, due to its lower work function. Some cathodes are made of tantalum
.
; it forms a monoatomic layer of barium
with an extremely low work function. More modern formulations utilize a mixture of barium oxide, strontium oxide
and calcium oxide
. Another standard formulation is barium oxide, calcium oxide, and aluminium oxide
in a 5:3:2 ratio. Thorium oxide is used as well. Oxide-coated cathodes operate at about 800-1000 °C, orange-hot. They are used in most small glass vacuum tubes, but are rarely used in high-power tubes since they are vulnerable to high voltages and oxygen ions, and undergo rapid degradation under such conditions.
For manufacturing convenience, the oxide-coated cathodes are usually coated with carbonate
s, which are then converted to oxides by heating, and then the metal monolayer is formed in a process called electrode activation. The activation may be achieved by microwave heating, direct electric current heating, or electron bombardment while the tube is on the exhausting machine, until the production of gases ceases. The purity of cathode materials is crucial for tube lifetime.
(LaB6) and cerium hexaboride
(CeB6) are used as the coating of some high-current cathodes. Hexaborides show low work function, around 2.5 eV
. They are also resistant to poisoning. Cerium boride cathodes show lower evaporation rate at 1700 K
than lanthanum boride, but it becomes equal at 1850 K and higher. Cerium boride cathodes have one and a half times the lifetime of lanthanum boride, due to its higher resistance to carbon contamination. Boride cathodes are about ten times as "bright" as the tungsten ones and have 10-15 times longer lifetime. They are used e.g. in electron microscope
s, microwave tubes, electron lithography, electron beam welding
, X-Ray tube
s, and free electron laser
s. However these materials tend to be expensive.
Other hexaborides can be employed as well; examples are calcium hexaboride
, strontium hexaboride, barium hexaboride, yttrium hexaboride, gadolinium hexaboride, samarium hexaboride, and thorium hexaboride.
in 1923. A small amount of thorium
is added to the tungsten of the filament. The filament is heated white-hot, at about 2400 °C, and thorium atoms migrate to the surface of the filament and form the emissive layer. Heating the filament in a hydrocarbon atmosphere carburizes the surface and stabilizes the emissive layer. Thoriated filaments can have very long lifetimes and are resistant to high voltages. They are used in nearly all big high-power vacuum tubes for radio transmitters, and in some tubes for hi-fi amplifiers. Their lifetimes tend to be longer than those of oxide cathodes.
is used instead of thorium dioxide. Other replacement materials are lanthanum(III) oxide
, yttrium(III) oxide
, cerium(IV) oxide
, and their mixtures.
s and boride
s of transition metal
s, e.g. zirconium carbide
, hafnium carbide, tantalum carbide
, hafnium diboride
, and their mixtures. Metals from groups IIIB
(scandium
, yttrium
, and some lanthanide
s, often gadolinium
and samarium
) and IVB
(hafnium
, zirconium
, titanium
) are usually chosen.
In addition to tungsten, other refractory metals and alloys can be used, e.g. tantalum
, molybdenum
and rhenium
and their alloys.
A barrier layer of other material can be placed between the base metal and the emission layer, to inhibit chemical reaction between these. The material has to be resistant to high temperatures, have high melting point and very low vapor pressure, and be electrically conductive. Materials used can be e.g. tantalum diboride, titanium diboride, zirconium diboride
, niobium diboride, tantalum carbide
, zirconium carbide
, tantalum nitride, and zirconium nitride
.
in a vacuum tube
or cathode ray tube
. The cathode element had to achieve the required temperature in order for these tubes to function properly. This is why older electronics often needed some time to "warm up" after being powered on; this phenomenon can still be observed in the cathode ray tubes of some modern televisions and computer monitors. The cathode heats to a temperature that causes electron
s to be 'boiled out' of its surface into the evacuated space in the tube, a process called thermionic emission
. The temperature required for modern oxide-coated cathodes is around 800–1000 °C (1,472–1,832 F)
The cathode is usually in the form of a long narrow sheet metal cylinder at the center of the tube. The heater consists of a fine wire or ribbon, made of a high resistance
metal alloy like nichrome
, similar to the heating element
in a toaster
but finer. It runs through the center of the cathode, often being coiled on tiny insulating supports or bent into hairpin-like shapes to give enough surface area to produce the required heat. The ends of the wire are electrically connected to two pins protruding from the end of the tube. When current
passes through the wire it becomes red hot, and the radiated heat strikes the inside surface of the cathode, heating it. The red or orange glow seen coming from operating vacuum tubes is produced by the heater.
