Plain-carbon steel
Encyclopedia
Carbon steel, also called plain-carbon steel, is steel
where the main interstitial alloy
ing constituent is carbon
. The American Iron and Steel Institute
(AISI) defines carbon steel as: "Steel is considered to be carbon steel when no minimum content is specified or required for chromium
, cobalt
, molybdenum
, nickel
, niobium
, titanium
, tungsten
, vanadium
or zirconium
, or any other element to be added to obtain a desired alloying effect; when the specified minimum for copper does not exceed 0.40 percent; or when the maximum content specified for any of the following elements does not exceed the percentages noted: manganese
1.65, silicon
0.60, copper
0.60."
The term "carbon steel" may also be used in reference to steel which is not stainless steel
; in this use carbon steel may include alloy papers.
As the carbon content rises, steel has the ability to become harder and stronger
through heat treating, but this also makes it less ductile. Regardless of the heat treatment, a higher carbon content reduces weldability
. In carbon steels, the higher carbon content lowers the melting point.
.
It is often used when large quantities of steel are needed, for example as structural steel
. The density of mild steel is approximately 7.85 g/cm3 (7850 kg/m3 or 0.284 lb/in3) and the Young's modulus
is 210 GPa (30,457,924.9 psi).
Low carbon steels suffer from yield-point runout where the material has two yield points. The first yield point (or upper yield point) is higher than the second and the yield drops dramatically after the upper yield point. If a low carbon steel is only stressed to some point between the upper and lower yield point then the surface may develop Lüder bands.
s can have a significant effect on the quality of the resulting steel. Trace amounts of sulfur
in particular make the steel red-short
. Low alloy carbon steel, such as A36
grade, contains about 0.05% sulfur and melts around 1426 –. Manganese
is often added to improve the hardenability
of low carbon steels. These additions turn the material into a low alloy steel
by some definitions, but AISI
's definition of carbon steel allows up to 1.65% manganese by weight.
Medium carbon steel
Approximately 0.30–0.59% carbon content. Balances ductility and strength and has good wear resistance; used for large parts, forging and automotive components.
High carbon steel
Approximately 0.6–0.99% carbon content. Very strong, used for springs and high-strength wires.
Ultra-high carbon steel
Approximately 1.0–2.0% carbon content. Steels that can be tempered to great hardness. Used for special purposes like (non-industrial-purpose) knives, axles or punches. Most steels with more than 1.2% carbon content are made using powder metallurgy
. Note that steel with a carbon content above 2.0% is considered cast iron
.
The purpose of heat treating carbon steel is to change the mechanical properties of steel, usually ductility, hardness, yield strength, or impact resistance. Note that the electrical and thermal conductivity are slightly altered. As with most strengthening techniques for steel, Young's modulus
is unaffected. Steel has a higher solid solubility for carbon in the austenite
phase; therefore all heat treatments, except spheroidizing and process annealing, start by heating to an austenitic phase. The rate at which the steel is cooled through the eutectoid reaction affects the rate at which carbon diffuses out of austenite. Generally speaking, cooling swiftly will give a finer pearlite
(until the martensite
critical temperature is reached) and cooling slowly will give a coarser pearlite. Cooling a hypoeutectoid (less than 0.77 wt% C) steel results in a pearlitic structure with α-ferrite
at the grain boundaries. If it is hypereutectoid (more than 0.77 wt% C) steel then the structure is full pearlite with small grains of cementite
scattered throughout. The relative amounts of constituents are found using the lever rule
. Here is a list of the types of heat treatments possible:
; therefore wide pieces cannot be thru-hardened. Alloy steels have a better hardenability, so they can through-harden and do not require case hardening. This property of carbon steel can be beneficial, because it gives the surface good wear characteristics but leaves the core tough.
Steel
Steel is an alloy that consists mostly of iron and has a carbon content between 0.2% and 2.1% by weight, depending on the grade. Carbon is the most common alloying material for iron, but various other alloying elements are used, such as manganese, chromium, vanadium, and tungsten...
where the main interstitial alloy
Alloy
An alloy is a mixture or metallic solid solution composed of two or more elements. Complete solid solution alloys give single solid phase microstructure, while partial solutions give two or more phases that may or may not be homogeneous in distribution, depending on thermal history...
ing constituent is carbon
Carbon
Carbon is the chemical element with symbol C and atomic number 6. As a member of group 14 on the periodic table, it is nonmetallic and tetravalent—making four electrons available to form covalent chemical bonds...
