IUPAC nomenclature of inorganic chemistry
Encyclopedia
The IUPAC nomenclature of inorganic chemistry is a systematic
Systematic name
A systematic name is a name given in a systematic way to one unique group, organism, object or chemical substance, out of a specific population or collection...

 method of naming inorganic chemical compound
Chemical compound
A chemical compound is a pure chemical substance consisting of two or more different chemical elements that can be separated into simpler substances by chemical reactions. Chemical compounds have a unique and defined chemical structure; they consist of a fixed ratio of atoms that are held together...

s, as recommended by the International Union of Pure and Applied Chemistry
International Union of Pure and Applied Chemistry
The International Union of Pure and Applied Chemistry is an international federation of National Adhering Organizations that represents chemists in individual countries. It is a member of the International Council for Science . The international headquarters of IUPAC is located in Zürich,...

 (IUPAC). The rules are commonly known as "The Red Book"
Ideally, every inorganic compound
Inorganic compound
Inorganic compounds have traditionally been considered to be of inanimate, non-biological origin. In contrast, organic compounds have an explicit biological origin. However, over the past century, the classification of inorganic vs organic compounds has become less important to scientists,...

 should have a name from which an unambiguous formula
Chemical formula
A chemical formula or molecular formula is a way of expressing information about the atoms that constitute a particular chemical compound....

 can be determined. There is also an IUPAC nomenclature of organic chemistry
IUPAC nomenclature of organic chemistry
The IUPAC nomenclature of organic chemistry is a systematic method of naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry . Ideally, every possible organic compound should have a name from which an unambiguous structural formula can be drawn. ...

.

System

The names "caffeine" and "3,7-dihydro-1,3,7-trimethyl-1H-purine-2,6-dione" both signify the same chemical. The systematic name encodes the structure and composition of the caffeine molecule in some detail, and provides an unambiguous reference to this compound, whereas the name "caffeine" just names it. These advantages make the systematic name far superior to the common name when absolute clarity and precision are required. However, for the sake of brevity, even professional chemists will use the non-systematic name almost all of the time, because caffeine is a well-known common chemical with a unique structure. Similarly, H2O is most often simply called water
Water
Water is a chemical substance with the chemical formula H2O. A water molecule contains one oxygen and two hydrogen atoms connected by covalent bonds. Water is a liquid at ambient conditions, but it often co-exists on Earth with its solid state, ice, and gaseous state . Water also exists in a...

 in English, though other chemical names do exist.
  1. Single atom anions are named with an -ide suffix: for example, H is hydride
    Hydride
    In chemistry, a hydride is the anion of hydrogen, H−, or, more commonly, a compound in which one or more hydrogen centres have nucleophilic, reducing, or basic properties. In compounds that are regarded as hydrides, hydrogen is bonded to a more electropositive element or group...

    .
  2. Compounds with a positive ion
    Ion
    An ion is an atom or molecule in which the total number of electrons is not equal to the total number of protons, giving it a net positive or negative electrical charge. The name was given by physicist Michael Faraday for the substances that allow a current to pass between electrodes in a...

     (cation): The name of the compound is simply the cation's name (usually the same as the element's), followed by the anion. For example, NaCl is sodium chloride
    Sodium chloride
    Sodium chloride, also known as salt, common salt, table salt or halite, is an inorganic compound with the formula NaCl. Sodium chloride is the salt most responsible for the salinity of the ocean and of the extracellular fluid of many multicellular organisms...

    , and CaF2 is calcium fluoride
    Calcium fluoride
    Calcium fluoride is the inorganic compound with the formula CaF2. This ionic compound of calcium and fluorine occurs naturally as the mineral fluorite . It is the source of most of the world's fluorine. This insoluble solid adopts a cubic structure wherein calcium is coordinated to eight fluoride...

    .
  3. Cations able to take on more than one positive charge are labeled with Roman numerals
    Roman numerals
    The numeral system of ancient Rome, or Roman numerals, uses combinations of letters from the Latin alphabet to signify values. The numbers 1 to 10 can be expressed in Roman numerals as:...

     in parentheses. For example, Cu+ is copper(I), Cu2+ is copper(II). An older, deprecated notation is to append -ous or -ic to the root of the Latin name to name ions with a lesser or greater charge. Under this naming convention, Cu+ is cuprous and Cu2+ is cupric. For naming metal complexes see the page on complex (chemistry)
    Complex (chemistry)
    In chemistry, a coordination complex or metal complex, is an atom or ion , bonded to a surrounding array of molecules or anions, that are in turn known as ligands or complexing agents...