There is not much room in the cathode, and the cathode is often built with the heater wire touching it. The inside of the cathode is insulated by a coating of alumina (aluminum oxide). This is not a very good insulator at high temperatures, therefore tubes have a rating for maximum voltage between cathode and heater, usually only 200 - 300 V.
Heaters require a low voltage, high current source of power. Miniature receiving tubes for line-operated equipment used on the order of 0.5 to 4 watts for heater power; high power tubes such as rectifiers or output tubes would have used on the order of 10 to 20 watts, and broadcast transmitter tubes might need a kilowatt or more to heat the cathode.
The voltage required was usually 5 or 6 volts AC
. This was supplied by a separate 'heater winding' on the device's power supply transformer
that also supplied the higher voltages required by the tubes' plates and other electrodes. A more common approach used in transformerless line-operated radio and television receivers such as the All American Five
was to connect all the tube heaters in series across the supply line. Since all the heaters were rated at the same current, they would share voltage according to their heater ratings. Battery-operated radio sets used direct-current power for the heaters, and tubes intended for battery sets were designed to use as little heater power as necessary, to economize on battery replacement. Radio receivers were built with tubes using as little as 50 mA for the heaters, but these types were developed at about the same time as transistors which replaced them. Where leakage or stray fields from the heater circuit could potentially be coupled to the cathode, direct current was sometimes used for heater power. This would eliminate a source of noise in sensitive audio or instrumentation circuits.
The activated electrodes can be destroyed by contact with oxygen
or other chemicals (e.g. aluminium
, or silicate
s), either present as residual gases, entering the tube via leaks, or released by outgassing
or migration from the construction elements. This results in diminished emissivity. This process is known as cathode poisoning. High-reliability tubes had to be developed for the early Whirlwind
computer, with filaments free of traces of silicon
.
Slow degradation of the emissive layer and sudden burning and interruption of the filament are two main failure mode
s of vacuum tubes.
Vacuum tube
In electronics, a vacuum tube, electron tube , or thermionic valve , reduced to simply "tube" or "valve" in everyday parlance, is a device that relies on the flow of electric current through a vacuum...
s, a hot cathode is a cathode
Cathode
A cathode is an electrode through which electric current flows out of a polarized electrical device. Mnemonic: CCD .Cathode polarity is not always negative...
electrode which emits electron
Electron
The electron is a subatomic particle with a negative elementary electric charge. It has no known components or substructure; in other words, it is generally thought to be an elementary particle. An electron has a mass that is approximately 1/1836 that of the proton...
s due to thermionic emission
Thermionic emission
Thermionic emission is the heat-induced flow of charge carriers from a surface or over a potential-energy barrier. This occurs because the thermal energy given to the carrier overcomes the binding potential, also known as work function of the metal. The charge carriers can be electrons or ions, and...
. In the accelerator community, these are referred to as thermionic cathodes. (Cf. cold cathode
Cold cathode
A cold cathode is a cathode used within nixie tubes, gas discharge lamps, discharge tubes, and some types of vacuum tube which is not electrically heated by the circuit to which it is connected...
s, where field electron emission is used and which do not require heating.) The heating element is usually an electrical filament. Hot cathodes typically achieve much higher power density than cold cathodes, emitting significantly more electrons from the same surface area.
Hot cathodes are the main source of electrons in electron gun
Electron gun
An electron gun is an electrical component that produces an electron beam that has a precise kinetic energy and is most often used in television sets and computer displays which use cathode ray tube technology, as well as in other instruments, such as electron microscopes and particle...
s in cathode ray tube
Cathode ray tube
The cathode ray tube is a vacuum tube containing an electron gun and a fluorescent screen used to view images. It has a means to accelerate and deflect the electron beam onto the fluorescent screen to create the images. The image may represent electrical waveforms , pictures , radar targets and...
