Magmatic water or juvenile water is water which exists within and in equilibrium with a magma

Magma

Magma is a mixture of molten rock, volatiles and solids that is found beneath the surface of the Earth, and is expected to exist on other terrestrial planets. Besides molten rock, magma may also contain suspended crystals and dissolved gas and sometimes also gas bubbles. Magma often collects in...

 or water rich volatile

Volatiles

In planetary science, volatiles are that group of chemical elements and chemical compounds with low boiling points that are associated with a planet's or moon's crust and/or atmosphere. Examples include nitrogen, water, carbon dioxide, ammonia, hydrogen, and methane, all compounds of C, H, O...

 fluids which are derived from a magma. This magmatic water is released to the atmosphere during a volcanic eruption. Magmatic water may also be released as hydrothermal fluids during the late stages of magmatic crystallization or solidification within the Earth's crust

Crust (geology)

In geology, the crust is the outermost solid shell of a rocky planet or natural satellite, which is chemically distinct from the underlying mantle...

. The crystallization of hydroxyl

Hydroxyl

A hydroxyl is a chemical group containing an oxygen atom covalently bonded with a hydrogen atom. In inorganic chemistry, the hydroxyl group is known as the hydroxide ion, and scientists and reference works generally use these different terms though they refer to the same chemical structure in...

 bearing amphibole

Amphibole

Amphibole is the name of an important group of generally dark-colored rock-forming inosilicate minerals, composed of double chain tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures.-Mineralogy:...

 and mica

Mica

The mica group of sheet silicate minerals includes several closely related materials having highly perfect basal cleavage. All are monoclinic, with a tendency towards pseudohexagonal crystals, and are similar in chemical composition...

 minerals acts to contain part of the magmatic water within a solidified igneous rock

Igneous rock

Igneous rock is one of the three main rock types, the others being sedimentary and metamorphic rock. Igneous rock is formed through the cooling and solidification of magma or lava...

. Ultimate sources of this magmatic water includes water and hydrous minerals in rocks melted during subduction

Subduction

In geology, subduction is the process that takes place at convergent boundaries by which one tectonic plate moves under another tectonic plate, sinking into the Earth's mantle, as the plates converge. These 3D regions of mantle downwellings are known as "Subduction Zones"...

 as well as primordial water brought up from the deep mantle

Mantle (geology)

The mantle is a part of a terrestrial planet or other rocky body large enough to have differentiation by density. The interior of the Earth, similar to the other terrestrial planets, is chemically divided into layers. The mantle is a highly viscous layer between the crust and the outer core....

.

Water in silicate melts

Water has limited solubility

Solubility

Solubility is the property of a solid, liquid, or gaseous chemical substance called solute to dissolve in a solid, liquid, or gaseous solvent to form a homogeneous solution of the solute in the solvent. The solubility of a substance fundamentally depends on the used solvent as well as on...

 in silicate melts ranging from essentially zero at surface pressure to up to as much as 10% at 1100 °C and 5 kbar of pressure for a granitic melt. Solubility is lower for more mafic

Mafic

Mafic is an adjective describing a silicate mineral or rock that is rich in magnesium and iron; the term is a portmanteau of the words "magnesium" and "ferric". Most mafic minerals are dark in color and the relative density is greater than 3. Common rock-forming mafic minerals include olivine,...

 magmas. As the temperature and pressure drop during emplacement and cooling of the magma a separate aqueous phase will exolve. This aqueous phase will be enriched in other volatile and silicate incompatible species such as the metals: copper

Copper

Copper is a chemical element with the symbol Cu and atomic number 29. It is a ductile metal with very high thermal and electrical conductivity. Pure copper is soft and malleable; an exposed surface has a reddish-orange tarnish...

, lead

Lead

Lead is a main-group element in the carbon group with the symbol Pb and atomic number 82. Lead is a soft, malleable poor metal. It is also counted as one of the heavy metals. Metallic lead has a bluish-white color after being freshly cut, but it soon tarnishes to a dull grayish color when exposed...

, zinc

Zinc

Zinc , or spelter , is a metallic chemical element; it has the symbol Zn and atomic number 30. It is the first element in group 12 of the periodic table. Zinc is, in some respects, chemically similar to magnesium, because its ion is of similar size and its only common oxidation state is +2...

, silver

Silver

Silver is a metallic chemical element with the chemical symbol Ag and atomic number 47. A soft, white, lustrous transition metal, it has the highest electrical conductivity of any element and the highest thermal conductivity of any metal...

 and gold

Gold

Gold is a chemical element with the symbol Au and an atomic number of 79. Gold is a dense, soft, shiny, malleable and ductile metal. Pure gold has a bright yellow color and luster traditionally considered attractive, which it maintains without oxidizing in air or water. Chemically, gold is a...

