Hops
Encyclopedia
Hops are the female flower
clusters (commonly called seed cones or strobiles
), of a hop species, Humulus lupulus
. They are used primarily as a flavoring and stability agent in beer
, to which they impart a bitter, tangy flavor, though hops are also used for various purposes in other beverages and herbal medicine
. Hops were cultivated continuously around the 8th or 9th century AD in Bohemian gardens in the Hallertau
district of Bavaria
and other parts of Europe
. However, the first documented use of hops in beer as a bittering agent is from the eleventh century. Before this period, brewers used a wide variety of bitter herbs and flowers, including dandelion, burdock root
, marigold
, horehound
(the German name for horehound means "mountain hops"), ground ivy, and heather
. Hops are used extensively in brewing for their many purported benefits, including balancing the sweetness of the malt
with bitterness, contributing a variety of desirable flavors and aromas, and having an antibiotic
effect that favors the activity of brewer's yeast over less desirable microorganisms. Historically, it is believed that traditional herb combinations for ales were abandoned when it was noticed that ales made with hops were less prone to spoilage.
The hop plant is a vigorous climbing herbaceous
perennial
, usually trained to grow up strings in a field called a hopfield, hop garden, or hop yard when grown commercially. Many different types of hops are grown by farmers around the world, with different types being used for particular styles of beer.
region of present-day Germany
, although the first mention of the use of hops in brewing in that country was 1079.
Not until the thirteenth century in Germany did hops begin to start threatening the use of gruit
for flavoring. In Britain, hopped beer was first imported from Holland around 1400; but hops were condemned in 1519 as a "wicked and pernicious weed". In 1471, Norwich
, England
, banned use of the plant in the brewing of ale
(beer was the name for fermented malt liquors bittered with hops, until such recent times as the words were used as synonyms), and not until 1524 were hops first grown in southeast England. It was another century before hop cultivation began in the present-day United States, in 1629.
in Germany (which, in 2006, had more hop-growing area than any other country on Earth), the Yakima (Washington) and Willamette
(Oregon
) valleys, and western Canyon County, Idaho (including the communities of Parma
, Wilder
, Greenleaf
, and Notus
). The principal production centres in the UK are in Kent
(which produces Kent Goldings hops) and Worcestershire
. Essentially all of the harvested hops are used in beer making.
Male and female flowers of the hop plant develop on separate plants (dioecious). Because viable seeds are undesirable for brewing beer, only female plants are grown in hopfields which prevents pollination; female plants are propagated vegetatively
or male plants are culled if plants are grown from seeds.
Until mechanisation, the need for massed labor at harvest time meant hop-growing had a big social impact. For example, many of those hop picking in Kent
, a hop region first mechanised in the 1960s, were from eastern areas of London. This provided a break from urban conditions that was spent in the countryside. Whole families would come down on special trains and live in hoppers' huts
and gradients for most of September, even the smallest children helping in the fields.
In Kent, many growers issued their own currency to those doing the labor because of a shortage of small denomination coin of the realm. In some cases, the coins issued, often adorned with fanciful hops images, were themselves quite beautiful.
People also came from Birmingham and other Midlands cities to pick hops in the Malvern
area of Worcestershire. Some photographs have been preserved.
Sonoma County in California
was, pre-mechanization, a major US producer of hops. As in other hop-growing regions, the labor-intensive harvesting work involved large numbers of migrant workers traveling from other parts of the state or elsewhere for the annual hop harvest. During the Great Depression
, many workers were migrant laborers from Oklahoma and the surrounding region who had recently come to California. Others included locals, particularly older school children. Sometimes whole families would work in the harvest. The remnants of this significant hop industry are still noticeable in the form of old hop kilns that survive in Sonoma County. In part because of the hop industry's importance to the county, local Florian Dauenhauer of Santa Rosa
, the seat of Sonoma County, created one of the earliest and most significant hop-harvesting machines but ironically this mechanization helped destroy the local industry. It enabled large-scale mechanized production which moved to larger farms in other areas.
As of 2005, the ten leading countries for hop cultivation (based on reported total production) were these.
before they are used in the brewing process, but are sometimes used to make "wet-hop" beer immediately after a harvest. Hop resins are composed of two main acid
s: alpha and beta acids.
Alpha acid
s have a mild antibiotic
/bacteriostatic effect against Gram-positive
bacteria, and favor the exclusive activity of brewing yeast in the fermentation of beer. Alpha acids are responsible for the bitter flavor in the beer.
Beta acids do not isomerize
during the boil of wort
, and have a negligible effect on beer taste. Instead they contribute to beer's bitter aroma, and high beta acid hop varieties are often added at the end of the wort boil for aroma. Beta acids may oxidize into compounds that can give beer off-flavors of rotten vegetables or cooked corn.
The effect of hops on the finished beer varies by type and use, though there are two main hop types: bittering and aroma. Bittering hops have higher concentrations of alpha acids, and are responsible for the large majority of the bitter flavor of a beer. European (so called "noble") hops typically average 5–9% alpha acids by weight, and the newer American species typically ranging from 8–19% aabw. Aroma hops usually have a lower concentration of alpha acids (~5%) and are the primary contributors of hop aroma and (non-bitter) flavor. Bittering hops are boiled for a longer period of time, typically 60–90 minutes, in order to maximize the isomerization of the alpha acids. They often have inferior aromatic properties, as the aromatic compounds evaporate off during the boil.
