Smaltite
Encyclopedia
Smaltite is a variety of the mineral skutterudite
consisting of cobalt
iron
nickel
arsenide
: (Co,Fe,Ni)As2.
Smaltite crystallizes in the cubic system with the same hemihedral symmetry
as pyrite
; crystal
s have usually the form of cubes or cubo-octahedra, but are imperfectly developed and of somewhat rare occurrence. More often the mineral is found as compact or granular masses. The color is tin-white to steel-grey, with a metallic luster
; the streak is greyish black. Hardness is 5.5 and the specific gravity
is 6.5. The cobalt is partly replaced by iron
and nickel
, and as the latter increases in amount there is a passage to the isomorphous species chloanthite (NiAs2).
Smaltite occurs in veins with ore
s of cobalt, nickel, copper
and silver
. The best known localities are Cobalt, Ontario
and Schneeberg
in Saxony
, Germany
. The name smaltite was given by F. S. Beudant
in 1832 because the mineral was used in the preparation of smalt
for producing a blue color in porcelain
and glass
.
Skutterudite
Skutterudite is a cobalt arsenide mineral that has variable amounts of nickel and iron substituting for cobalt with a general formula: As3. Some references give the arsenic a variable formula subscript of 2-3. High nickel varieties are referred to as nickel-skutterudite, previously chloanthite...
consisting of cobalt
Cobalt
Cobalt is a chemical element with symbol Co and atomic number 27. It is found naturally only in chemically combined form. The free element, produced by reductive smelting, is a hard, lustrous, silver-gray metal....
iron
Iron
Iron is a chemical element with the symbol Fe and atomic number 26. It is a metal in the first transition series. It is the most common element forming the planet Earth as a whole, forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust...
nickel
Nickel
Nickel is a chemical element with the chemical symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel belongs to the transition metals and is hard and ductile...
arsenide
Arsenide
Arsenide is an arsenic anion with the charge −3. The trianion is formed by the reduction of arsenic by three electrons. For example heating arsenic powder with excess sodium gives sodium arsenide . The anions have no existence in solution since they are extremely basic...
: (Co,Fe,Ni)As2.
Smaltite crystallizes in the cubic system with the same hemihedral symmetry
Symmetry
Symmetry generally conveys two primary meanings. The first is an imprecise sense of harmonious or aesthetically pleasing proportionality and balance; such that it reflects beauty or perfection...
as pyrite
Pyrite
The mineral pyrite, or iron pyrite, is an iron sulfide with the formula FeS2. This mineral's metallic luster and pale-to-normal, brass-yellow hue have earned it the nickname fool's gold because of its resemblance to gold...
; crystal
Crystal
A crystal or crystalline solid is a solid material whose constituent atoms, molecules, or ions are arranged in an orderly repeating pattern extending in all three spatial dimensions. The scientific study of crystals and crystal formation is known as crystallography...
s have usually the form of cubes or cubo-octahedra, but are imperfectly developed and of somewhat rare occurrence. More often the mineral is found as compact or granular masses. The color is tin-white to steel-grey, with a metallic luster
Lustre (mineralogy)
Lustre is a description of the way light interacts with the surface of a crystal, rock, or mineral. The word lustre traces its origins back to the Latin word lux, meaning "light", and generally implies radiance, gloss, or brilliance....
; the streak is greyish black. Hardness is 5.5 and the specific gravity
Specific gravity
Specific gravity is the ratio of the density of a substance to the density of a reference substance. Apparent specific gravity is the ratio of the weight of a volume of the substance to the weight of an equal volume of the reference substance. The reference substance is nearly always water for...
is 6.5. The cobalt is partly replaced by iron
Iron
Iron is a chemical element with the symbol Fe and atomic number 26. It is a metal in the first transition series. It is the most common element forming the planet Earth as a whole, forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust...
and nickel
Nickel
Nickel is a chemical element with the chemical symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel belongs to the transition metals and is hard and ductile...
, and as the latter increases in amount there is a passage to the isomorphous species chloanthite (NiAs2).
Smaltite occurs in veins with ore
Ore
An ore is a type of rock that contains minerals with important elements including metals. The ores are extracted through mining; these are then refined to extract the valuable element....
s of cobalt, nickel, copper
Copper
Copper is a chemical element with the symbol Cu and atomic number 29. It is a ductile metal with very high thermal and electrical conductivity. Pure copper is soft and malleable; an exposed surface has a reddish-orange tarnish...
and silver
Silver
Silver is a metallic chemical element with the chemical symbol Ag and atomic number 47. A soft, white, lustrous transition metal, it has the highest electrical conductivity of any element and the highest thermal conductivity of any metal...
. The best known localities are Cobalt, Ontario
Cobalt, Ontario
Cobalt is a town in the district of Timiskaming, province of Ontario, Canada, with a population of 1,223 In 2001 Cobalt was named "Ontario's Most Historic Town" by a panel of judges on the TV Ontario program Studio 2, and in 2002 the area was designated a National Historic Site.-History:Silver was...
and Schneeberg
Schneeberg, Saxony
Schneeberg is a town in Saxony’s district of Erzgebirgskreis. It has roughly 16,400 inhabitants and belongs to the Town League of Silberberg . It lies 4 km west of Aue, and southeast of Zwickau.- Location :...
in Saxony
Saxony
The Free State of Saxony is a landlocked state of Germany, contingent with Brandenburg, Saxony Anhalt, Thuringia, Bavaria, the Czech Republic and Poland. It is the tenth-largest German state in area, with of Germany's sixteen states....
, Germany
Germany
Germany , officially the Federal Republic of Germany , is a federal parliamentary republic in Europe. The country consists of 16 states while the capital and largest city is Berlin. Germany covers an area of 357,021 km2 and has a largely temperate seasonal climate...
. The name smaltite was given by F. S. Beudant
François Sulpice Beudant
François Sulpice Beudant , French mineralogist and geologist, was born in Paris.He was educated at the Ecole Polytechnique and Ecole Normale, and in 1811 was appointed professor of mathematics at the lycée of Avignon. Thence he was called, in 1813, to the lycée of Marseilles to fill the post of...
in 1832 because the mineral was used in the preparation of smalt
Smalt
Smalt is powdered glass, colored to a deep powder blue hue using cobalt ions derived from cobalt oxide . Smalt is used as a pigment in painting, and for surface decoration of other types of glass and ceramics, and other media...
for producing a blue color in porcelain
Porcelain
Porcelain is a ceramic material made by heating raw materials, generally including clay in the form of kaolin, in a kiln to temperatures between and...
and glass
Glass
Glass is an amorphous solid material. Glasses are typically brittle and optically transparent.The most familiar type of glass, used for centuries in windows and drinking vessels, is soda-lime glass, composed of about 75% silica plus Na2O, CaO, and several minor additives...
.