. The American Iron and Steel Institute
American Iron and Steel Institute
The American Iron and Steel Institute is an association of North American steel producers. Its predecessor organizations date back to 1855 making it one of the oldest trade associations in the United States. AISI assumed its present form in 1908, with Elbert H...
(AISI) defines carbon steel as: "Steel is considered to be carbon steel when no minimum content is specified or required for chromium
Chromium
Chromium is a chemical element which has the symbol Cr and atomic number 24. It is the first element in Group 6. It is a steely-gray, lustrous, hard metal that takes a high polish and has a high melting point. It is also odorless, tasteless, and malleable...
, cobalt
Cobalt
Cobalt is a chemical element with symbol Co and atomic number 27. It is found naturally only in chemically combined form. The free element, produced by reductive smelting, is a hard, lustrous, silver-gray metal....
, molybdenum
Molybdenum
Molybdenum , is a Group 6 chemical element with the symbol Mo and atomic number 42. The name is from Neo-Latin Molybdaenum, from Ancient Greek , meaning lead, itself proposed as a loanword from Anatolian Luvian and Lydian languages, since its ores were confused with lead ores...
, nickel
Nickel
Nickel is a chemical element with the chemical symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel belongs to the transition metals and is hard and ductile...
, niobium
Niobium
Niobium or columbium , is a chemical element with the symbol Nb and atomic number 41. It's a soft, grey, ductile transition metal, which is often found in the pyrochlore mineral, the main commercial source for niobium, and columbite...
, titanium
Titanium
Titanium is a chemical element with the symbol Ti and atomic number 22. It has a low density and is a strong, lustrous, corrosion-resistant transition metal with a silver color....
, tungsten
Tungsten
Tungsten , also known as wolfram , is a chemical element with the chemical symbol W and atomic number 74.A hard, rare metal under standard conditions when uncombined, tungsten is found naturally on Earth only in chemical compounds. It was identified as a new element in 1781, and first isolated as...
, vanadium
Vanadium
Vanadium is a chemical element with the symbol V and atomic number 23. It is a hard, silvery gray, ductile and malleable transition metal. The formation of an oxide layer stabilizes the metal against oxidation. The element is found only in chemically combined form in nature...
or zirconium
Zirconium
Zirconium is a chemical element with the symbol Zr and atomic number 40. The name of zirconium is taken from the mineral zircon. Its atomic mass is 91.224. It is a lustrous, grey-white, strong transition metal that resembles titanium...
, or any other element to be added to obtain a desired alloying effect; when the specified minimum for copper does not exceed 0.40 percent; or when the maximum content specified for any of the following elements does not exceed the percentages noted: manganese
Manganese
Manganese is a chemical element, designated by the symbol Mn. It has the atomic number 25. It is found as a free element in nature , and in many minerals...
1.65, silicon
Silicon
Silicon is a chemical element with the symbol Si and atomic number 14. A tetravalent metalloid, it is less reactive than its chemical analog carbon, the nonmetal directly above it in the periodic table, but more reactive than germanium, the metalloid directly below it in the table...
0.60, copper
Copper
Copper is a chemical element with the symbol Cu and atomic number 29. It is a ductile metal with very high thermal and electrical conductivity. Pure copper is soft and malleable; an exposed surface has a reddish-orange tarnish...
0.60."
The term "carbon steel" may also be used in reference to steel which is not stainless steel
Stainless steel
In metallurgy, stainless steel, also known as inox steel or inox from French "inoxydable", is defined as a steel alloy with a minimum of 10.5 or 11% chromium content by mass....
; in this use carbon steel may include alloy papers.
As the carbon content rises, steel has the ability to become harder and stronger
Strength of materials
In materials science, the strength of a material is its ability to withstand an applied stress without failure. The applied stress may be tensile, compressive, or shear. Strength of materials is a subject which deals with loads, deformations and the forces acting on a material. A load applied to a...
through heat treating, but this also makes it less ductile. Regardless of the heat treatment, a higher carbon content reduces weldability
Weldability
The weldability, also known as joinability, of a material refers to its ability to be welded. Many metals and thermoplastics can be welded, but some are easier to weld than others...
. In carbon steels, the higher carbon content lowers the melting point.
Types
Carbon steel is broken down in to four classes based on carbon content:Mild and low carbon steel
Mild steel is the most common form of steel because its price is relatively low while it provides material properties that are acceptable for many applications. Low carbon steel contains approximately 0.05–0.25% carbon and mild steel contains 0.16–0.29% carbon; therefore, it is neither brittle nor ductile. Mild steel has a relatively low tensile strength, but it is cheap and malleable; surface hardness can be increased through carburizingCarburization
Carburizing, spelled carburising in the UK, is a heat treatment process in which iron or steel is heated in the presence of another material which liberates carbon as it decomposes. Depending on the amount of time and temperature, the affected area can vary in carbon content...