; alkali

Alkali

In chemistry, an alkali is a basic, ionic salt of an alkali metal or alkaline earth metal element. Some authors also define an alkali as a base that dissolves in water. A solution of a soluble base has a pH greater than 7. The adjective alkaline is commonly used in English as a synonym for base,...

s and alkaline earths and others, including: lithium

Lithium

Lithium is a soft, silver-white metal that belongs to the alkali metal group of chemical elements. It is represented by the symbol Li, and it has the atomic number 3. Under standard conditions it is the lightest metal and the least dense solid element. Like all alkali metals, lithium is highly...

, beryllium

Beryllium

Beryllium is the chemical element with the symbol Be and atomic number 4. It is a divalent element which occurs naturally only in combination with other elements in minerals. Notable gemstones which contain beryllium include beryl and chrysoberyl...

, boron

Boron

Boron is the chemical element with atomic number 5 and the chemical symbol B. Boron is a metalloid. Because boron is not produced by stellar nucleosynthesis, it is a low-abundance element in both the solar system and the Earth's crust. However, boron is concentrated on Earth by the...

, rubidium

Rubidium

Rubidium is a chemical element with the symbol Rb and atomic number 37. Rubidium is a soft, silvery-white metallic element of the alkali metal group. Its atomic mass is 85.4678. Elemental rubidium is highly reactive, with properties similar to those of other elements in group 1, such as very rapid...

; and volatiles: fluorine

Fluorine

Fluorine is the chemical element with atomic number 9, represented by the symbol F. It is the lightest element of the halogen column of the periodic table and has a single stable isotope, fluorine-19. At standard pressure and temperature, fluorine is a pale yellow gas composed of diatomic...

, chlorine

Chlorine

Chlorine is the chemical element with atomic number 17 and symbol Cl. It is the second lightest halogen, found in the periodic table in group 17. The element forms diatomic molecules under standard conditions, called dichlorine...

 and carbon dioxide

Carbon dioxide

Carbon dioxide is a naturally occurring chemical compound composed of two oxygen atoms covalently bonded to a single carbon atom...

.

Water in silicate melts at the high temperature and pressure conditions within the crust exists as a supercritical fluid

Supercritical fluid

A supercritical fluid is any substance at a temperature and pressure above its critical point, where distinct liquid and gas phases do not exist. It can effuse through solids like a gas, and dissolve materials like a liquid...

 rather than in a gaseous state (the critical point

Critical point (thermodynamics)

In physical chemistry, thermodynamics, chemistry and condensed matter physics, a critical point, also called a critical state, specifies the conditions at which a phase boundary ceases to exist...

 for water is at 374 °C and 218 bar).

Stable isotope data

Stable isotope

Stable isotope

Stable isotopes are chemical isotopes that may or may not be radioactive, but if radioactive, have half-lives too long to be measured.Only 90 nuclides from the first 40 elements are energetically stable to any kind of decay save proton decay, in theory...

 studies of oxygen and hydrogen in igneous rocks indicate that the oxygen-18

Oxygen-18

Oxygen-18 is a natural, stable isotope of oxygen and one of the environmental isotopes.18O is an important precursor for the production of fluorodeoxyglucose used in positron emission tomography...

, δ¹⁸O, content is approximately 6 - 8 ‰ higher than standard mean ocean water (SMOW) while the deuterium

Deuterium

Deuterium, also called heavy hydrogen, is one of two stable isotopes of hydrogen. It has a natural abundance in Earth's oceans of about one atom in of hydrogen . Deuterium accounts for approximately 0.0156% of all naturally occurring hydrogen in Earth's oceans, while the most common isotope ...

, δ²H, content is 40 to 80 ‰ lower than SMOW. Water in equilibrium with igneous melts should bear the same isotopic signature for oxygen-18 and deuterium. Isotope data on hydrothermal solutions spatially associated with igneous intrusions should reflect this isotopic signature. However, isotopic studies of hydrothermal waters indicate that most bear the isotopic signature of meteoric water

Meteoric water

Meteoric water is a hydrologic term of long standing for water in the ground which originates from precipitation. This includes water from lakes, rivers, and icemelts, which all originate from precipitation indirectly.- Overview :...

. Any magmatic waters in these hydrothermal solutions must have been swamped by the circulating meteoric groundwaters of the environment.

Fluid inclusions

Fluid inclusions

thumb|250px|Trapped in a time capsule the same size as the diameter of a human hair, the ore-forming liquid in this inclusion was so hot and contained so much dissolved solids that when it cooled, crystals of halite, sylvite, gypsum, and hematite formed. As the samples cooled, the fluid shrank more...

are microscopic bubbles of aqueous solutions which were trapped within crystals during crystallization and are considered as relic samples of the mineralizing waters. Analyses of the isotopic content of these trapped bubbles show a wide range of δ¹⁸O and δ²H content. All examined show an enrichment in ¹⁸O and depletion in ²H relative to SMOW and meteoric waters. Fluid inclusion data from a number of ore deposits plot directly on the magmatic water region of an δ¹⁸O vs δ²H plot.