Minium (mineral)
Encyclopedia
Minium is the naturally occurring form of lead tetroxide, Pb2+2Pb4+O4. It is a light to vivid red and may have brown to yellow tints. It typically occurs as scaly to earthy masses. It crystallizes in the tetragonal crystal system
Crystal system
In crystallography, the terms crystal system, crystal family, and lattice system each refer to one of several classes of space groups, lattices, point groups, or crystals...

.

Minium is rare and occurs in lead mineral deposits that have been subjected to severe oxidizing
Redox
Redox reactions describe all chemical reactions in which atoms have their oxidation state changed....

 conditions. It also occurs as a result of mine fires. It occurs associated with galena
Galena
Galena is the natural mineral form of lead sulfide. It is the most important lead ore mineral.Galena is one of the most abundant and widely distributed sulfide minerals. It crystallizes in the cubic crystal system often showing octahedral forms...

, cerussite
Cerussite
Cerussite is a mineral consisting of lead carbonate , and an important ore of lead. The name is from the Latin cerussa, white lead. Cerussa nativa was mentioned by Conrad Gessner in 1565, and in 1832 F. S. Beudant applied the name cruse to the mineral, whilst the present form, cerussite, is due to...

, massicot
Massicot
Massicot is one of the natural mineral forms of lead oxide, PbO. Massicot is the orthorhombic dimorph of the tetragonal form of lead oxide, litharge. It forms soft yellow to reddish-yellow, earthy, scaley masses which are very dense, with a specific gravity of 9.64.It was first described in 1841...

, litharge
Litharge
Litharge is one of the natural mineral forms of lead oxide, PbO. Litharge is a secondary mineral which forms from the oxidation of galena ores. It forms as coatings and encrustations with internal tetragonal crystal structure. It is dimorphous with the orthorhombic form massicot...

, native lead
Lead
Lead is a main-group element in the carbon group with the symbol Pb and atomic number 82. Lead is a soft, malleable poor metal. It is also counted as one of the heavy metals. Metallic lead has a bluish-white color after being freshly cut, but it soon tarnishes to a dull grayish color when exposed...

, wulfenite
Wulfenite
Wulfenite is a lead molybdate mineral with the formula PbMoO4. It can be most often found as thin tabular crystals with a bright orange-red to yellow-orange color, sometimes brown, although the color can be highly variable. In its yellow form it is sometimes called "yellow lead ore".It crystallizes...

 and mimetite
Mimetite
Mimetite, whose name derives from the Greek Μιμητής mimethes, meaning "imitator", is an arsenate mineral which forms as a secondary mineral in lead deposits, usually by the oxidation of galena and arsenopyrite. The name is a reference to mimetite's resemblance to the mineral pyromorphite...

.

It occurs in a variety of worldwide areas in relatively small amounts. It occurs at Langhecke, Hesse
Hesse
Hesse or Hessia is both a cultural region of Germany and the name of an individual German state.* The cultural region of Hesse includes both the State of Hesse and the area known as Rhenish Hesse in the neighbouring Rhineland-Palatinate state...

; Badenweiler
Badenweiler
Badenweiler, a health resort and spa of the Breisgau-Hochschwarzwald district of Baden-Württemberg, Germany, historically in the Markgräflerland. It is 28 kilometers by road and rail from Basel, 10 kilometers from the French border, and 20 kilometers away from Mulhouse...

, Baden-Wurttemberg
Baden-Württemberg
Baden-Württemberg is one of the 16 states of Germany. Baden-Württemberg is in the southwestern part of the country to the east of the Upper Rhine, and is the third largest in both area and population of Germany's sixteen states, with an area of and 10.7 million inhabitants...

; Bleialf
Bleialf
Bleialf is a municipality in the district of Bitburg-Prüm, in Rhineland-Palatinate, western Germany....