.
It is often used when large quantities of steel are needed, for example as structural steel
Structural steel
Structural steel is steel construction material, a profile, formed with a specific shape or cross section and certain standards of chemical composition and mechanical properties...
. The density of mild steel is approximately 7.85 g/cm3 (7850 kg/m3 or 0.284 lb/in3) and the Young's modulus
Young's modulus
Young's modulus is a measure of the stiffness of an elastic material and is a quantity used to characterize materials. It is defined as the ratio of the uniaxial stress over the uniaxial strain in the range of stress in which Hooke's Law holds. In solid mechanics, the slope of the stress-strain...
is 210 GPa (30,457,924.9 psi).
Low carbon steels suffer from yield-point runout where the material has two yield points. The first yield point (or upper yield point) is higher than the second and the yield drops dramatically after the upper yield point. If a low carbon steel is only stressed to some point between the upper and lower yield point then the surface may develop Lüder bands.
Higher carbon steels
Carbon steels which can successfully undergo heat-treatment have a carbon content in the range of 0.30–1.70% by weight. Trace impurities of various other elementChemical element
A chemical element is a pure chemical substance consisting of one type of atom distinguished by its atomic number, which is the number of protons in its nucleus. Familiar examples of elements include carbon, oxygen, aluminum, iron, copper, gold, mercury, and lead.As of November 2011, 118 elements...
s can have a significant effect on the quality of the resulting steel. Trace amounts of sulfur
Sulfur
Sulfur or sulphur is the chemical element with atomic number 16. In the periodic table it is represented by the symbol S. It is an abundant, multivalent non-metal. Under normal conditions, sulfur atoms form cyclic octatomic molecules with chemical formula S8. Elemental sulfur is a bright yellow...
in particular make the steel red-short
Red-short
Red-short, hot-short or Sulfur embrittlement is the quality possessed by carbon steel that suffers from having too much sulfur as an impurity.Iron or steel, when heated to above 900 °F , glows with a red color...
. Low alloy carbon steel, such as A36
A36 steel
A36 steel is a standard steel alloy which is a common structural steel used in the United States.The A36 standard was established by the standards organization ASTM International.- Properties :...
grade, contains about 0.05% sulfur and melts around 1426 –. Manganese
Manganese
Manganese is a chemical element, designated by the symbol Mn. It has the atomic number 25. It is found as a free element in nature , and in many minerals...
is often added to improve the hardenability
Hardenability
The hardenability of a metal alloy is its capability to be hardened by heat treatment. It should not be confused with hardness, which is a measure of a sample's resistance to indentation or scratching. It is an important property for welding, since it is inversely proportional to weldability,...
of low carbon steels. These additions turn the material into a low alloy steel
Low alloy steel
Alloy steel is steel that is alloyed with a variety of elements in total amounts between 1.0% and 50% by weight to improve its mechanical properties. Alloy steels are broken down into two groups: low-alloy steels and high-alloy steels...
by some definitions, but AISI
American Iron and Steel Institute
The American Iron and Steel Institute is an association of North American steel producers. Its predecessor organizations date back to 1855 making it one of the oldest trade associations in the United States. AISI assumed its present form in 1908, with Elbert H...
's definition of carbon steel allows up to 1.65% manganese by weight.
Medium carbon steel
Approximately 0.30–0.59% carbon content. Balances ductility and strength and has good wear resistance; used for large parts, forging and automotive components.
High carbon steel
Approximately 0.6–0.99% carbon content. Very strong, used for springs and high-strength wires.
Ultra-high carbon steel
Approximately 1.0–2.0% carbon content. Steels that can be tempered to great hardness. Used for special purposes like (non-industrial-purpose) knives, axles or punches. Most steels with more than 1.2% carbon content are made using powder metallurgy
Powder metallurgy
Powder metallurgy is the process of blending fine powdered materials, pressing them into a desired shape , and then heating the compressed material in a controlled atmosphere to bond the material . The powder metallurgy process generally consists of four basic steps: powder manufacture, powder...
. Note that steel with a carbon content above 2.0% is considered cast iron
Cast iron
Cast iron is derived from pig iron, and while it usually refers to gray iron, it also identifies a large group of ferrous alloys which solidify with a eutectic. The color of a fractured surface can be used to identify an alloy. White cast iron is named after its white surface when fractured, due...
.