s, electron microscope
Electron microscope
An electron microscope is a type of microscope that uses a beam of electrons to illuminate the specimen and produce a magnified image. Electron microscopes have a greater resolving power than a light-powered optical microscope, because electrons have wavelengths about 100,000 times shorter than...
s, vacuum tube
Vacuum tube
In electronics, a vacuum tube, electron tube , or thermionic valve , reduced to simply "tube" or "valve" in everyday parlance, is a device that relies on the flow of electric current through a vacuum...
s, and fluorescent lamp
Fluorescent lamp
A fluorescent lamp or fluorescent tube is a gas-discharge lamp that uses electricity to excite mercury vapor. The excited mercury atoms produce short-wave ultraviolet light that then causes a phosphor to fluoresce, producing visible light. A fluorescent lamp converts electrical power into useful...
s.
Principles
Hot cathodes may be either directly heated, where the filament itself is the source of electrons, or indirectly heated, where the filament is electrically insulated from the cathode; this configuration minimizes the introduction of hum when the filament is energized with alternating currentAlternating current
In alternating current the movement of electric charge periodically reverses direction. In direct current , the flow of electric charge is only in one direction....
. The filament is most often made of tungsten
Tungsten
Tungsten , also known as wolfram , is a chemical element with the chemical symbol W and atomic number 74.A hard, rare metal under standard conditions when uncombined, tungsten is found naturally on Earth only in chemical compounds. It was identified as a new element in 1781, and first isolated as...
. With indirectly heated cathodes, the filament is usually called the heater instead. The cathode for indirect heating is usually realized as a nickel tube which surrounds the heater.
The first cathodes consisted simply of a tungsten filament heated to white incandescence (known as bright emitters). Later cathodes are typically covered with an emissive layer, made of a material with lower work function
Work function
In solid-state physics, the work function is the minimum energy needed to remove an electron from a solid to a point immediately outside the solid surface...
, which emits electrons more easily than bare tungsten metal, reducing the necessary temperature and lowering the emission of metal ions. Cathodes can be made of pure sintered tungsten as well; tungsten cathodes in the shape of a parabolic
Parabola
In mathematics, the parabola is a conic section, the intersection of a right circular conical surface and a plane parallel to a generating straight line of that surface...
mirror are used in electron beam furnace
Electron beam furnace
An electron beam furnace is a type of vacuum furnace employing high-energy electron beam in vacuum as the mean for delivery of heat to the material being melted...
s. Thorium
Thorium
Thorium is a natural radioactive chemical element with the symbol Th and atomic number 90. It was discovered in 1828 and named after Thor, the Norse god of thunder....
can be added to tungsten to increase its emissivity, due to its lower work function. Some cathodes are made of tantalum
Tantalum
Tantalum is a chemical element with the symbol Ta and atomic number 73. Previously known as tantalium, the name comes from Tantalus, a character in Greek mythology. Tantalum is a rare, hard, blue-gray, lustrous transition metal that is highly corrosion resistant. It is part of the refractory...
.
Oxide-coated cathodes
A common type is an oxide-coated cathode. The earliest material used was barium oxideBarium oxide
Barium oxide, BaO, is a white hygroscopic compound formed by the burning of barium in oxygen, although it is often formed through the decomposition of other barium salts.It reacts with water to form barium hydroxide.-Uses:...
; it forms a monoatomic layer of barium
Barium
Barium is a chemical element with the symbol Ba and atomic number 56. It is the fifth element in Group 2, a soft silvery metallic alkaline earth metal. Barium is never found in nature in its pure form due to its reactivity with air. Its oxide is historically known as baryta but it reacts with...
with an extremely low work function. More modern formulations utilize a mixture of barium oxide, strontium oxide
Strontium oxide
Strontium oxide or strontia, SrO, is formed when strontium reacts with oxygen. Burning strontium in air results in a mixture of strontium oxide and strontium nitride. It also forms from the decomposition of strontium carbonate SrCO3...
and calcium oxide
Calcium oxide
Calcium oxide , commonly known as quicklime or burnt lime, is a widely used chemical compound. It is a white, caustic, alkaline crystalline solid at room temperature....
