Polydymite, Ni²⁺Ni₂³⁺S₄, is a supergene

Supergene (geology)

In ore deposit geology, supergene processes or enrichment occur relatively near the surface. Supergene processes include the predominance of meteoric water circulation with concomitant oxidation and chemical weathering. The descending meteoric waters oxidize the primary sulfide ore minerals and...

 thiospinel

Thiospinel group

The thiospinel group is a group of sulfide minerals with a general formula AB2X4 where A is nominally a +2 metal, B is a +3 metal and X is -2 sulfide or similar anion...

 sulfide mineral

Sulfide mineral

The sulfide minerals are a class of minerals containing sulfide as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the arsenides, the antimonides, the bismuthinides, the sulfarsenides and the sulfosalts...

 associated with the weathering of primary pentlandite

Pentlandite

Pentlandite is an iron-nickel sulfide, 9S8. Pentlandite usually has a Ni:Fe ratio of close to 1:1. It also contains minor cobalt.Pentlandite forms isometric crystals, but is normally found in massive granular aggregates. It is brittle with a hardness of 3.5 - 4 and specific gravity of 4.6 - 5.0 and...

 nickel sulfide.

Polydymite crystallises in the isometric system, with a hardness of 4.5 to 5.5 and a specific gravity of about 4, is dark violet gray to copper-red, often with verdigris and patina from associated copper and arsenic sulfides, and is typically in amorphous to massive infill of lower saprolite

Saprolite

Saprolite is a chemically weathered rock. Saprolites form in the lower zones of soil profiles and represent deep weathering of the bedrock surface. In most outcrops its color comes from ferric compounds...

 ultramafic lithologies

Lithology

The lithology of a rock unit is a description of its physical characteristics visible at outcrop, in hand or core samples or with low magnification microscopy, such as colour, texture, grain size, or composition. It may be either a detailed description of these characteristics or be a summary of...

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Polydymite is the nickel equivalent of violarite

Violarite

Violarite is a supergene sulfide mineral associated with the weathering and oxidation of primary pentlandite nickel sulfide ore minerals....

 and in many cases these two minerals are formed together, potentially in solid solution

Solid solution

A solid solution is a solid-state solution of one or more solutes in a solvent. Such a mixture is considered a solution rather than a compound when the crystal structure of the solvent remains unchanged by addition of the solutes, and when the mixture remains in a single homogeneous phase...

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Common contaminants of polydymite are cobalt

Cobalt

Cobalt is a chemical element with symbol Co and atomic number 27. It is found naturally only in chemically combined form. The free element, produced by reductive smelting, is a hard, lustrous, silver-gray metal....

 and iron. Polydymite forms a series with linnaeite

Linnaeite

Linnaeite is a cobalt sulfide mineral with the composition Co+2Co+32S4 . It was discovered in 1845 in Västmanland, Sweden, and was named to honor Carl Linnaeus ....

, Co⁺²Co⁺³₂S₄.

Paragenesis

Polydymite is formed by oxidisation of primary sulfide assemblages in nickel sulfide mineralisation. The process of formation involves oxidation of Ni²⁺ and Fe²⁺ which is contained within the primary pentlandite

Pentlandite

Pentlandite is an iron-nickel sulfide, 9S8. Pentlandite usually has a Ni:Fe ratio of close to 1:1. It also contains minor cobalt.Pentlandite forms isometric crystals, but is normally found in massive granular aggregates. It is brittle with a hardness of 3.5 - 4 and specific gravity of 4.6 - 5.0 and...

-pyrrhotite

Pyrrhotite

Pyrrhotite is an unusual iron sulfide mineral with a variable iron content: FeS . The FeS endmember is known as troilite. Pyrrhotite is also called magnetic pyrite because the color is similar to pyrite and it is weakly magnetic...

-pyrite

Pyrite

The mineral pyrite, or iron pyrite, is an iron sulfide with the formula FeS2. This mineral's metallic luster and pale-to-normal, brass-yellow hue have earned it the nickname fool's gold because of its resemblance to gold...

 assemblage.

Continued oxidation of polydymite leads to replacement by goethite

Goethite

Goethite , named after the German polymath Johann Wolfgang von Goethe, is an iron bearing oxide mineral found in soil and other low-temperature environments. Goethite has been well known since prehistoric times for its use as a pigment. Evidence has been found of its use in paint pigment samples...

 and formation of a gossan

Gossan

Gossan is intensely oxidized, weathered or decomposed rock, usually the upper and exposed part of an ore deposit or mineral vein. In the classic gossan or iron cap all that remains is iron oxides and quartz often in the form of boxworks, quartz lined cavities retaining the shape of the dissolved...

ous boxwork, with nickel tending to remain as impurities within the goethite or hematite, or rarely as carbonate minerals.

Occurrence

Polydymite is reported widely from the oxidised regolith

Regolith

Regolith is a layer of loose, heterogeneous material covering solid rock. It includes dust, soil, broken rock, and other related materials and is present on Earth, the Moon, some asteroids, and other terrestrial planets and moons.-Etymology:...

above primary nickel sulfide ore systems worldwide. It is less common than related violarite, due to the high iron content of most primary sulfides.

Economic importance

Polydymite is an important transitional ore in many nickel sulfide mines, as it has increased nickel tenor (Ni% as a total of sulfide) and occupies a position within the mineralised profile where it must be extracted to pay for development down to the most valuable fresh mineralisation.