    .
  4. Oxyanion
    Oxyanion
    An oxyanion or oxoanion is a chemical compound with the generic formula AxOyz− . Oxoanions are formed by a large majority of the chemical elements. The formulae of simple oxoanions are determined by the octet rule...

    s (polyatomic anions containing oxygen) are named with -ite or -ate, for a lesser or greater quantity of oxygen. For example, NO2 is nitrite, while NO3 is nitrate. If four oxyanions are possible, the prefixes hypo- and per- are used: hypochlorite is ClO, perchlorate is ClO4,
  5. The prefix bi- is a deprecated way of indicating the presence of a single hydrogen
    Hydrogen
    Hydrogen is the chemical element with atomic number 1. It is represented by the symbol H. With an average atomic weight of , hydrogen is the lightest and most abundant chemical element, constituting roughly 75% of the Universe's chemical elemental mass. Stars in the main sequence are mainly...

     ion, as in "sodium bicarbonate
    Sodium bicarbonate
    Sodium bicarbonate or sodium hydrogen carbonate is the chemical compound with the formula Na HCO3. Sodium bicarbonate is a white solid that is crystalline but often appears as a fine powder. It has a slightly salty, alkaline taste resembling that of washing soda . The natural mineral form is...

    " (NaHCO3). The modern method specifically names the hydrogen
    Hydrogen
    Hydrogen is the chemical element with atomic number 1. It is represented by the symbol H. With an average atomic weight of , hydrogen is the lightest and most abundant chemical element, constituting roughly 75% of the Universe's chemical elemental mass. Stars in the main sequence are mainly...

     atom. Thus, NaHCO3 would be pronounced sodium hydrogen carbonate.


Positively charged ions are called cations and negatively charged ions are called anions. The cation is always named first. Ions can be metals or polyatomic ions. Therefore the name of the metal or positive polyatomic ion is followed by the name of the non-metal or negative polyatomic ion. The positive ion retains its element name whereas for a single non-metal anion the ending is changed to -ide.

Example: sodium chloride, potassium oxide
Potassium oxide
Potassium oxide is an ionic compound of potassium and oxygen. This pale yellow solid, the simplest oxide of potassium, is a rarely encountered, highly reactive compound...

, or calcium carbonate
Calcium carbonate
Calcium carbonate is a chemical compound with the formula CaCO3. It is a common substance found in rocks in all parts of the world, and is the main component of shells of marine organisms, snails, coal balls, pearls, and eggshells. Calcium carbonate is the active ingredient in agricultural lime,...

.

When the metal has more than one possible ionic charge or oxidation number
Oxidation number
In coordination chemistry, the oxidation number of a central atom in a coordination compound is the charge that it would have if all the ligands were removed along with the electron pairs that were shared with the central atom. Oxidation numbers are often confused with oxidation states.The...

 the name becomes ambiguous. In these cases the oxidation number (the same as the charge) of the metal ion is represented by a Roman numeral in parentheses immediately following the metal ion name. For example in uranium(VI) fluoride the oxidation number
Oxidation number
In coordination chemistry, the oxidation number of a central atom in a coordination compound is the charge that it would have if all the ligands were removed along with the electron pairs that were shared with the central atom. Oxidation numbers are often confused with oxidation states.The...

 of uranium
Uranium
Uranium is a silvery-white metallic chemical element in the actinide series of the periodic table, with atomic number 92. It is assigned the chemical symbol U. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons...

 is 6. Another example is the iron oxides. FeO is iron(II) oxide and Fe2O3 is iron(III) oxide.

An older system used prefixes and suffixes to indicate the oxidation number, according to the following scheme:
Oxidation state Cations and acids Anions
Lowest hypo- -ous hypo- -ite
  -ous -ite
  -ic -ate
  per- -ic per- -ate
Highest hyper- -ic hyper- -ate


Thus the four oxyacids of chlorine
Chlorine
Chlorine is the chemical element with atomic number 17 and symbol Cl. It is the second lightest halogen, found in the periodic table in group 17. The element forms diatomic molecules under standard conditions, called dichlorine...

 are called hypochlorous acid (HOCl), chlorous acid (HOClO), chloric acid (HOClO2) and perchloric acid (HOClO3), and their respective conjugate base
Conjugate acid
Within the Brønsted–Lowry acid-base theory , a conjugate acid is the acid member, HX, of a pair of two compounds that transform into each other by gain or loss of a proton. A conjugate acid can also be seen as the chemical substance that releases, or donates, a proton in the forward chemical...

s are the hypochlorite, chlorite, chlorate and perchlorate ions. This system has partially fallen out of use, but survives in the common name
Common name
A common name of a taxon or organism is a name in general use within a community; it is often contrasted with the scientific name for the same organism...

s of many chemical compound
Chemical compound
A chemical compound is a pure chemical substance consisting of two or more different chemical elements that can be separated into simpler substances by chemical reactions. Chemical compounds have a unique and defined chemical structure; they consist of a fixed ratio of atoms that are held together...

s: the modern literature contains few references to "ferric chloride" (instead calling it "iron(III) chloride"), but names like "potassium permanganate" (instead of "potassium manganate(VII)") and "sulfuric acid" abound.