. Another standard formulation is barium oxide, calcium oxide, and aluminium oxide
Aluminium oxide
Aluminium oxide is an amphoteric oxide with the chemical formula 23. It is commonly referred to as alumina, or corundum in its crystalline form, as well as many other names, reflecting its widespread occurrence in nature and industry...
in a 5:3:2 ratio. Thorium oxide is used as well. Oxide-coated cathodes operate at about 800-1000 °C, orange-hot. They are used in most small glass vacuum tubes, but are rarely used in high-power tubes since they are vulnerable to high voltages and oxygen ions, and undergo rapid degradation under such conditions.
For manufacturing convenience, the oxide-coated cathodes are usually coated with carbonate
Carbonate
In chemistry, a carbonate is a salt of carbonic acid, characterized by the presence of the carbonate ion, . The name may also mean an ester of carbonic acid, an organic compound containing the carbonate group C2....
s, which are then converted to oxides by heating, and then the metal monolayer is formed in a process called electrode activation. The activation may be achieved by microwave heating, direct electric current heating, or electron bombardment while the tube is on the exhausting machine, until the production of gases ceases. The purity of cathode materials is crucial for tube lifetime.
Boride cathodes
Lanthanum hexaborideLanthanum hexaboride
]]Lanthanum hexaboride is an inorganic chemical, a boride of lanthanum. It is a refractory ceramic material that has a melting point of 2210 °C, and is insoluble in water and hydrochloric acid. It has a low work function and one of the highest electron emissivities known, and is stable in...
(LaB6) and cerium hexaboride
Cerium hexaboride
]Cerium hexaboride is an inorganic chemical, a boride of cerium. It is a refractory ceramic material. It has low work function and one of the highest electron emissivity known, and is stable in vacuum...
(CeB6) are used as the coating of some high-current cathodes. Hexaborides show low work function, around 2.5 eV
Electronvolt
In physics, the electron volt is a unit of energy equal to approximately joule . By definition, it is equal to the amount of kinetic energy gained by a single unbound electron when it accelerates through an electric potential difference of one volt...
. They are also resistant to poisoning. Cerium boride cathodes show lower evaporation rate at 1700 K
Kelvin
The kelvin is a unit of measurement for temperature. It is one of the seven base units in the International System of Units and is assigned the unit symbol K. The Kelvin scale is an absolute, thermodynamic temperature scale using as its null point absolute zero, the temperature at which all...
than lanthanum boride, but it becomes equal at 1850 K and higher. Cerium boride cathodes have one and a half times the lifetime of lanthanum boride, due to its higher resistance to carbon contamination. Boride cathodes are about ten times as "bright" as the tungsten ones and have 10-15 times longer lifetime. They are used e.g. in electron microscope
Electron microscope
An electron microscope is a type of microscope that uses a beam of electrons to illuminate the specimen and produce a magnified image. Electron microscopes have a greater resolving power than a light-powered optical microscope, because electrons have wavelengths about 100,000 times shorter than...
s, microwave tubes, electron lithography, electron beam welding
Electron beam welding
Electron beam welding is a fusion welding process in which a beam of high-velocity electrons is applied to the materials being joined. The workpieces melt as the kinetic energy of the electrons is transformed into heat upon impact, and the filler metal, if used, also melts to form part of the weld...
, X-Ray tube
X-ray tube
An X-ray tube is a vacuum tube that produces X-rays. They are used in X-ray machines. X-rays are part of the electromagnetic spectrum, an ionizing radiation with wavelengths shorter than ultraviolet light...
s, and free electron laser
Free electron laser
A free-electron laser, or FEL, is a laser that shares the same optical properties as conventional lasers such as emitting a beam consisting of coherent electromagnetic radiation which can reach high power, but which uses some very different operating principles to form the beam...
s. However these materials tend to be expensive.
Other hexaborides can be employed as well; examples are calcium hexaboride
Calcium hexaboride
Calcium hexaboride is a compound of calcium and boron with the chemical formula CaB6. It is an important material due to its high electrical conductivity, hardness, chemical stability, and melting point. It is a black, lustrous, chemically inert powder with a low density...
, strontium hexaboride, barium hexaboride, yttrium hexaboride, gadolinium hexaboride, samarium hexaboride, and thorium hexaboride.