The degree of bitterness imparted by hops depends on the degree to which otherwise insoluble alpha acid
s (AAs) are isomer
ized during the boil, and the impact of a given amount of hops is specified in International Bitterness Units (IBUs). Unboiled hops are only mildly bitter. On the other hand, the (non-bitter) flavor and aroma of hops come from the essential oils, which evaporate during the boil.
Aroma hops are typically added to the wort later to prevent the evaporation of the essential oils, to impart "hop taste" (if during the final 30 minutes of boil) or "hop aroma" (if during the final 10 minutes, or less, of boil). Aroma hops are often added after the wort has cooled and while the beer ferments, a technique known as "dry hopping" which contributes to the hop aroma. The four major components of the essential oil of hops are myrcene, humulene
, caryophyllene
, and farnesene
which comprise about 60–80% of the oil for most hop varieties.
Today a substantial amount of "dual-use" hops are used as well. These have high concentrations of alpha acids and good aromatic properties. These can be added to the boil at any time, depending on the desired effect.
Flavors and aromas are described appreciatively using terms which include "grassy", "floral", "citrus", "spicy", "piney," "lemony," and "earthy". Many pale lager
s have fairly low hop influence, while lagers marketed as Pilsener
or brewed in the Czech Republic may have noticeable noble hop aroma. Certain ale
s (particularly the highly-hopped style known as India Pale Ale
, or IPA) can have high levels of hop bitterness.
Undried or "wet" hops are sometimes used.
s are usually brewed with European (often German and Austrian, since 1981 also Czech) noble hop varieties such as Saaz
, Hallertau and Strissel Spalt. British ales use hop varieties such as Fuggles, Goldings and Bullion. North American beers use Cascade hops
, Columbus hops, Centennial hops, Willamette hops and Amarillo hops
.
an cultivar
s, Hallertau, Tettnanger, Spalt, and Saaz
. They are each named for a specific region or city in which they were first grown or primarily grown. They contain high amounts of the hop oil humulene
and low amounts of alpha acids cohumulone and adhumulone, as well as lower amounts of the harsher-tasting beta acids lupulone, colupulone, and adlupulone.
Their low relative bitterness but strong aroma are often distinguishing characteristics of European-style lager
beer
, such as Pilsener
, Dunkel
, and Oktoberfest/Märzen. In beer, they are considered aroma hops (as opposed to bittering hops); see Pilsner Urquell
as a classic example of the Bohemian Pilsener style, which showcases Noble hops.
As with grapes, land where the hops were grown affects the hops' characteristics. Much as Dortmunder beer may only within the EU be labelled "Dortmunder" if it has been brewed in Dortmund
, Noble hops may only officially be considered "Noble" if they were grown in the areas for which the hops varieties were named.
Some consider the English varieties Fuggle and East Kent Goldings to be noble. They are characterized through analysis as having an alpha:beta ratio of 1:1, low alpha-acid levels (2–5%) with a low cohumulone content, low myrcene in the hop oil, high humulene in the oil, a ratio of humulene:caryophyllene above three, and poor storability resulting in them being more prone to oxidation. In reality this means that they have a relatively consistent bittering potential as they age, due to beta-acid oxidation, and a flavor that improves as they age during periods of poor storage.
, a carbonated beverage similar to soda that is popular in Sweden
during December, as well as Malta
, a Latin American soft drink. They are also used for flavor in some blended teas.
in a way similar to valerian
, as a treatment for anxiety, restlessness, and insomnia. A pillow filled with hops is a popular folk remedy for sleeplessness. Hops may be used alone, but more frequently they are combined with other herbs, such as valerian. The relaxing effect of hops may be due, in part, to the specific chemical component dimethylvinyl carbinol
. Hops tend to be unstable when exposed to light or air and lose their potency after a few months' storage.
Toxicity
Dermatitis
sometimes results from harvesting hops. Although few cases require medical treatment, it is estimated that 3% of the workers suffer some type of skin lesions on the face, hands, and legs. Hops are toxic to dogs, resulting in life-threatening hyperthermia.
Flower
A flower, sometimes known as a bloom or blossom, is the reproductive structure found in flowering plants . The biological function of a flower is to effect reproduction, usually by providing a mechanism for the union of sperm with eggs...
clusters (commonly called seed cones or strobiles
Strobilus
A strobilus is a structure present on many land plant species consisting of sporangia-bearing structures densely aggregated along a stem. Strobili are often called cones, but many botanists restrict the use of the term cone to the woody seed strobili of conifers...
), of a hop species, Humulus lupulus
Humulus lupulus
Humulus lupulus is a species of Humulus in the Cannabaceae family.Common hop is a dioecious, perennial herbaceous climbing plant which sends up new shoots in early spring and dies back to the cold-hardy rhizome in autumn...