, Eifel
Eifel
The Eifel is a low mountain range in western Germany and eastern Belgium. It occupies parts of southwestern North Rhine-Westphalia, northwestern Rhineland-Palatinate and the south of the German-speaking Community of Belgium....

 district; Horhausen
Horhausen
Horhausen is the name of several municipalities in Rhineland-Palatinate:* Horhausen, Altenkirchen* Horhausen, Rhein-Lahn...

, Rhineland-Palatinate
Rhineland-Palatinate
Rhineland-Palatinate is one of the 16 states of the Federal Republic of Germany. It has an area of and about four million inhabitants. The capital is Mainz. English speakers also commonly refer to the state by its German name, Rheinland-Pfalz ....

 in Germany
Germany
Germany , officially the Federal Republic of Germany , is a federal parliamentary republic in Europe. The country consists of 16 states while the capital and largest city is Berlin. Germany covers an area of 357,021 km2 and has a largely temperate seasonal climate...

. It occurs at Mies
Mies
Mies is a municipality in the district of Nyon in the canton of Vaud in Switzerland.It is approximately half-way between Geneva and Nyon. Mies sits on Lake Geneva , which lies to the southeast and is 410m above sea-level. The highest point of Mies is 455m above sea level. The part of Mies touching...

, Slovenia
Slovenia
Slovenia , officially the Republic of Slovenia , is a country in Central and Southeastern Europe touching the Alps and bordering the Mediterranean. Slovenia borders Italy to the west, Croatia to the south and east, Hungary to the northeast, and Austria to the north, and also has a small portion of...

; Leadhills
Leadhills
Leadhills is a village in South Lanarkshire, Scotland, 5¾ miles WSW of Elvanfoot. Population 835. Originally known as Waterhead, It is the second highest village in Scotland after Wanlockhead, lying 395m above sea-level, near the source of Glengonnar Water, an affluent of the River Clyde...

, Lanarkshire
Lanarkshire
Lanarkshire or the County of Lanark ) is a Lieutenancy area, registration county and former local government county in the central Lowlands of Scotland...

, Scotland
Scotland
Scotland is a country that is part of the United Kingdom. Occupying the northern third of the island of Great Britain, it shares a border with England to the south and is bounded by the North Sea to the east, the Atlantic Ocean to the north and west, and the North Channel and Irish Sea to the...

; Castelberg St. Avold, Moselle
Moselle
Moselle is a department in the east of France named after the river Moselle.- History :Moselle is one of the original 83 departments created during the French Revolution on March 4, 1790...

, France
France
The French Republic , The French Republic , The French Republic , (commonly known as France , is a unitary semi-presidential republic in Western Europe with several overseas territories and islands located on other continents and in the Indian, Pacific, and Atlantic oceans. Metropolitan France...

; from Langban
Långban
Långban is a mining area in Värmland in Sweden. It belongs to Filipstad Municipality, with the nearest city being Filipstad, 21 km south. It was systematically mined through 1711-1972, but has traces from the 15th century. It is the birthplace of Swedish-American inventor John EricssonIt has...

, Varmland
Värmland
' is a historical province or landskap in the west of middle Sweden. It borders Västergötland, Dalsland, Dalarna, Västmanland and Närke. It is also bounded by Norway in the west. Latin name versions are Vermelandia and Wermelandia. Although the province's land originally was Götaland, the...

, Sweden
Sweden
Sweden , officially the Kingdom of Sweden , is a Nordic country on the Scandinavian Peninsula in Northern Europe. Sweden borders with Norway and Finland and is connected to Denmark by a bridge-tunnel across the Öresund....

; Sarrabus, Sardinia
Sardinia
Sardinia is the second-largest island in the Mediterranean Sea . It is an autonomous region of Italy, and the nearest land masses are the French island of Corsica, the Italian Peninsula, Sicily, Tunisia and the Spanish Balearic Islands.The name Sardinia is from the pre-Roman noun *sard[],...

, Italy
Italy
Italy , officially the Italian Republic languages]] under the European Charter for Regional or Minority Languages. In each of these, Italy's official name is as follows:;;;;;;;;), is a unitary parliamentary republic in South-Central Europe. To the north it borders France, Switzerland, Austria and...