Thoriated filaments
Thoriated filaments are another option, discovered in 1914 and made practical by Irving LangmuirIrving Langmuir
Irving Langmuir was an American chemist and physicist. His most noted publication was the famous 1919 article "The Arrangement of Electrons in Atoms and Molecules" in which, building on Gilbert N. Lewis's cubical atom theory and Walther Kossel's chemical bonding theory, he outlined his...
in 1923. A small amount of thorium
Thorium
Thorium is a natural radioactive chemical element with the symbol Th and atomic number 90. It was discovered in 1828 and named after Thor, the Norse god of thunder....
is added to the tungsten of the filament. The filament is heated white-hot, at about 2400 °C, and thorium atoms migrate to the surface of the filament and form the emissive layer. Heating the filament in a hydrocarbon atmosphere carburizes the surface and stabilizes the emissive layer. Thoriated filaments can have very long lifetimes and are resistant to high voltages. They are used in nearly all big high-power vacuum tubes for radio transmitters, and in some tubes for hi-fi amplifiers. Their lifetimes tend to be longer than those of oxide cathodes.
Thorium alternatives
Due to concerns about thorium radioactivity and toxicity, efforts have been made to find alternatives. One of them is zirconiated tungsten, where zirconium dioxideZirconium dioxide
Zirconium dioxide , sometimes known as zirconia , is a white crystalline oxide of zirconium. Its most naturally occurring form, with a monoclinic crystalline structure, is the rare mineral baddeleyite. The high temperature cubic crystalline form is rarely found in nature as mineral tazheranite O2...
is used instead of thorium dioxide. Other replacement materials are lanthanum(III) oxide
Lanthanum(III) oxide
Lanthanum oxide is La2O3, an inorganic compound containing the rare earth element lanthanum and oxygen. It is used to develop ferroelectric materials, and in optical materials.-Properties:...
, yttrium(III) oxide
Yttrium(III) oxide
Yttrium oxide is Y2O3. It is an air-stable, white solid substance. Yttrium oxide is used as a common starting material for both materials science as well as inorganic compounds.-Materials science:...
, cerium(IV) oxide
Cerium(IV) oxide
Cerium oxide, also known as ceric oxide, ceria, cerium oxide or cerium dioxide, is an oxide of the rare earth metal cerium...
, and their mixtures.
Other materials
In addition to the listed oxides and borides, other materials can be used as well. Some examples are carbideCarbide
In chemistry, a carbide is a compound composed of carbon and a less electronegative element. Carbides can be generally classified by chemical bonding type as follows: salt-like, covalent compounds, interstitial compounds, and "intermediate" transition metal carbides...
s and boride
Boride
In chemistry a boride is a chemical compound between boron and a less electronegative element, for example silicon boride . The borides are a very large group of compounds that are generally high melting and are not ionic in nature. Some borides exhibit very useful physical properties. The term...
s of transition metal
Transition metal
The term transition metal has two possible meanings:*The IUPAC definition states that a transition metal is "an element whose atom has an incomplete d sub-shell, or which can give rise to cations with an incomplete d sub-shell." Group 12 elements are not transition metals in this definition.*Some...
s, e.g. zirconium carbide
Zirconium carbide
Zirconium carbide is an extremely hard refractory ceramic material, commercially used in tool bits for cutting tools. It is usually processed by sintering. It has the appearance of a gray metallic powder with cubic crystal structure...
, hafnium carbide, tantalum carbide
Tantalum carbide
Tantalum carbides form a family of binary chemical compounds of tantalum and carbon with the empirical formula TaCx, where x usually varies between 0.4 and 1. They are extremely hard, brittle, refractory ceramic materials with metallic electrical conductivity. They appear as brown-gray powders...
, hafnium diboride
Hafnium diboride
Hafnium diboride is an ultra-high temperature ceramic composed of Hafnium and Boron. It has a melting temperature of about 3250 degrees Celsius. It is an unusual ceramic, having relatively high thermal and electrical conductivities. It is a grey, metallic looking material...
, and their mixtures. Metals from groups IIIB
Group 3 element
The group 3 elements are a group of chemical elements in the periodic table. This group, like other d-block groups, should contain four elements, but it is not agreed what elements belong in the group...
(scandium
Scandium
Scandium is a chemical element with symbol Sc and atomic number 21. A silvery-white metallic transition metal, it has historically been sometimes classified as a rare earth element, together with yttrium and the lanthanoids...