. They are used primarily as a flavoring and stability agent in beer
Beer
Beer is the world's most widely consumed andprobably oldest alcoholic beverage; it is the third most popular drink overall, after water and tea. It is produced by the brewing and fermentation of sugars, mainly derived from malted cereal grains, most commonly malted barley and malted wheat...
, to which they impart a bitter, tangy flavor, though hops are also used for various purposes in other beverages and herbal medicine
Herbalism
Herbalism is a traditional medicinal or folk medicine practice based on the use of plants and plant extracts. Herbalism is also known as botanical medicine, medical herbalism, herbal medicine, herbology, herblore, and phytotherapy...
. Hops were cultivated continuously around the 8th or 9th century AD in Bohemian gardens in the Hallertau
Hallertau
The Hallertau or Holledau is an area in Bavaria, Germany. At 178 km², it is listed as the largest continuous hop-planting area in the world...
district of Bavaria
Bavaria
Bavaria, formally the Free State of Bavaria is a state of Germany, located in the southeast of Germany. With an area of , it is the largest state by area, forming almost 20% of the total land area of Germany...
and other parts of Europe
Europe
Europe is, by convention, one of the world's seven continents. Comprising the westernmost peninsula of Eurasia, Europe is generally 'divided' from Asia to its east by the watershed divides of the Ural and Caucasus Mountains, the Ural River, the Caspian and Black Seas, and the waterways connecting...
. However, the first documented use of hops in beer as a bittering agent is from the eleventh century. Before this period, brewers used a wide variety of bitter herbs and flowers, including dandelion, burdock root
Burdock
Burdock is any of a group of biennial thistles in the genus Arctium, family Asteraceae. Native to the Old World, several species have been widely introduced worldwide....
, marigold
Calendula
Calendula , pot marigold, is a genus of about 12–20 species of annual or perennial herbaceous plants in the daisy family Asteraceae, native to the area from Macaronesia east through the Mediterranean region to Iran...
, horehound
Horehound
Horehound or hoarhound is a common name applied to two related genera of flowering plants in the family Lamiaceae:*Ballota*MarrubiumSpecifically, it may refer to the following species:*White Horehound or Common Horehound...
(the German name for horehound means "mountain hops"), ground ivy, and heather
Calluna
Calluna vulgaris is the sole species in the genus Calluna in the family Ericaceae. It is a low-growing perennial shrub growing to tall, or rarely to and taller, and is found widely in Europe and Asia Minor on acidic soils in open sunny situations and in moderate shade...
. Hops are used extensively in brewing for their many purported benefits, including balancing the sweetness of the malt
Malt
Malt is germinated cereal grains that have been dried in a process known as "malting". The grains are made to germinate by soaking in water, and are then halted from germinating further by drying with hot air...
with bitterness, contributing a variety of desirable flavors and aromas, and having an antibiotic
Antibiotic
An antibacterial is a compound or substance that kills or slows down the growth of bacteria.The term is often used synonymously with the term antibiotic; today, however, with increased knowledge of the causative agents of various infectious diseases, antibiotic has come to denote a broader range of...
effect that favors the activity of brewer's yeast over less desirable microorganisms. Historically, it is believed that traditional herb combinations for ales were abandoned when it was noticed that ales made with hops were less prone to spoilage.
The hop plant is a vigorous climbing herbaceous
Herbaceous
A herbaceous plant is a plant that has leaves and stems that die down at the end of the growing season to the soil level. They have no persistent woody stem above ground...
perennial
Perennial plant
A perennial plant or simply perennial is a plant that lives for more than two years. The term is often used to differentiate a plant from shorter lived annuals and biennials. The term is sometimes misused by commercial gardeners or horticulturalists to describe only herbaceous perennials...
, usually trained to grow up strings in a field called a hopfield, hop garden, or hop yard when grown commercially. Many different types of hops are grown by farmers around the world, with different types being used for particular styles of beer.
History
The first documented instance of hop cultivation was in 736, in the HallertauHallertau
The Hallertau or Holledau is an area in Bavaria, Germany. At 178 km², it is listed as the largest continuous hop-planting area in the world...
region of present-day Germany
Germany
Germany , officially the Federal Republic of Germany , is a federal parliamentary republic in Europe. The country consists of 16 states while the capital and largest city is Berlin. Germany covers an area of 357,021 km2 and has a largely temperate seasonal climate...
, although the first mention of the use of hops in brewing in that country was 1079.
Not until the thirteenth century in Germany did hops begin to start threatening the use of gruit
Gruit
Gruit is an old-fashioned herb mixture used for bittering and flavoring beer, popular before the extensive use of hops. Gruit or grut ale may also refer to the beverage produced using gruit....
for flavoring. In Britain, hopped beer was first imported from Holland around 1400; but hops were condemned in 1519 as a "wicked and pernicious weed". In 1471, Norwich
Norwich
Norwich is a city in England. It is the regional administrative centre and county town of Norfolk. During the 11th century, Norwich was the largest city in England after London, and one of the most important places in the kingdom...
, England
England
England is a country that is part of the United Kingdom. It shares land borders with Scotland to the north and Wales to the west; the Irish Sea is to the north west, the Celtic Sea to the south west, with the North Sea to the east and the English Channel to the south separating it from continental...