; near Anarak
Anarak
Anarak is a city in and the capital of Anarak District, in Nain County, Isfahan Province, Iran. At the 2006 census, its population was 1,285, in 462 families. It is situated at an altitude of ....

, Iran
Iran
Iran , officially the Islamic Republic of Iran , is a country in Southern and Western Asia. The name "Iran" has been in use natively since the Sassanian era and came into use internationally in 1935, before which the country was known to the Western world as Persia...

; and Tsumeb
Tsumeb
Tsumeb is a city of 15,000 inhabitants and the largest town in Oshikoto region in northern Namibia. Tsumeb is the home of the world-famous Tsumeb mine, and the "gateway to the north" of Namibia. It is the closest town to the Etosha National Park...

, Namibia
Namibia
Namibia, officially the Republic of Namibia , is a country in southern Africa whose western border is the Atlantic Ocean. It shares land borders with Angola and Zambia to the north, Botswana to the east and South Africa to the south and east. It gained independence from South Africa on 21 March...

. In the USA it is reported from the Jay Gould mine, Alturas County, Idaho
Alturas County, Idaho
Alturas County was a county in Idaho Territory and later the state of Idaho from 1864 to 1895. It covered an area larger than the states of Maryland, New Jersey, and Delaware combined. Most present-day southern Idaho counties were created at least in part from the original Alturas County area...

; the Leadville district, Lake County, Colorado
Lake County, Colorado
Lake County is one of the 64 counties of the State of Colorado of the United States. The highest natural point in Colorado and the entire Rocky Mountains is the summit of Mount Elbert in Lake County at 14,440 feet elevation. The county population was 7,812 at U.S. Census 2000. The county seat...

; in the Tonopah-Belmont mine, Maricopa County, Arizona
Maricopa County, Arizona
-2010:Whereas according to the 2010 U.S. Census Bureau:*73.0% White*5.0% Black*2.1% Native American*3.5% Asian*0.2% Native Hawaiian or Pacific Islander*3.5% Two or more races*12.7% Other races*29.6% Hispanic or Latino -2000:...

. It also occurs in Eschuchapa and Guerrero
Guerrero
Guerrero officially Estado Libre y Soberano de Guerrero is one of the 31 states which, with the Federal District, comprise the 32 Federal Entities of Mexico. It is divided in 81 municipalities and its capital city is Chilpancingo....

, Mexico
Mexico
The United Mexican States , commonly known as Mexico , is a federal constitutional republic in North America. It is bordered on the north by the United States; on the south and west by the Pacific Ocean; on the southeast by Guatemala, Belize, and the Caribbean Sea; and on the east by the Gulf of...

. Good specimens were produced by a mine fire at the Broken Hill mine in New South Wales
New South Wales
New South Wales is a state of :Australia, located in the east of the country. It is bordered by Queensland, Victoria and South Australia to the north, south and west respectively. To the east, the state is bordered by the Tasman Sea, which forms part of the Pacific Ocean. New South Wales...

, Australia
Australia
Australia , officially the Commonwealth of Australia, is a country in the Southern Hemisphere comprising the mainland of the Australian continent, the island of Tasmania, and numerous smaller islands in the Indian and Pacific Oceans. It is the world's sixth-largest country by total area...

.

It was named for the Minius River in northwest Spain
Spain
Spain , officially the Kingdom of Spain languages]] under the European Charter for Regional or Minority Languages. In each of these, Spain's official name is as follows:;;;;;;), is a country and member state of the European Union located in southwestern Europe on the Iberian Peninsula...

. The name was originally applied to cinnabar
Cinnabar
Cinnabar or cinnabarite , is the common ore of mercury.-Word origin:The name comes from κινναβαρι , a Greek word most likely applied by Theophrastus to several distinct substances...

, but after the material was determined to be a coating on the cinnabar, the name minium was applied to the red lead contaminant.
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