, yttrium
Yttrium
Yttrium is a chemical element with symbol Y and atomic number 39. It is a silvery-metallic transition metal chemically similar to the lanthanides and it has often been classified as a "rare earth element". Yttrium is almost always found combined with the lanthanides in rare earth minerals and is...
, and some lanthanide
Lanthanide
The lanthanide or lanthanoid series comprises the fifteen metallic chemical elements with atomic numbers 57 through 71, from lanthanum through lutetium...
s, often gadolinium
Gadolinium
Gadolinium is a chemical element with the symbol Gd and atomic number 64. It is a silvery-white, malleable and ductile rare-earth metal. It is found in nature only in combined form. Gadolinium was first detected spectroscopically in 1880 by de Marignac who separated its oxide and is credited with...
and samarium
Samarium
Samarium is a chemical element with the symbol Sm, atomic number 62 and atomic weight 150.36. It is a moderately hard silvery metal which readily oxidizes in air. Being a typical member of the lanthanide series, samarium usually assumes the oxidation state +3...
) and IVB
Group 4 element
The Group 4 elements are a group of chemical elements in the periodic table. In the modern IUPAC nomenclature, Group 4 of the periodic table contains titanium , zirconium , hafnium and rutherfordium . This group lies in the d-block of the periodic table...
(hafnium
Hafnium
Hafnium is a chemical element with the symbol Hf and atomic number 72. A lustrous, silvery gray, tetravalent transition metal, hafnium chemically resembles zirconium and is found in zirconium minerals. Its existence was predicted by Dmitri Mendeleev in 1869. Hafnium was the penultimate stable...
, zirconium
Zirconium
Zirconium is a chemical element with the symbol Zr and atomic number 40. The name of zirconium is taken from the mineral zircon. Its atomic mass is 91.224. It is a lustrous, grey-white, strong transition metal that resembles titanium...
, titanium
Titanium
Titanium is a chemical element with the symbol Ti and atomic number 22. It has a low density and is a strong, lustrous, corrosion-resistant transition metal with a silver color....
) are usually chosen.
In addition to tungsten, other refractory metals and alloys can be used, e.g. tantalum
Tantalum
Tantalum is a chemical element with the symbol Ta and atomic number 73. Previously known as tantalium, the name comes from Tantalus, a character in Greek mythology. Tantalum is a rare, hard, blue-gray, lustrous transition metal that is highly corrosion resistant. It is part of the refractory...
, molybdenum
Molybdenum
Molybdenum , is a Group 6 chemical element with the symbol Mo and atomic number 42. The name is from Neo-Latin Molybdaenum, from Ancient Greek , meaning lead, itself proposed as a loanword from Anatolian Luvian and Lydian languages, since its ores were confused with lead ores...
and rhenium
Rhenium
Rhenium is a chemical element with the symbol Re and atomic number 75. It is a silvery-white, heavy, third-row transition metal in group 7 of the periodic table. With an average concentration of 1 part per billion , rhenium is one of the rarest elements in the Earth's crust. The free element has...
and their alloys.
A barrier layer of other material can be placed between the base metal and the emission layer, to inhibit chemical reaction between these. The material has to be resistant to high temperatures, have high melting point and very low vapor pressure, and be electrically conductive. Materials used can be e.g. tantalum diboride, titanium diboride, zirconium diboride
Zirconium diboride
Zirconium diboride is a highly covalent refractory ceramic material with a hexagonal crystal structure. ZrB2 is an Ultra High Temperature Ceramic with a melting point of 3246 °C...
, niobium diboride, tantalum carbide
Tantalum carbide
Tantalum carbides form a family of binary chemical compounds of tantalum and carbon with the empirical formula TaCx, where x usually varies between 0.4 and 1. They are extremely hard, brittle, refractory ceramic materials with metallic electrical conductivity. They appear as brown-gray powders...
, zirconium carbide
Zirconium carbide
Zirconium carbide is an extremely hard refractory ceramic material, commercially used in tool bits for cutting tools. It is usually processed by sintering. It has the appearance of a gray metallic powder with cubic crystal structure...
, tantalum nitride, and zirconium nitride
Zirconium nitride
Zirconium nitride is an inorganic compound found in a variety of uses.-Properties:ZrN applied by the physical vapor deposition coating process is a light gold color similar to elemental gold.ZrN superconducts below .-Uses:...