Naming simple ionic compounds

An ionic compound is named by its cation followed by its anion. See polyatomic ions for a list of possible ions.

For cations that take on multiple charges, the charge is written using Roman numerals in parentheses immediately following the element name. For example, Cu(NO3)2 is copper(II) nitrate
Copper(II) nitrate
Copper nitrate is the chemical compound with the formula Cu2. Commonly referred to simply as copper nitrate, the anhydrous form is a blue, crystalline solid...

, because the charge of two nitrate
Nitrate
The nitrate ion is a polyatomic ion with the molecular formula NO and a molecular mass of 62.0049 g/mol. It is the conjugate base of nitric acid, consisting of one central nitrogen atom surrounded by three identically-bonded oxygen atoms in a trigonal planar arrangement. The nitrate ion carries a...

 ions (NO3−1) is 2 × −1 = −2, and since the net charge of the ionic compound
Ionic compound
In chemistry, an ionic compound is a chemical compound in which ions are held together in a lattice structure by ionic bonds. Usually, the positively charged portion consists of metal cations and the negatively charged portion is an anion or polyatomic ion. Ions in ionic compounds are held together...

 must be zero, the Cu ion has a 2+ charge. This compound is therefore copper(II) nitrate. In the case of cations with a 4+ oxidation state, the acceptable format for the Roman numeral 4 is IV and not IIII.

The Roman numerals in fact show the oxidation number
Oxidation number
In coordination chemistry, the oxidation number of a central atom in a coordination compound is the charge that it would have if all the ligands were removed along with the electron pairs that were shared with the central atom. Oxidation numbers are often confused with oxidation states.The...

, but in simple ionic compounds (i.e., not metal complexes
Complex (chemistry)
In chemistry, a coordination complex or metal complex, is an atom or ion , bonded to a surrounding array of molecules or anions, that are in turn known as ligands or complexing agents...

) this will always equal the ionic charge on the metal. For a simple overview see http://www.cofc.edu/~deavorj/101/nomenclature.html, for more details see selected pages from IUPAC rules for naming inorganic compounds.

List of common ion names

Monatomic anions:
Cl chloride
Chloride
The chloride ion is formed when the element chlorine, a halogen, picks up one electron to form an anion Cl−. The salts of hydrochloric acid HCl contain chloride ions and can also be called chlorides. The chloride ion, and its salts such as sodium chloride, are very soluble in water...

S2− sulfide
Sulfide
A sulfide is an anion of sulfur in its lowest oxidation state of 2-. Sulfide is also a slightly archaic term for thioethers, a common type of organosulfur compound that are well known for their bad odors.- Properties :...

P3− phosphide
Phosphide
In chemistry, a phosphide is a compound of phosphorus with a less electronegative element or elements. Binary compounds are formed with the majority of less electronegative elements with the exception of Hg, Pb, Sb, Bi, Te, Po...



Polyatomic ion
Polyatomic ion
A polyatomic ion, also known as a molecular ion, is a charged species composed of two or more atoms covalently bonded or of a metal complex that can be considered as acting as a single unit in the context of acid and base chemistry or in the formation of salts. The prefix "poly-" means "many," in...

s:
NH4+ ammonium
Ammonium
The ammonium cation is a positively charged polyatomic cation with the chemical formula NH. It is formed by the protonation of ammonia...

H3O+ hydronium
Hydronium
In chemistry, a hydronium ion is the cation , a type of oxonium ion produced by protonation of water. This cation is often used to represent the nature of the proton in aqueous solution, where the proton is highly solvated...

NO3 nitrate
Nitrate
The nitrate ion is a polyatomic ion with the molecular formula NO and a molecular mass of 62.0049 g/mol. It is the conjugate base of nitric acid, consisting of one central nitrogen atom surrounded by three identically-bonded oxygen atoms in a trigonal planar arrangement. The nitrate ion carries a...