Heat treatment
Young's modulus
Young's modulus is a measure of the stiffness of an elastic material and is a quantity used to characterize materials. It is defined as the ratio of the uniaxial stress over the uniaxial strain in the range of stress in which Hooke's Law holds. In solid mechanics, the slope of the stress-strain...
is unaffected. Steel has a higher solid solubility for carbon in the austenite
Austenite
Austenite, also known as gamma phase iron, is a metallic non-magnetic allotrope of iron or a solid solution of iron, with an alloying element. In plain-carbon steel, austenite exists above the critical eutectoid temperature of ; other alloys of steel have different eutectoid temperatures...
phase; therefore all heat treatments, except spheroidizing and process annealing, start by heating to an austenitic phase. The rate at which the steel is cooled through the eutectoid reaction affects the rate at which carbon diffuses out of austenite. Generally speaking, cooling swiftly will give a finer pearlite
Pearlite
Pearlite is often said to be a two-phased, lamellar structure composed of alternating layers of alpha-ferrite and cementite that occurs in some steels and cast irons...
(until the martensite
Martensite
Martensite, named after the German metallurgist Adolf Martens , most commonly refers to a very hard form of steel crystalline structure, but it can also refer to any crystal structure that is formed by displacive transformation. It includes a class of hard minerals occurring as lath- or...
critical temperature is reached) and cooling slowly will give a coarser pearlite. Cooling a hypoeutectoid (less than 0.77 wt% C) steel results in a pearlitic structure with α-ferrite
Ferrite (iron)
Ferrite or alpha iron is a materials science term for iron, or a solid solution with iron as the main constituent, with a body centred cubic crystal structure. It is the component which gives steel and cast iron their magnetic properties, and is the classic example of a ferromagnetic material...
at the grain boundaries. If it is hypereutectoid (more than 0.77 wt% C) steel then the structure is full pearlite with small grains of cementite
Cementite
Cementite, also known as iron carbide, is a chemical compound of iron and carbon, with the formula Fe3C . By weight, it is 6.67% carbon and 93.3% iron. It has an orthorhombic crystal structure. It is a hard, brittle material, normally classified as a ceramic in its pure form, though it is more...
scattered throughout. The relative amounts of constituents are found using the lever rule
Lever rule
The lever rule is a tool used to determine weight percentages of each phase of a binary equilibrium phase diagram. It is used to determine the percent weight of liquid and solid phases for a given binary composition and temperature that is between the liquidus and solidus.-Binary Phase...
. Here is a list of the types of heat treatments possible:
- Spheroidizing: Spheroidite forms when carbon steel is heated to approximately 700 °C for over 30 hours. Spheroidite can form at lower temperatures but the time needed drastically increases, as this is a diffusion-controlled process. The result is a structure of rods or spheres of cementite within primary structure (ferrite or pearlite, depending on which side of the eutectoid you are on). The purpose is to soften higher carbon steels and allow more formability. This is the softest and most ductile form of steel. The image to the right shows where spheroidizing usually occurs.
- Full annealingAnnealing (metallurgy)Annealing, in metallurgy and materials science, is a heat treatment wherein a material is altered, causing changes in its properties such as strength and hardness. It is a process that produces conditions by heating to above the recrystallization temperature, maintaining a suitable temperature, and...
: Carbon steel is heated to approximately 40 °C above Ac3 or Ac1 for 1 hour; this assures all the ferriteFerrite (iron)Ferrite or alpha iron is a materials science term for iron, or a solid solution with iron as the main constituent, with a body centred cubic crystal structure. It is the component which gives steel and cast iron their magnetic properties, and is the classic example of a ferromagnetic material...
transforms into austeniteAusteniteAustenite, also known as gamma phase iron, is a metallic non-magnetic allotrope of iron or a solid solution of iron, with an alloying element. In plain-carbon steel, austenite exists above the critical eutectoid temperature of ; other alloys of steel have different eutectoid temperatures...
(although cementiteCementiteCementite, also known as iron carbide, is a chemical compound of iron and carbon, with the formula Fe3C . By weight, it is 6.67% carbon and 93.3% iron. It has an orthorhombic crystal structure. It is a hard, brittle material, normally classified as a ceramic in its pure form, though it is more...
might still exist if the carbon content is greater than the eutectoid). The steel must then be cooled slowly, in the realm of 38°C (68.4°F) per hour. Usually it is just furnace cooled, where the furnace is turned off with the steel still inside. This results in a coarse pearlitic structure, which means the "bands" of pearlitePearlitePearlite is often said to be a two-phased, lamellar structure composed of alternating layers of alpha-ferrite and cementite that occurs in some steels and cast irons...
are thick. Fully annealed steel is soft and ductile, with no internal stresses, which is often necessary for cost-effective forming. Only spheroidized steel is softer and more ductile. - Process annealing: A process used to relieve stress in a cold-worked carbon steel with less than 0.3 wt% C. The steel is usually heated up to 550–650 °C for 1 hour, but sometimes temperatures as high as 700 °C. The image rightward shows the area where process annealing occurs.