.
Cathode heater
A cathode heater is a heated wire filament used to heat the cathodeCathode
A cathode is an electrode through which electric current flows out of a polarized electrical device. Mnemonic: CCD .Cathode polarity is not always negative...
in a vacuum tube
Vacuum tube
In electronics, a vacuum tube, electron tube , or thermionic valve , reduced to simply "tube" or "valve" in everyday parlance, is a device that relies on the flow of electric current through a vacuum...
or cathode ray tube
Cathode ray tube
The cathode ray tube is a vacuum tube containing an electron gun and a fluorescent screen used to view images. It has a means to accelerate and deflect the electron beam onto the fluorescent screen to create the images. The image may represent electrical waveforms , pictures , radar targets and...
. The cathode element had to achieve the required temperature in order for these tubes to function properly. This is why older electronics often needed some time to "warm up" after being powered on; this phenomenon can still be observed in the cathode ray tubes of some modern televisions and computer monitors. The cathode heats to a temperature that causes electron
Electron
The electron is a subatomic particle with a negative elementary electric charge. It has no known components or substructure; in other words, it is generally thought to be an elementary particle. An electron has a mass that is approximately 1/1836 that of the proton...
s to be 'boiled out' of its surface into the evacuated space in the tube, a process called thermionic emission
Thermionic emission
Thermionic emission is the heat-induced flow of charge carriers from a surface or over a potential-energy barrier. This occurs because the thermal energy given to the carrier overcomes the binding potential, also known as work function of the metal. The charge carriers can be electrons or ions, and...
. The temperature required for modern oxide-coated cathodes is around 800–1000 °C (1,472–1,832 F)
The cathode is usually in the form of a long narrow sheet metal cylinder at the center of the tube. The heater consists of a fine wire or ribbon, made of a high resistance
Electrical resistance
The electrical resistance of an electrical element is the opposition to the passage of an electric current through that element; the inverse quantity is electrical conductance, the ease at which an electric current passes. Electrical resistance shares some conceptual parallels with the mechanical...
metal alloy like nichrome
Nichrome
Nichrome is a non-magnetic alloy of nickel, chromium, and often iron, usually used as a resistance wire. Patented in 1905, it is the oldest documented form of resistance heating alloy. A common alloy is 80% nickel and 20% chromium, by mass, but there are many others to accommodate various...
, similar to the heating element
Heating element
A heating element converts electricity into heat through the process of Joule heating. Electric current through the element encounters resistance, resulting in heating of the element....
in a toaster
Toaster
The toaster is typically a small electric kitchen appliance designed to toast multiple types of bread products. A typical modern two-slice toaster draws anywhere between 600 and 1200 W and makes toast in 1 to 3 minutes...
but finer. It runs through the center of the cathode, often being coiled on tiny insulating supports or bent into hairpin-like shapes to give enough surface area to produce the required heat. The ends of the wire are electrically connected to two pins protruding from the end of the tube. When current
Electric current
Electric current is a flow of electric charge through a medium.This charge is typically carried by moving electrons in a conductor such as wire...
passes through the wire it becomes red hot, and the radiated heat strikes the inside surface of the cathode, heating it. The red or orange glow seen coming from operating vacuum tubes is produced by the heater.
There is not much room in the cathode, and the cathode is often built with the heater wire touching it. The inside of the cathode is insulated by a coating of alumina (aluminum oxide). This is not a very good insulator at high temperatures, therefore tubes have a rating for maximum voltage between cathode and heater, usually only 200 - 300 V.
Heaters require a low voltage, high current source of power. Miniature receiving tubes for line-operated equipment used on the order of 0.5 to 4 watts for heater power; high power tubes such as rectifiers or output tubes would have used on the order of 10 to 20 watts, and broadcast transmitter tubes might need a kilowatt or more to heat the cathode.
The voltage required was usually 5 or 6 volts AC
Alternating current
In alternating current the movement of electric charge periodically reverses direction. In direct current , the flow of electric charge is only in one direction....