, banned use of the plant in the brewing of ale
Ale
Ale is a type of beer brewed from malted barley using a warm fermentation with a strain of brewers' yeast. The yeast will ferment the beer quickly, giving it a sweet, full bodied and fruity taste...
(beer was the name for fermented malt liquors bittered with hops, until such recent times as the words were used as synonyms), and not until 1524 were hops first grown in southeast England. It was another century before hop cultivation began in the present-day United States, in 1629.
World production
Important production centers are the HallertauHallertau
The Hallertau or Holledau is an area in Bavaria, Germany. At 178 km², it is listed as the largest continuous hop-planting area in the world...
in Germany (which, in 2006, had more hop-growing area than any other country on Earth), the Yakima (Washington) and Willamette
Willamette Valley
The Willamette Valley is the most populated region in the state of Oregon of the United States. Located in the state's northwest, the region is surrounded by tall mountain ranges to the east, west and south and the valley's floor is broad, flat and fertile because of Ice Age conditions...
(Oregon
Oregon
Oregon is a state in the Pacific Northwest region of the United States. It is located on the Pacific coast, with Washington to the north, California to the south, Nevada on the southeast and Idaho to the east. The Columbia and Snake rivers delineate much of Oregon's northern and eastern...
) valleys, and western Canyon County, Idaho (including the communities of Parma
Parma
Parma is a city in the Italian region of Emilia-Romagna famous for its ham, its cheese, its architecture and the fine countryside around it. This is the home of the University of Parma, one of the oldest universities in the world....
, Wilder
Wilder, Idaho
Wilder is a city in Canyon County, Idaho, United States. The population was 1,462 at the 2000 census. The home of former Idaho State Governor Phil Batt, Wilder is primarily an agricultural community, with onions, hops, seed corn, beans and alfalfa seed among the major crops...
, Greenleaf
Greenleaf, Idaho
Greenleaf is a city in Canyon County, Idaho, United States. The population was 862 at the 2000 census. Named after Quaker poet and abolitionist John Greenleaf Whittier.Greenleaf is part of the Boise City–Nampa, Idaho Metropolitan Statistical Area....
, and Notus
Notus, Idaho
Notus is a city in Canyon County, Idaho, United States. The population was 458 at the 2000 census. It is part of the Boise City–Nampa, Idaho Metropolitan Statistical Area.-Geography:Notus is located at ....
). The principal production centres in the UK are in Kent
Kent
Kent is a county in southeast England, and is one of the home counties. It borders East Sussex, Surrey and Greater London and has a defined boundary with Essex in the middle of the Thames Estuary. The ceremonial county boundaries of Kent include the shire county of Kent and the unitary borough of...
(which produces Kent Goldings hops) and Worcestershire
Worcestershire
Worcestershire is a non-metropolitan county, established in antiquity, located in the West Midlands region of England. For Eurostat purposes it is a NUTS 3 region and is one of three counties that comprise the "Herefordshire, Worcestershire and Warwickshire" NUTS 2 region...
. Essentially all of the harvested hops are used in beer making.
Methods
Hops are a climbing plant. They are trained up strings or wires which support the plants and allow them significantly greater growth with the same sunlight profile. Energy that would have been required to build structural cells is also freed for crop growth.Male and female flowers of the hop plant develop on separate plants (dioecious). Because viable seeds are undesirable for brewing beer, only female plants are grown in hopfields which prevents pollination; female plants are propagated vegetatively
Vegetative reproduction
Vegetative reproduction is a form of asexual reproduction in plants. It is a process by which new individuals arise without production of seeds or spores...
or male plants are culled if plants are grown from seeds.
Until mechanisation, the need for massed labor at harvest time meant hop-growing had a big social impact. For example, many of those hop picking in Kent
Kent
Kent is a county in southeast England, and is one of the home counties. It borders East Sussex, Surrey and Greater London and has a defined boundary with Essex in the middle of the Thames Estuary. The ceremonial county boundaries of Kent include the shire county of Kent and the unitary borough of...
, a hop region first mechanised in the 1960s, were from eastern areas of London. This provided a break from urban conditions that was spent in the countryside. Whole families would come down on special trains and live in hoppers' huts
Hopper hut
A hopper hut was a form of temporary accommodation provided for hop-pickers on English farms in the 19th and 20th centuries.-Background:thumb|Hopper huts at Grange Farm, TonbridgeBefore the days of mechanised farming, hop picking was a labour-intensive process, requiring a vastly greater number of...
and gradients for most of September, even the smallest children helping in the fields.
In Kent, many growers issued their own currency to those doing the labor because of a shortage of small denomination coin of the realm. In some cases, the coins issued, often adorned with fanciful hops images, were themselves quite beautiful.
People also came from Birmingham and other Midlands cities to pick hops in the Malvern
Malvern, Worcestershire
Malvern is a town and civil parish in Worcestershire, England, governed by Malvern Town Council. As of the 2001 census it has a population of 28,749, and includes the historical settlement and commercial centre of Great Malvern on the steep eastern flank of the Malvern Hills, and the former...
area of Worcestershire. Some photographs have been preserved.