- Isothermal annealing: It is a process in which hypoeutectoid steel is heated above the upper critical temperature and this temperature is maintained for a time and then the temperature is brought down below lower critical temperature and is again maintained. Then finally it is cooled at room temperature. This method rids any temperature gradient.
- Normalizing: Carbon steel is heated to approximately 55 °C above Ac3 or Acm for 1 hour; this assures the steel completely transforms to austenite. The steel is then air-cooled, which is a cooling rate of approximately 38 °C (68 °F) per minute. This results in a fine pearlitic structure, and a more-uniform structure. Normalized steel has a higher strength than annealed steel; it has a relatively high strength and ductility.
- Quenching: Carbon steel with at least 0.4 wt% C is heated to normalizing temperatures and then rapidly cooled (quenched) in water, brine, or oil to the critical temperature. The critical temperature is dependent on the carbon content, but as a general rule is lower as the carbon content increases. This results in a martensitic structure; a form of steel that possesses a super-saturated carbon content in a deformed body-centered cubic (BCC) crystalline structure, properly termed body-centered tetragonal (BCT), with much internal stress. Thus quenched steel is extremely hard but brittleBrittleA material is brittle if, when subjected to stress, it breaks without significant deformation . Brittle materials absorb relatively little energy prior to fracture, even those of high strength. Breaking is often accompanied by a snapping sound. Brittle materials include most ceramics and glasses ...
, usually too brittle for practical purposes. These internal stresses cause stress cracks on the surface. Quenched steel is approximately three to four (with more carbon) fold harder than normalized steel. - MartemperingMartemperingMartempering is a heat treatment for steel involving austenitisation followed by step quenching, at a rate fast enough to avoid the formation of ferrite, pearlite or bainite to a temperature slightly above the martensite start point. Soaking must be long enough to avoid the formation of bainite...
(Marquenching): Martempering is not actually a tempering procedure, hence the term "marquenching". It is a form of isothermal heat treatment applied after an initial quench of typically in a molten salt bath at a temperature right above the "martensite start temperature". At this temperature, residual stresses within the material are relieved and some bainite may be formed from the retained austenite which did not have time to transform into anything else. In industry, this is a process used to control the ductility and hardness of a material. With longer marquenching, the ductility increases with a minimal loss in strength; the steel is held in this solution until the inner and outer temperatures equalize. Then the steel is cooled at a moderate speed to keep the temperature gradient minimal. Not only does this process reduce internal stresses and stress cracks, but it also increases the impact resistance.
- Quench and temperingTemperingTempering is a heat treatment technique for metals, alloys and glass. In steels, tempering is done to "toughen" the metal by transforming brittle martensite or bainite into a combination of ferrite and cementite or sometimes Tempered martensite...
: This is the most common heat treatment encountered, because the final properties can be precisely determined by the temperature and time of the tempering. Tempering involves reheating quenched steel to a temperature below the eutectoid temperature then cooling. The elevated temperature allows very small amounts of spheroidite to form, which restores ductility, but reduces hardness. Actual temperatures and times are carefully chosen for each composition.
- AustemperingAustemperingAustempering is an isothermal heat treatment that is applied to ferrous metals, most notably steel and ductile iron. In steel it produces a lower bainite microstructure whereas in cast irons it produces a structure of acicular ferrite and high carbon, stabilized austenite known as ausferrite. It is...
: The austempering process is the same as martempering, except the steel is held in the molten salt bath through the bainite transformation temperatures, and then moderately cooled. The resulting bainite steel has a greater ductility, higher impact resistance, and less distortion. The disadvantage of austempering is it can only be used on a few steels, and it requires a special salt bath.
Case hardening
Case hardening processes harden only the exterior of the steel part, creating a hard, wear resistant skin (the "case") but preserving a tough and ductile interior. Carbon steels are not very hardenableHardenability
The hardenability of a metal alloy is its capability to be hardened by heat treatment. It should not be confused with hardness, which is a measure of a sample's resistance to indentation or scratching. It is an important property for welding, since it is inversely proportional to weldability,...
; therefore wide pieces cannot be thru-hardened. Alloy steels have a better hardenability, so they can through-harden and do not require case hardening. This property of carbon steel can be beneficial, because it gives the surface good wear characteristics but leaves the core tough.