. This was supplied by a separate 'heater winding' on the device's power supply transformer
Transformer
A transformer is a device that transfers electrical energy from one circuit to another through inductively coupled conductors—the transformer's coils. A varying current in the first or primary winding creates a varying magnetic flux in the transformer's core and thus a varying magnetic field...
that also supplied the higher voltages required by the tubes' plates and other electrodes. A more common approach used in transformerless line-operated radio and television receivers such as the All American Five
All American Five
The term All American Five is a colloquial name for mass-produced, superheterodyne radio receivers that used five vacuum tubes in their design. These radio sets were designed to receive amplitude modulation broadcasts in the medium wave band, and were manufactured in the United States from the mid...
was to connect all the tube heaters in series across the supply line. Since all the heaters were rated at the same current, they would share voltage according to their heater ratings. Battery-operated radio sets used direct-current power for the heaters, and tubes intended for battery sets were designed to use as little heater power as necessary, to economize on battery replacement. Radio receivers were built with tubes using as little as 50 mA for the heaters, but these types were developed at about the same time as transistors which replaced them. Where leakage or stray fields from the heater circuit could potentially be coupled to the cathode, direct current was sometimes used for heater power. This would eliminate a source of noise in sensitive audio or instrumentation circuits.
Failure modes
The emissive layers degrade slowly with time, and much more quickly when the cathode is overloaded with too high current. The result is weakened emission and diminished power of the tubes, or brightness of the CRTs.The activated electrodes can be destroyed by contact with oxygen
Oxygen
Oxygen is the element with atomic number 8 and represented by the symbol O. Its name derives from the Greek roots ὀξύς and -γενής , because at the time of naming, it was mistakenly thought that all acids required oxygen in their composition...
or other chemicals (e.g. aluminium
Aluminium
Aluminium or aluminum is a silvery white member of the boron group of chemical elements. It has the symbol Al, and its atomic number is 13. It is not soluble in water under normal circumstances....
, or silicate
Silicate
A silicate is a compound containing a silicon bearing anion. The great majority of silicates are oxides, but hexafluorosilicate and other anions are also included. This article focuses mainly on the Si-O anions. Silicates comprise the majority of the earth's crust, as well as the other...
s), either present as residual gases, entering the tube via leaks, or released by outgassing
Outgassing
Outgassing is the release of a gas that was dissolved, trapped, frozen or absorbed in some material. As an example, research has shown how the concentration of carbon dioxide in the Earth's atmosphere has sometimes been linked to ocean outgassing...
or migration from the construction elements. This results in diminished emissivity. This process is known as cathode poisoning. High-reliability tubes had to be developed for the early Whirlwind
Whirlwind (computer)
The Whirlwind computer was developed at the Massachusetts Institute of Technology. It is the first computer that operated in real time, used video displays for output, and the first that was not simply an electronic replacement of older mechanical systems...
computer, with filaments free of traces of silicon
Silicon
Silicon is a chemical element with the symbol Si and atomic number 14. A tetravalent metalloid, it is less reactive than its chemical analog carbon, the nonmetal directly above it in the periodic table, but more reactive than germanium, the metalloid directly below it in the table...
.
Slow degradation of the emissive layer and sudden burning and interruption of the filament are two main failure mode
Failure mode
Failure causes are defects in design, process, quality, or part application, which are the underlying cause of a failure or which initiate a process which leads to failure. Where failure depends on the user of the product or process, then human error must be considered.-Component failure:A part...
s of vacuum tubes.
Transmitting tube hot cathode characteristics
Material | Operating temperature Operating temperature An operating temperature is the temperature at which an electrical or mechanical device operates. The device will operate effectively within a specified temperature range which varies based on the device function and application context, and ranges from the minimum operating temperature to the... |
Emission efficacy | Specific emission |
---|---|---|---|
Tungsten Tungsten Tungsten , also known as wolfram , is a chemical element with the chemical symbol W and atomic number 74.A hard, rare metal under standard conditions when uncombined, tungsten is found naturally on Earth only in chemical compounds. It was identified as a new element in 1781, and first isolated as... |
2500 K | 5 mA/W | 500 mA/cm2 |
Thoriated tungsten | 2000 K | 100 mA/W | 5 A/cm2 |
Oxide coated | 1100 K | 500 mA/W | 10 A/cm2 |
Barium aluminate | 1300 K | 400 mA/W | 4 A/cm2 |