NO2 nitrite
Nitrite
The nitrite ion has the chemical formula NO2−. The anion is symmetric with equal N-O bond lengths and a O-N-O bond angle of ca. 120°. On protonation the unstable weak acid nitrous acid is produced. Nitrite can be oxidised or reduced, with product somewhat dependent on the oxidizing/reducing agent...

ClO hypochlorite
Hypochlorite
The hypochlorite ion, also known as chlorate anion is ClO−. A hypochlorite compound is a chemical compound containing this group, with chlorine in oxidation state +1.Hypochlorites are the salts of hypochlorous acid...

ClO2 chlorite
Chlorite
The chlorite ion is ClO2−. A chlorite is a compound that contains this group,with chlorine in oxidation state +3. Chlorites are also known as salts of chlorous acid.-Oxidation states:...

ClO3 chlorate
Chlorate
The chlorate anion has the formula ClO. In this case, the chlorine atom is in the +5 oxidation state. "Chlorate" can also refer to chemical compounds containing this anion; chlorates are the salts of chloric acid. "Chlorate", when followed by a roman numeral in parentheses, e.g...

ClO4 perchlorate
Perchlorate
Perchlorates are the salts derived from perchloric acid . They occur both naturally and through manufacturing. They have been used as a medicine for more than 50 years to treat thyroid gland disorders. They are used extensively within the pyrotechnics industry, and ammonium perchlorate is also a...

SO32− sulfite
Sulfite
Sulfites are compounds that contain the sulfite ion SO. The sulfite ion is the conjugate base of bisulfite. Although the acid itself is elusive, its salts are widely used.-Structure:...

SO42− sulfate
Sulfate
In inorganic chemistry, a sulfate is a salt of sulfuric acid.-Chemical properties:...

HSO3 hydrogen sulfite (or bisulfite
Bisulfite
Bisulfite ion is the ion HSO3−. Salts containing the HSO3− ion are termed bisulfites also known as sulfite lyes...

)
HCO3 hydrogen carbonate (or bicarbonate
Bicarbonate
In inorganic chemistry, bicarbonate is an intermediate form in the deprotonation of carbonic acid...

)
CO32− carbonate
Carbonate
In chemistry, a carbonate is a salt of carbonic acid, characterized by the presence of the carbonate ion, . The name may also mean an ester of carbonic acid, an organic compound containing the carbonate group C2....

PO43− phosphate
Phosphate
A phosphate, an inorganic chemical, is a salt of phosphoric acid. In organic chemistry, a phosphate, or organophosphate, is an ester of phosphoric acid. Organic phosphates are important in biochemistry and biogeochemistry or ecology. Inorganic phosphates are mined to obtain phosphorus for use in...

HPO42− hydrogen phosphate
H2PO4 dihydrogen phosphate
CrO42− chromate
Chromate
Chromate salts contain the chromate anion, CrO42−. Dichromate salts contain the dichromate anion, Cr2O72−. They are oxyanions of chromium in the oxidation state +6. They are moderately strong oxidizing agents.- Chemical properties :...

Cr2O72− dichromate
BO33− borate
Borate
Borates are chemical compounds which contain oxoanions of boron in oxidation state +3. The simplest borate ion, BO33−, has a trigonal planar structure. Other borates are made up of trigonal BO3 or tetrahedral BO4 structural units, sharing oxygen atoms...

AsO43− arsenate
Arsenate
The arsenate ion is AsO43−.An arsenate is any compound that contains this ion. Arsenates are salts or esters of arsenic acid.The arsenic atom in arsenate has a valency of 5 and is also known as pentavalent arsenic or As[V]....

C2O42− oxalate
Oxalate
Oxalate , is the dianion with formula C2O42− also written 22−. Either name is often used for derivatives, such as disodium oxalate, 2C2O42−, or an ester of oxalic acid Oxalate (IUPAC: ethanedioate), is the dianion with formula C2O42− also written (COO)22−. Either...

CN cyanide
Cyanide
A cyanide is a chemical compound that contains the cyano group, -C≡N, which consists of a carbon atom triple-bonded to a nitrogen atom. Cyanides most commonly refer to salts of the anion CN−. Most cyanides are highly toxic....

SCN thiocyanate
Thiocyanate
Thiocyanate is the anion [SCN]−. It is the conjugate base of thiocyanic acid. Common derivatives include the colourless salts potassium thiocyanate and sodium thiocyanate. Organic compounds containing the functional group SCN are also called thiocyanates...