Sonoma County in California
California
California is a state located on the West Coast of the United States. It is by far the most populous U.S. state, and the third-largest by land area...
was, pre-mechanization, a major US producer of hops. As in other hop-growing regions, the labor-intensive harvesting work involved large numbers of migrant workers traveling from other parts of the state or elsewhere for the annual hop harvest. During the Great Depression
Great Depression
The Great Depression was a severe worldwide economic depression in the decade preceding World War II. The timing of the Great Depression varied across nations, but in most countries it started in about 1929 and lasted until the late 1930s or early 1940s...
, many workers were migrant laborers from Oklahoma and the surrounding region who had recently come to California. Others included locals, particularly older school children. Sometimes whole families would work in the harvest. The remnants of this significant hop industry are still noticeable in the form of old hop kilns that survive in Sonoma County. In part because of the hop industry's importance to the county, local Florian Dauenhauer of Santa Rosa
Santa Rosa, California
Santa Rosa is the county seat of Sonoma County, California, United States. The 2010 census reported a population of 167,815. Santa Rosa is the largest city in California's Wine Country and fifth largest city in the San Francisco Bay Area, after San Jose, San Francisco, Oakland, and Fremont and 26th...
, the seat of Sonoma County, created one of the earliest and most significant hop-harvesting machines but ironically this mechanization helped destroy the local industry. It enabled large-scale mechanized production which moved to larger farms in other areas.
As of 2005, the ten leading countries for hop cultivation (based on reported total production) were these.
Hop producing country | Hop output in metric tonnes (t) |
---|---|
Germany | 34,438 |
United States | 23,494 |
Mainland China | 10,576 |
Czech Republic | 7,831 |
Poland | 3,414 |
Slovenia | 2,539 |
United Kingdom | 1,693 |
Spain | 1,537 |
Ukraine | 1,474 |
Early Modern France | 1,372 |
Albania | 1,000 |
New Zealand | 900 |
Brewing
Hops are usually dried in an oast houseOast house
An oast, oast house or hop kiln is a building designed for kilning hops as part of the brewing process. They can be found in most hop-growing areas and are often good examples of vernacular architecture...
before they are used in the brewing process, but are sometimes used to make "wet-hop" beer immediately after a harvest. Hop resins are composed of two main acid
Acid
An acid is a substance which reacts with a base. Commonly, acids can be identified as tasting sour, reacting with metals such as calcium, and bases like sodium carbonate. Aqueous acids have a pH of less than 7, where an acid of lower pH is typically stronger, and turn blue litmus paper red...
s: alpha and beta acids.
Alpha acid
Alpha acid
Alpha acids are a class of compounds primarily of importance to the production of beer. They are found in the resin glands of the flowers of the hop plant and are the source of hop bitterness. Alpha acids may be isomerized to form iso-alpha acids by the application of heat in solution...
s have a mild antibiotic
Antibiotic
An antibacterial is a compound or substance that kills or slows down the growth of bacteria.The term is often used synonymously with the term antibiotic; today, however, with increased knowledge of the causative agents of various infectious diseases, antibiotic has come to denote a broader range of...
/bacteriostatic effect against Gram-positive
Gram-positive
Gram-positive bacteria are those that are stained dark blue or violet by Gram staining. This is in contrast to Gram-negative bacteria, which cannot retain the crystal violet stain, instead taking up the counterstain and appearing red or pink...
bacteria, and favor the exclusive activity of brewing yeast in the fermentation of beer. Alpha acids are responsible for the bitter flavor in the beer.
Beta acids do not isomerize
Isomerisation
In chemistry isomerisation is the process by which one molecule is transformed into another molecule which has exactly the same atoms, but the atoms are rearranged e.g. A-B-C → B-A-C . In some molecules and under some conditions, isomerisation occurs spontaneously...
during the boil of wort
Wort (brewing)
Wort, , is the liquid extracted from the mashing process during the brewing of beer or whisky. Wort contains the sugars that will be fermented by the brewing yeast to produce alcohol.- Production :...
, and have a negligible effect on beer taste. Instead they contribute to beer's bitter aroma, and high beta acid hop varieties are often added at the end of the wort boil for aroma. Beta acids may oxidize into compounds that can give beer off-flavors of rotten vegetables or cooked corn.
The effect of hops on the finished beer varies by type and use, though there are two main hop types: bittering and aroma. Bittering hops have higher concentrations of alpha acids, and are responsible for the large majority of the bitter flavor of a beer. European (so called "noble") hops typically average 5–9% alpha acids by weight, and the newer American species typically ranging from 8–19% aabw. Aroma hops usually have a lower concentration of alpha acids (~5%) and are the primary contributors of hop aroma and (non-bitter) flavor. Bittering hops are boiled for a longer period of time, typically 60–90 minutes, in order to maximize the isomerization of the alpha acids. They often have inferior aromatic properties, as the aromatic compounds evaporate off during the boil.