MnO4 permanganate
Permanganate
A permanganate is the general name for a chemical compound containing the manganate ion, . Because manganese is in the +7 oxidation state, the permanganate ion is a strong oxidizing agent. The ion has tetrahedral geometry...


Naming hydrates

Hydrate
Hydrate
Hydrate is a term used in inorganic chemistry and organic chemistry to indicate that a substance contains water. The chemical state of the water varies widely between hydrates, some of which were so labeled before their chemical structure was understood....

s are ionic compounds that have absorbed water. They are named as the ionic compound followed by a numerical prefix and -hydrate. The numerical prefixes used are listed below (see IUPAC numerical multiplier
IUPAC numerical multiplier
The numerical multiplier in IUPAC nomenclature indicates how many particular atoms or functional groups are attached at a particular point in a molecule...

):
  1. mono-
  2. di-
  3. tri-
  4. tetra-
  5. penta-
  6. hexa-
  7. hepta-
  8. octa-
  9. nona-
  10. deca-

For example, CuSO4 · 5H2O is "copper(II) sulfate pentahydrate".

Naming molecular compounds

Inorganic molecular compounds are named with a prefix (see list above) before each element. The more electronegative
Electronegativity
Electronegativity, symbol χ , is a chemical property that describes the tendency of an atom or a functional group to attract electrons towards itself. An atom's electronegativity is affected by both its atomic number and the distance that its valence electrons reside from the charged nucleus...

 element is written last and with an -ide suffix. For example, H2O (water) can be called dihydrogen monoxide. Organic molecules do not follow this rule. In addition, the prefix mono- is not used with the first element; for example, SO2 is sulfur dioxide, not "monosulfur dioxide". Sometimes prefixes are shortened when the ending vowel of the prefix "conflicts" with a starting vowel in the compound. This makes the name easier to pronounce; for example, CO is "carbon monoxide" (as opposed to "monooxide").

Naming acids

Acids are named by the anion they form when dissolved in water. If an acid forms an anion ending in ide, then its name is formed by adding the prefix hydro to the anion's name and replacing the ide with ic. Finally the word acid is appended. For example, hydrochloric acid forms a chloride anion. With sulfur, however, the whole word is kept instead of the root: i.e.: hydrosulfuric acid. Secondly, anions with an -ate suffix are formed when acids with an -ic suffix are dissolved, e.g. chloric acid
Chloric acid
Chloric acid, HClO3, is an oxoacid of chlorine, and the formal precursor of chlorate salts. It is a strong acid and oxidizing agent....

  dissociates into chlorate anions to form salts such as sodium chlorate
Sodium chlorate
Sodium chlorate is a chemical compound with the chemical formula . When pure, it is a white crystalline powder that is readily soluble in water. It is hygroscopic. It decomposes above 250 °C to release oxygen and leave sodium chloride...

 ; anions with an -ite suffix are formed when acids with an -ous suffix are dissolved in water, e.g. chlorous acid
Chlorous acid
Chlorous acid is an inorganic compound with the formula HClO2. It is a weak acid. Chlorine has oxidation state +3 in this acid. The pure substance is unstable, disproportionating to hypochlorous acid and chloric acid :Although the acid is difficult to obtain in pure substance, the conjugate base,...

 (HClO2) disassociates into chlorite anions to form salts such as sodium chlorite
Sodium chlorite
Sodium chlorite is a chemical compound used in the manufacture of paper.-Use:The main application of sodium chlorite is the generation of chlorine dioxide for bleaching and stripping of textiles, pulp, and paper. It is also used for disinfection of a few municipal water treatment plants after...

 (NaClO2).
--121.54.54.33 (talk) 11:38, 1 December 2011 (UTC)kaye valdez--121.54.54.33 (talk) 11:38, 1 December 2011 (UTC)

2005 revision of IUPAC's nomenclature for inorganic compounds

See also

  • IUPAC nomenclature
    IUPAC nomenclature
    A chemical nomenclature is a set of rules to generate systematic names for chemical compounds. The nomenclature used most frequently worldwide is the one created and developed by the International Union of Pure and Applied Chemistry ....

  • IUPAC nomenclature of organic chemistry
    IUPAC nomenclature of organic chemistry
    The IUPAC nomenclature of organic chemistry is a systematic method of naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry . Ideally, every possible organic compound should have a name from which an unambiguous structural formula can be drawn. ...

  • List of inorganic compounds
  • Water of Crystallization
    Water of crystallization
    In crystallography, water of crystallization or water of hydration or crystallization water is water that occurs in crystals. Water of crystallization is necessary for the maintenance of crystalline properties, but capable of being removed by sufficient heat...


External links

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