The degree of bitterness imparted by hops depends on the degree to which otherwise insoluble alpha acid
Alpha acid
Alpha acids are a class of compounds primarily of importance to the production of beer. They are found in the resin glands of the flowers of the hop plant and are the source of hop bitterness. Alpha acids may be isomerized to form iso-alpha acids by the application of heat in solution...
s (AAs) are isomer
Isomer
In chemistry, isomers are compounds with the same molecular formula but different structural formulas. Isomers do not necessarily share similar properties, unless they also have the same functional groups. There are many different classes of isomers, like stereoisomers, enantiomers, geometrical...
ized during the boil, and the impact of a given amount of hops is specified in International Bitterness Units (IBUs). Unboiled hops are only mildly bitter. On the other hand, the (non-bitter) flavor and aroma of hops come from the essential oils, which evaporate during the boil.
Aroma hops are typically added to the wort later to prevent the evaporation of the essential oils, to impart "hop taste" (if during the final 30 minutes of boil) or "hop aroma" (if during the final 10 minutes, or less, of boil). Aroma hops are often added after the wort has cooled and while the beer ferments, a technique known as "dry hopping" which contributes to the hop aroma. The four major components of the essential oil of hops are myrcene, humulene
Humulene
Humulene, also known as α-humulene or α-caryophyllene, is a naturally occurring monocyclic sesquiterpene, which is a terpenoid consisting of 3 isoprene units. It is found in the essential oils of Humulus lupulus from which it derives its name. It is an isomer of β-caryophyllene, and the two are...
, caryophyllene
Caryophyllene
Caryophyllene , or -β-caryophyllene, is a natural bicyclic sesquiterpene that is a constituent of many essential oils, especially clove oil, the oil from the stems and flowers of Syzygium aromaticum , the essential oil of hemp Cannabis sativa, rosemary Rosmarinus oficinalis, and hops...
, and farnesene
Farnesene
The term farnesene refers to a set of six closely related chemical compounds which all are sesquiterpenes. α-Farnesene and β-farnesene are isomers, differing by the location of one double bond. α-Farnesene is 3,7,11-trimethyl-1,3,6,10-dodecatetraene and β-farnesene is...
which comprise about 60–80% of the oil for most hop varieties.
Today a substantial amount of "dual-use" hops are used as well. These have high concentrations of alpha acids and good aromatic properties. These can be added to the boil at any time, depending on the desired effect.
Flavors and aromas are described appreciatively using terms which include "grassy", "floral", "citrus", "spicy", "piney," "lemony," and "earthy". Many pale lager
Pale lager
Pale lager is a very pale to golden-coloured beer with a well attenuated body and a varying degree of noble hop bitterness. The brewing process for this beer developed in the mid 19th century when Gabriel Sedlmayr took pale ale brewing techniques back to the Spaten Brewery in Germany and applied it...
s have fairly low hop influence, while lagers marketed as Pilsener
Pilsener
Pilsner is a type of pale lager. It takes its name from the city of Pilsen , Bohemia, in today's Czech Republic, where it has been developed since 1842, when a bottom-fermented beer was first produced. The original Pilsner Urquell beer is produced there today.-Origin:Until the mid-1840s, most ...
or brewed in the Czech Republic may have noticeable noble hop aroma. Certain ale
Ale
Ale is a type of beer brewed from malted barley using a warm fermentation with a strain of brewers' yeast. The yeast will ferment the beer quickly, giving it a sweet, full bodied and fruity taste...
s (particularly the highly-hopped style known as India Pale Ale
India Pale Ale
India Pale Ale or IPA is a style of beer within the broader category of pale ale. It was first brewed in England in the 19th century.The first known use of the expression "India pale ale" comes from an advertisement in the Liverpool Mercury newspaper published January 30, 1835...
, or IPA) can have high levels of hop bitterness.
Undried or "wet" hops are sometimes used.
Hop varieties
Particular hop varieties are associated with beer regions and styles, for example pale lagerPale lager
Pale lager is a very pale to golden-coloured beer with a well attenuated body and a varying degree of noble hop bitterness. The brewing process for this beer developed in the mid 19th century when Gabriel Sedlmayr took pale ale brewing techniques back to the Spaten Brewery in Germany and applied it...
s are usually brewed with European (often German and Austrian, since 1981 also Czech) noble hop varieties such as Saaz
Saaz hops
Saaz is a "noble" variety of hops.It was named after the Czech city of Žatec . This hop is used extensively in Bohemia to flavor beer styles such as the Czech pilsener.Saaz hops accounted for more than 2/3 of total 2009 hop production in the Czech Republic....
, Hallertau and Strissel Spalt. British ales use hop varieties such as Fuggles, Goldings and Bullion. North American beers use Cascade hops
Cascade hops
Cascade is one of the many varieties of hops. Cascade hops are the most widely used hops by craft breweries in the USA.-History:Cascade is a variety of hop developed in the U.S.D.A. breeding program in Oregon at Oregon State University and released as a U.S. aroma variety in 1972...
, Columbus hops, Centennial hops, Willamette hops and Amarillo hops
Amarillo hops
Amarillo is an aroma variety of hops. The Amarillo variety, designated VGXP01 c.v., was discovered and introduced by Virgil Gamache Farms Inc. in Washington State...
.
Noble hops
The term noble hops traditionally refers to four varieties of hop which are low in bitterness and high in aroma. They are the central EuropeCentral Europe
Central Europe or alternatively Middle Europe is a region of the European continent lying between the variously defined areas of Eastern and Western Europe...
an cultivar
Cultivar
A cultivar'Cultivar has two meanings as explained under Formal definition. When used in reference to a taxon, the word does not apply to an individual plant but to all those plants sharing the unique characteristics that define the cultivar. is a plant or group of plants selected for desirable...
s, Hallertau, Tettnanger, Spalt, and Saaz
Saaz hops
Saaz is a "noble" variety of hops.It was named after the Czech city of Žatec . This hop is used extensively in Bohemia to flavor beer styles such as the Czech pilsener.Saaz hops accounted for more than 2/3 of total 2009 hop production in the Czech Republic....
. They are each named for a specific region or city in which they were first grown or primarily grown. They contain high amounts of the hop oil humulene
Humulene
Humulene, also known as α-humulene or α-caryophyllene, is a naturally occurring monocyclic sesquiterpene, which is a terpenoid consisting of 3 isoprene units. It is found in the essential oils of Humulus lupulus from which it derives its name. It is an isomer of β-caryophyllene, and the two are...
and low amounts of alpha acids cohumulone and adhumulone, as well as lower amounts of the harsher-tasting beta acids lupulone, colupulone, and adlupulone.
Their low relative bitterness but strong aroma are often distinguishing characteristics of European-style lager
Lager
Lager is a type of beer made from malted barley that is brewed and stored at low temperatures. There are many types of lager; pale lager is the most widely-consumed and commercially available style of beer in the world; Pilsner, Bock, Dortmunder Export and Märzen are all styles of lager...
beer
Beer
Beer is the world's most widely consumed andprobably oldest alcoholic beverage; it is the third most popular drink overall, after water and tea. It is produced by the brewing and fermentation of sugars, mainly derived from malted cereal grains, most commonly malted barley and malted wheat...
, such as Pilsener
Pilsener
Pilsner is a type of pale lager. It takes its name from the city of Pilsen , Bohemia, in today's Czech Republic, where it has been developed since 1842, when a bottom-fermented beer was first produced. The original Pilsner Urquell beer is produced there today.-Origin:Until the mid-1840s, most ...
, Dunkel
Dunkel
Dunkel, or Dunkles, is a dark German beer. Dunkel is the German word meaning dark, and dunkel beers typically range in colour from amber to dark reddish brown. They are characterized by their smooth malty flavour....
, and Oktoberfest/Märzen. In beer, they are considered aroma hops (as opposed to bittering hops); see Pilsner Urquell
Pilsner Urquell
Plzeňský Prazdroj , known better by its German name Pilsner Urquell , is a bottom-fermented beer produced since 1842 in Pilsen, part of today's Czech Republic. Pilsner Urquell was the first pilsner beer in the world...
as a classic example of the Bohemian Pilsener style, which showcases Noble hops.
As with grapes, land where the hops were grown affects the hops' characteristics. Much as Dortmunder beer may only within the EU be labelled "Dortmunder" if it has been brewed in Dortmund
Dortmund
Dortmund is a city in Germany. It is located in the Bundesland of North Rhine-Westphalia, in the Ruhr area. Its population of 585,045 makes it the 7th largest city in Germany and the 34th largest in the European Union....
, Noble hops may only officially be considered "Noble" if they were grown in the areas for which the hops varieties were named.
Some consider the English varieties Fuggle and East Kent Goldings to be noble. They are characterized through analysis as having an alpha:beta ratio of 1:1, low alpha-acid levels (2–5%) with a low cohumulone content, low myrcene in the hop oil, high humulene in the oil, a ratio of humulene:caryophyllene above three, and poor storability resulting in them being more prone to oxidation. In reality this means that they have a relatively consistent bittering potential as they age, due to beta-acid oxidation, and a flavor that improves as they age during periods of poor storage.
- Hallertau or Hallertauer–The original German lager hop; named after HallertauHallertauThe Hallertau or Holledau is an area in Bavaria, Germany. At 178 km², it is listed as the largest continuous hop-planting area in the world...
or Holledau region in central Bavaria. Due to susceptibility to crop disease, it was largely replaced by HersbruckHersbruckHersbruck is a small town in Middle Franconia, Bavaria, Germany, belonging to the district Nürnberger Land. Famous for the late-gothic artwork of the Hersbruck altar, the "Hirtenmuseum" and the beautiful landscape of the "Hersbrucker Schweiz".-History:...
er in the 1970s and 1980s. (Alpha acid 3.5–5.5% / beta acid 3–4%) - Saaz–Noble hop used extensively in Bohemia to flavor pale Czech lagers such as Pilsner UrquellPilsner UrquellPlzeňský Prazdroj , known better by its German name Pilsner Urquell , is a bottom-fermented beer produced since 1842 in Pilsen, part of today's Czech Republic. Pilsner Urquell was the first pilsner beer in the world...
. Soft aroma and bitterness. (Alpha acid 3–4.5% /Beta acid 3–4.5%) - Spalt–Traditional German noble hop from the SpaltSpaltSpalt is a town in the district of Roth, in Bavaria, Germany. It is situated 19 km southwest of Schwabach. The city of Spalt is famous for its growing of hops for beer.-Geography:...
er region south of Nuremberg. With a delicate, spicy aroma. (Alpha acid 4–5% / beta acid 4–5%) - Tettnang–Comes from TettnangTettnangTettnang is a town in the Bodensee district in southern Baden-Württemberg in a region of Germany known as Swabia.It lies 7 kilometers from Lake Constance. The region produces significant quantities of hops, an ingredient of beer, and ships them to breweries throughout the world.-History:Tettinang...
, a small town in southern Baden-WürttembergBaden-WürttembergBaden-Württemberg is one of the 16 states of Germany. Baden-Württemberg is in the southwestern part of the country to the east of the Upper Rhine, and is the third largest in both area and population of Germany's sixteen states, with an area of and 10.7 million inhabitants...
in GermanyGermanyGermany , officially the Federal Republic of Germany , is a federal parliamentary republic in Europe. The country consists of 16 states while the capital and largest city is Berlin. Germany covers an area of 357,021 km2 and has a largely temperate seasonal climate...
. The region produces significant quantities of hops, and ships them to breweriesBreweryA brewery is a dedicated building for the making of beer, though beer can be made at home, and has been for much of beer's history. A company which makes beer is called either a brewery or a brewing company....
throughout the world. Noble German dual use hop used in European pale lagers, sometimes with Hallertau. Soft bitterness. (Alpha Acid 3.5–5.5% / Beta Acid 3.5–5.5%)
Beverages
The only major commercial use for hops is in beer, although hops are also an ingredient in JulmustJulmust
Julmust is a soft drink that is mainly consumed in Sweden around Christmas. During the rest of the year it is usually hard to find in stores, but sometimes it is sold at other times of the year under the name must. At Easter the name is påskmust ...
, a carbonated beverage similar to soda that is popular in Sweden
Sweden
Sweden , officially the Kingdom of Sweden , is a Nordic country on the Scandinavian Peninsula in Northern Europe. Sweden borders with Norway and Finland and is connected to Denmark by a bridge-tunnel across the Öresund....
during December, as well as Malta
Malta (soft drink)
Malta, young beer, Children's beer or wheat soda is a type of soft drink. It is a carbonated malt beverage, meaning it is brewed from barley, hops, and water much like beer; corn and caramel color may also be added...
, a Latin American soft drink. They are also used for flavor in some blended teas.
Medicinal
Hops are also used in herbal medicineHerbalism
Herbalism is a traditional medicinal or folk medicine practice based on the use of plants and plant extracts. Herbalism is also known as botanical medicine, medical herbalism, herbal medicine, herbology, herblore, and phytotherapy...
in a way similar to valerian
Valerian (herb)
Valerian is a hardy perennial flowering plant, with heads of sweetly scented pink or white flowers which bloom in the summer months. Valerian flower extracts were used as a perfume in the sixteenth century....
, as a treatment for anxiety, restlessness, and insomnia. A pillow filled with hops is a popular folk remedy for sleeplessness. Hops may be used alone, but more frequently they are combined with other herbs, such as valerian. The relaxing effect of hops may be due, in part, to the specific chemical component dimethylvinyl carbinol
2-Methyl-2-butanol
2-Methyl-2-butanol, also known as tert-amyl alcohol or amylene hydrate, is one of the isomers of amyl alcohol. It is a clear, colorless liquid with a strong odor of peppermint or camphor. In humans it possesses sedative, hypnotic, and anticonvulsant effects similar to ethanol through ingestion or...
. Hops tend to be unstable when exposed to light or air and lose their potency after a few months' storage.
Toxicity
Dermatitis
Dermatitis
-Etymology:Dermatitis derives from Greek derma "skin" + -itis "inflammation" and genetic disorder.-Terminology:There are several different types of dermatitis. The different kinds usually have in common an allergic reaction to specific allergens. The term may describe eczema, which is also called...
sometimes results from harvesting hops. Although few cases require medical treatment, it is estimated that 3% of the workers suffer some type of skin lesions on the face, hands, and legs. Hops are toxic to dogs, resulting in life-threatening hyperthermia.
See also
- GruitGruitGruit is an old-fashioned herb mixture used for bittering and flavoring beer, popular before the extensive use of hops. Gruit or grut ale may also refer to the beverage produced using gruit....
- Mugwort a herb historically used as a bitter in beer production
- Rhamnus prinoidesRhamnus prinoidesRhamnus prinioides, the Shiny-leaf Buckthorn, is an African shrub or small tree in the family Rhamnaceae. It was first described by French botanist Charles Louis L'Héritier de Brutelle in 1789.-Description:...
- Oast houseOast houseAn oast, oast house or hop kiln is a building designed for kilning hops as part of the brewing process. They can be found in most hop-growing areas and are often good examples of vernacular architecture...
- IsohumuloneIsohumuloneIsohumulones are compounds that contribute to the bitter taste of beer. They are in the class of compounds known as iso-alpha acids. The bitterness of beer is measured according to the International Bitterness Units scale, with one IBU corresponding to 1 part per million of isohumulone...
- XanthohumolXanthohumolXanthohumol is a prenylated chalconoid from hops and beer. It has a range of biological properties with potential therapeutic utility....